The influence of temperature on BTEXs release in used mineral oil incineration disposal process
-
摘要: 以废矿物油中苯系物(BTEXs)为研究对象,实验室条件下模拟废矿物油在空气气氛中的焚烧,并研究烟气中BTEXs的释放强度与焚烧温度的关系。试验条件:焚烧温度梯度为300、500、700、900、1 100 ℃,空气气氛,样品用量1.00 g。研究表明:在300~1 100 ℃的升温过程中,烟气中BTEXs残留率呈减小趋势;苯以外的BTEXs在达到700 ℃后减量效果显著提高,且当焚烧温度为1 100 ℃时,残留率为0~7.6%;苯在300~700 ℃的释放量呈增加趋势,且在700 ℃时焚烧烟气中苯浓度约为样品本底的14倍,在900和1 100 ℃时,提升焚烧温度对烟气中苯的减量效果不明显。Abstract: The incineration of used mineral oil under the condition of air atmosphere was simulated under the laboratory scale, and the relationship between the release intensity of BTEXs in flue gas and the incineration temperature studied. The experimental condition was as follows: incineration temperature at 300, 500, 700, 900 and 1 100 ℃, air atmosphere, the quantity of used mineral oil about 1.00 g. The results showed that in the increasing process of incineration temperature from 300 to 1 100 ℃, the total BTEXs release showed a trend of decrease. The reduction effect of BTEXs except benzene increased significantly when the incineration temperature was over 700 ℃, and when the incineration temperature was at 1 100 ℃, the residue rate was 0 to 7.6%. The benzene release showed an increased trend under the incineration temperature of 300 to 700 ℃, and at 700 ℃, the amount of benzene in the incineration flue gas was about 14 times of the sample's background content. From 900 to 1 100 ℃, the reduction effect of the benzene in the flue gas was not obvious by increasing the incineration temperature.
-
Key words:
- used mineral oil /
- BTEXs /
- incineration /
- temperature
-
[1] 廖蔚峰, 慎义勇 . 废矿物油的处理处置[J]. 中国资源综合利用, 2006,24(12):17-20.LIAO W F, SHEN Y Y . Disposal of waste oil[J]. China Resources Comprehrndive Utilization, 2006,24(12):17-20. [2] ARPA O, YUMRUTAS R, DEMIRBAS A . Production of diesel-like fuel from waste engine oil by pyrolitic distillation[J]. Applied Energy, 2010,87(1):122-127.
doi: 10.1016/j.apenergy.2009.05.042[3] SAINIO P, MÄKINEN I, HUTTER J W, et al. Feasibility study for the preparation of certified reference materials:part Ⅰ.mineral oil contaminated soils[J]. Accreditation and Quality Assurance, 2006,11(3):116-121.
doi: 10.1007/s00769-006-0101-4[4] NIU H, LI Z, LEE K , et al. Modelling the transport of oil-mineral-aggregates(OMAs) in the marine environment and assessment of their potential risks[J]. Environmental Modeling & Assessment, 2010,16(1):61-75.
doi: 10.30476/ijms.2019.44968 pmid: 31875081[5] 王琪, 黄启飞, 高兴保 , 等. 废矿物油贮存豁免量限值研究[J]. 环境工程技术学报, 2013,3(1):41-45.
doi: 10.3969/j.issn.1674-991X.2013.01.008WANG Q, HUANG Q F, GAO X B , et al. Exemption limit value for used mineral oil storage[J]. Journal of Environmental Engineering Technology, 2013,3(1):41-45. doi: 10.3969/j.issn.1674-991X.2013.01.008[6] 刘怡靖 . 废矿物油再生利用项目环评工作的探讨[J]. 环境科学与管理, 2012,37(2):176-178.LIU Y J . Study on environmental impact assessment of waste mineral oil recycling[J]. Environmental Science and Management, 2012,37(2):176-178. [7] 李杰峰, 邹钢 .一种废矿物油的再生工艺:CN105694962A[P]. 2016-06-22. [8] 卜素伟, 刘永民 . 安钢废矿物油再生利用的可行性分析[J]. 河南冶金, 2012,20(4):39-41.BU S W, LIU Y M . Study on feasibility of waste mineral oil recirculation[J]. Henan Metallurgy, 2012,20(4):39-41. [9] 黄启飞, 杨玉飞, 岳波 , 等. 典型危险废物污染控制关键环节识别研究[J]. 环境工程技术学报, 2013,3(1):6-9.
doi: 10.3969/j.issn.1674-991X.2013.01.002HUANG Q F, YANG Y F, YUE B , et al. Identification of the key pollution control links of the typical hazardous wastes[J]. Journal of Environmental Engineering Technology, 2013,3(1):6-9. doi: 10.3969/j.issn.1674-991X.2013.01.002[10] ROY S, LABELLE S, MEHTA P , et al. Phytoremediation of heavy metal and PAH-contaminated brownfield sites[J]. Plant and Soil, 2005,272(1):277-290.
doi: 10.1007/s11104-004-5295-9[11] CORMIER S A, LOMNICKI S, BACKES W , et al. Origin and health impacts of emissions of toxic by-products and fine particles from combustion and thermal treatment of hazardous wastes and materials[J]. Environmental Health Perspectives, 2006,114(6):810-817.
doi: 10.1289/ehp.8629 pmid: 16759977[12] ALI M F, ABBAS S . A review of methods for the demetallization of residual fuel oils[J]. Fuel Processing Technology, 2006,87(7):573-584.
doi: 10.1016/j.fuproc.2006.03.001[13] 苏毅 . 废矿物油的污染特性及其环境风险研究[D]. 重庆:重庆交通大学, 2015.SU Y . Research of pollution characteristics and environmental risk on used mineral oil[D]. Chongqing:Chongqing Jiaotong University, 2015. [14] 任立明, 王志国, 郑磊 . 我国社会源危险废物产生、回收及处置现状及管理对策[J]. 中国环境管理, 2013,5(2):59-64. [15] SAMAKSAMAN U, PENG T H, KUO J H , et al. Thermal treatment of soil co-contaminated with lube oil and heavy metals in a low-temperature two-stage fluidized bed incinerator[J]. Applied Thermal Engineering, 2015,93:131-138.
doi: 10.1016/j.applthermaleng.2015.09.024[16] OSU C I, OKORO I A . Distribution of organic compounds(PAHs and BTEX) and heavy metals(Pb,Zn,Fe,Cd) in an oil impacted soils,Rivers State Nigeria[J]. Journal of Applied Sciences in Environmental Sanitation, 2012,7(4):73-78. [17] 环境保护部. 环境空气苯系物的测定活性炭吸附/二硫化碳解吸-气相色谱法: HJ 584—2010[S].北京:中国环境科学出版社, 2010. [18] 肖惠平, 马增益, 贾海龙 , 等. 以氧化铝中空小球为床料的流化床焚烧甲苯气体试验研究[J].能源工程, 2013(1):60-63.XIAO H P, MA Z Y, JIA H L , et al. Experimental research on methylbenzene air fluidized bed incineration with small hollow Al2O3 bed material[J].Energy Engineering, 2013(1):60-63. [19] 李国政, 邱建华, 张峻松 , 等. 气质联用法测定烟用搭口胶热裂解产物中的苯系物[J].郑州轻工业学院学报(自然科学版), 2014(5):44-46.LI G Z, QIU J H, ZHANG J S , et al. Determination of benzene series in the cigarette lap adhesive pyrolysis products by GC-MS[J].Journal of Zhengzhou University of Light Industry (Natural Science), 2014(5):44-46. [20] 褚赟, 翁焕新, 章金骏 , 等. 污泥干化过程中苯系物(BTEX)的释放及其致癌风险评价[J]. 环境科学学报, 2009,29(4):777-785.CHU Y, WENG H X, ZHANG J J , et al. BTEX release and its carcinogenic risk assessment during swage sludge dewatering[J]. Acta Scientiae Circurn Stantiae, 2009,29(4):777-785. [21] 孔浩辉, 鲁虹, 陈翠玲 , 等. 不同氛围下烟草的热裂解行为研究[J]. 分析测试学报, 2010,29(6):612-616.KONG H H, LU H, CHEN C L , et al. Pyrolysing study of tobaccos under inert and oxidative conditions[J]. Journal of Instrumental Analysis, 2010,29(6):612-616. [22] RINK K K, LARSEN F S, KOZINSKI J A , et al. Thermal treatment of hazardous wastes:a comparison of fluidized bed and rotary kiln incineration[J]. Energy Fuels, 1993,7(6):803-813.
doi: 10.1080/10473289.1991.10466921 pmid: 1756041[23] MARANI D, BRAGUGLIA C M, MININNI G , et al. Behaviour of Cd,Cr,Mn,Ni,Pb and Zn in sewage sludge incineration by fluidised bed furnace[J]. Waste Management, 2003,23(2):117-124.
doi: 10.1016/S0956-053X(02)00044-2 pmid: 12623086[24] DESAI D L, ANTHONY E J, WANG J . A pilot-plant study for destruction of PCBs in contaminated soils using fluidized bed combustion technology[J]. Journal of Environmental Management, 2007,84(3):299-304.
doi: 10.1016/j.jenvman.2006.06.006[25] 吴冬冬 . 柴油机废气中苯系物测量及生成机理研究[D]. 武汉:华中科技大学, 2008.WU D D . Exhaust measuring and formation mechanism study of benzene and its analogies from the diesel engine[D]. Wuhan:Huazhong University of Science and Technology, 2008.
点击查看大图
计量
- 文章访问数: 376
- HTML全文浏览量: 62
- PDF下载量: 511
- 被引次数: 0