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江苏省表面处理行业废酸处置利用现状及其问题分析

陈昊 叶飞 李兵 焦少俊 赵泽华 孙聪聪

陈昊, 叶飞, 李兵, 焦少俊, 赵泽华, 孙聪聪. 江苏省表面处理行业废酸处置利用现状及其问题分析[J]. 环境工程技术学报, 2017, 7(6): 718-725. doi: 10.3969/j.issn.1674-991X.2017.06.099
引用本文: 陈昊, 叶飞, 李兵, 焦少俊, 赵泽华, 孙聪聪. 江苏省表面处理行业废酸处置利用现状及其问题分析[J]. 环境工程技术学报, 2017, 7(6): 718-725. doi: 10.3969/j.issn.1674-991X.2017.06.099
CHEN Hao, YE Fei, LI Bing, JIAO Shaojun, ZHAO Zehua, SUN Congcong. Waste acid disposal and utilization status and existing problems of surface treatment industry in Jiangsu Province[J]. Journal of Environmental Engineering Technology, 2017, 7(6): 718-725. doi: 10.3969/j.issn.1674-991X.2017.06.099
Citation: CHEN Hao, YE Fei, LI Bing, JIAO Shaojun, ZHAO Zehua, SUN Congcong. Waste acid disposal and utilization status and existing problems of surface treatment industry in Jiangsu Province[J]. Journal of Environmental Engineering Technology, 2017, 7(6): 718-725. doi: 10.3969/j.issn.1674-991X.2017.06.099

江苏省表面处理行业废酸处置利用现状及其问题分析

doi: 10.3969/j.issn.1674-991X.2017.06.099
详细信息
    作者简介:

    陈昊(1975—),男,工程师,主要从事环境监测、固体废物管理工作, 18851310098@139.com

    通讯作者:

    李兵 E-mail: LB870246570@163.com

  • 中图分类号: X322

Waste acid disposal and utilization status and existing problems of surface treatment industry in Jiangsu Province

More Information
    Corresponding author: Bing LI E-mail: LB870246570@163.com
  • 摘要: 为提升废酸处置利用行业的整体水平,江苏省环境保护厅于2016年对全省废无机酸处置利用行业开展了环境专项调查,调查对象覆盖江苏省9个地级市内已登记注册的49家废酸处置企业,对企业管理的规范性、工艺的合理性、生产的安全性和环保措施的有效性进行了评价,并按等级对企业进行评分。根据调查资料总结了江苏省不同表面处理行业废酸的产生规模、集中地区和危险特性等现状,探讨了省内表面处理废酸再生工艺及综合利用方法的特点和问题,并对江苏省废酸处置行业的规范和相关部门的管理提出了几点建议。

     

  • [1] ROUZMEH S S, NADERI R, MAHDAVIAN M . A sulfuric acid surface treatment of mild steel for enhancing the protective properties of an organosilane coating[J]. Progress in Organic Coatings, 2017,153:156-164.doi: doi.org/10.1016/j.porgcoat.2016.10.033.
    [2] 环境保护部.国家危险废物名录(2016版)[EB/OL].(2016-10-31)[2017-05-30]..
    [3] 最高人民检察院.最高人民法院、最高人民检察院关于办理环境污染刑事案件适用法律若干问题的解释[EB/OL].(2016-12-23)[2017-05-30]..
    [4] 武卫政 .环境公益诉讼迈出一大步[N].人民日报, 2015 -01-24(9).
    [5] REN H H, CAO L W . Current status and development of dilute sulphuric acid concentration[J].Sulphur Phosphorus & Bulk Materials Handling Related Engineering, 2012(2):45-48.
    doi: 10.1155/2019/1063514 pmid: 31871786
    [6] 陈文松, 宁寻安, 白晓燕 . 废酸液的资源化处理技术[J]. 工业水处理, 2008,28(3):20-22.

    CHEN W S, NING X A, BAI X Y . Treatment technologies of waste acid liquid for resource recycling[J]. Industrical Water Treatment, 2008,28(3):20-22.
    [7] 董凯, 方超, 李洪翠 , 等. 采用RUTHNER(焙烧)法实现废酸的再利用[ C]//2007山东环境科学学会年会.济南:山东环境科学学会, 2007.
    [8] 张振林, 杨绿, 王海林 . 酸洗废酸液的热化学再生技术评价[J]. 化工环保, 2016,36(6):605-610.

    ZHANG Z L, YANG L, WANG H L . Evaluation of thermal-chemistry regeneration technical for waste pickling liquid[J]. Environmental Protection of Chemical Industry, 2016,36(6):605-610.
    [9] 王光华, 查振林, 李健 , 等. 钢铁工业硫酸酸洗废液的处理[J]. 工业安全与环保, 2009,35(8):13-15.
    [10] ZHAI J, JIANG C H, WU J . Techniques for treating sulphuric acid pickling waste liquid of steel industry[J].Meteorological & Environmental Research, 2013(5):44-49.
    doi: 10.30476/ijms.2019.44968 pmid: 31875081
    [11] ZHAI J, JIANG C H, WU J .Waste steel-pickling sulphuric acid removal treated by freezing crystallization-acid retardation coupling technology[J]. Advanced Materials Research, 2014, 955/956/957/958/ 959:2915-2918.
    [12] DOROFEEV V Y, KORCHAGINA M V, NAUMENKO A A . Porous ceramic membranes for regeneration of waste sulfate solutions[J]. Glass and Ceramics, 2002,59(3):103-105.
    doi: 10.1023/A:1019527929046
    [13] 李海宇, 宋卫锋 . 膜处理技术在废酸回收中的应用[J]. 膜科学与技术, 2016,36(3):136-141.

    LI H Y, SONG W F . Application of membrane in the treatment of acid recovery[J]. Membrane Science and Technology, 2016,36(3):136-141.
    [14] 彭会清, 庞翠玲 . 膜分离技术在处理酸性废液中的应用概述[J].金属矿山, 2006(9):14-17.

    PENG H Q, PANG C L . Summarization of application of membrane separation technology in acidic liquid waste treatment[J].Metal Mine, 2006(9):14-17.
    [15] 朱秋华, 褚仁雪, 张蓉 , 等. 膜分离技术处理紫金某铜矿含铜酸性废水[J]. 有色冶金设计与研究, 2011,32(2):45-47.

    ZHU Q H, CHU R X, ZHANG R , et al. Treatment of copper-bearing acid mine drainage from a certain copper mine in Zijin with membrane separation technology[J]. Nonferrous Metal Engineering & Research, 2011,32(2):45-47.
    [16] VROUWENVELDER J S, KAPPELHOF J W N M, HEIJRNAN S G J, ,et al.Tools for fouling diagnosis of NF and RO membranes and assessment of the fouling potential of feed water[J]. Desalination, 2003,157(1/2/3):361-365.
    doi: 10.1016/S0011-9164(03)00417-X
    [17] ZHAO D, YU S . A review of recent advance in fouling mitigation of NF/RO membranes in water treatment: pretreatment, membrane modification, and chemical cleaning[J]. Desalination & Water Treatment, 2015,55(4):870-891.
    doi: 10.1016/j.watres.2019.115402 pmid: 31874390
    [18] OGAWA N, KIMURA K, WATANABE Y . Membrane fouling in nanofiltration/reverse osmosis membranes coupled with a membrane bioreactor used for municipal wastewater treatment[J]. Desalination & Water Treatment, 2012,18(1/2/3):292-296.
    doi: 10.1016/j.watres.2019.115402 pmid: 31874390
    [19] 王贵喜, 任艳平, 何宗健 . 不锈钢酸洗混合废酸(HNO3-HF)的回收以及离子交换法在其纯化中的应用[J].江西化工, 2010(1):138-141.
    [20] 张博, 刘红召, 王威 , 等. 弱碱性离子交换树脂从钼冶炼废酸中回收铼的研究[J].矿产保护与利用, 2016(4):41-46.

    ZHANG B, LIU H Z, WANG W , et al. Investigations on recycling rhenium from the waste acid of molybdenum smelting by weak base ion exchange resin[J].Conservation and Ultilization of Mineral Resource, 2016(4):41-46.
    [21] GAIKWAD R W, SAPKAL V S, SAPKAL R S . Ion exchange system design for removal of heavy metals from acid mine drainage wastewater[J]. Acta Montanistica Slovaca, 2010,15(4):298-304.
    [22] WÓDZKI R .Encyclopedia of separation science:level Ⅱ:methods and instrumentation:ion exchange:organic membranes[M/OL].[S.l.]:Elsevier Science Ltd, 2000: 1632-1639. .
    [23] KONONOVA O N, ZEMLYANSKAYA A I, DUBA E V . Ion-exchange recovery of nickel(Ⅱ) and cobalt(Ⅱ) from sulfuric acid solutions[J]. Russian Journal of Applied Chemistry, 2015,88(11):1763-1769.
    doi: 10.1134/S1070427215011004X
    [24] PLOKHOV E S, MIKHALENKO M G, PLOKHOV S V . Ion-exchange recovery of nickel(Ⅱ) from wash water formed in electroless plating in acid hypophosphite solutions[J]. Russian Journal of Applied Chemistry, 2006,79(10):1571-1575.
    doi: 10.1134/S1070427206100028
    [25] LI Q G, ZHANG Q X, LI Z E , et al. On the recovery of tungsten and molybdenum out of acid leaching solution by ion-exchange[J]. China Tungsten Industry, 2009,24(5):56-59.
    [26] 汤泉, 胡彩霞, 谢微 , 等. 基于废酸处理的聚硫氯化铝净水剂的合成研究[J].现代化工, 2016(2):77-79.

    TANG Q, HU C X, XIE W , et al. Synjournal of polysulfide aluminium chloride water purifying agent for waste acid treatment[J].Modern Chemical Industry, 2016(2):77-79.
    [27] 李明玉, 李善得, 唐启红 . 用硫铁矿烧渣生产新型高效复合聚铁PISC净水剂及在水处理中的应用[C]//全国水处理混凝技术研讨会.北京:中国化工学会, 2007.
    [28] 阳卫国 . 用钢管酸洗废水生产聚合硫酸铁技术的研究和应用[J]. 环境工程, 2011,29(6):25-27.

    YANG W G . Study and application of technology of a technique for a production of polymerizing iron sulphate using steel tube acid washing wastewater[J]. Environmental Engineering, 2011,29(6):25-27.
    [29] 刘立华, 曾荣今, 徐国荣 , 等. 钢铁酸洗废水制备聚磷氯化硫酸铝铁及其对制革废水的去除性能[C]//2014中国环境科学学会学术年会论文集(第五章).北京:中国环境科学学会, 2014.
    [30] JU Y D, YUAN H P . Preparation of composite flocculants and its decolorization of dyeing effluents[J].Dyeing & Finishing, 2012(20):14-17.
    doi: 10.3390/molecules24244613 pmid: 31861075
    [31] 汪浩, 陈世荣, 罗小虎 , 等. 利用硝酸型退锡废液回收锡单质的研究[J].印制电路信息, 2012(11):63-67.

    WANG H, CHEN S R, LUO X H , et al. The research of recycling tin from the spent nitric etching solution[J].Printed Circuit Information, 2012(11):63-67.
    [32] 张利, 刘兴勇 . 硝酸型PCB退锡废水回收利用工艺研究[J]. 广州化工, 2012,40(12):81-82.

    ZHANG L, LIU X Y . Study on the retrieve and utilizing of nitric spent tin stripper from printed circuit board[J]. Guangzhou Chemical Industry, 2012,40(12):81-82.
    [33] 郭云霄, 查正炯, 吴阳东 . 退锡废液的资源化利用研究[J]. 广东化工, 2016,43(8):130-131.

    GUO Y X, ZHA Z J, WU Y D . Research on resource recycle of spent tin-stripping solution[J]. Guangzhou Chemical Industry, 2016,43(8):130-131.
    [34] 李德良, 许中坚, 黄念东 , 等. PCB企业退焊锡废液治理再生研究[J]. 环境科学研究, 2000,13(5):17-19.

    LI D L, XU Z J, HUANG N D , et al. Studies of the regeneration process of the stripping wastewater in PCB enterprises[J]. Reserch of Environmental Science, 2000,13(5):17-19.
    [35] 牟林琳 . 液晶显示屏洗屏废酸制备磷肥的实验研究[D]. 武汉:武汉工程大学, 2014.

    MOU L L . Study of preparation of phosphate and compound fertilizer by waste water etching liquid in the production process of thin film transister liquid crystal display[D]. Wuhan:Wuhan Institute of Technology, 2014.
    [36] 柳正 . 我国磷矿资源的开发利用现状及发展战略[J].中国非金属矿工业导刊, 2006(1):7-9.
    [37] 刘序达 . 工业废磷化液的处理方法[J].表面技术, 2008(6):9.
    [38] 徐兴平, 王小娟 . 钢管钢丝绳厂酸性废水处理工艺设计与应用[J]. 中国资源综合利用, 2013,31(5):27-31.
    [39] 陈文衡, 谢文发, 刘婷 .利用表面处理过程产生的含镍废水制备电镀级硫酸镍的方法和设备:CN104229906A[P]. 2014-12-24.
    [40] 陈刚, 李静, 郝春亮 . 废酸处理技术简介[ C]//中国腐蚀与防护学会全国热浸镀大会,深圳:中国腐蚀与防护协会, 2004.
    [41] SCHMIDT B, WOLTERS R, KAPLIN J , et al. Rinse water regeneration in stainless steel pickling[J]. Desalination, 2007,211(1/2/3):64-71.
    doi: 10.1016/j.desal.2006.03.591
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  • 收稿日期:  2017-06-10
  • 刊出日期:  2017-11-20

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