典型全氟化合物PFOS/PFOA的生态风险及控制对策

曹莹; 张亚辉; 闫振广; 王一喆; 朱岩; 刘征涛

doi:10.3969/j.issn.1674-991X.2017.01.014

典型全氟化合物PFOS/PFOA的生态风险及控制对策

doi: 10.3969/j.issn.1674-991X.2017.01.014

曹莹¹,
张亚辉^1,*, ,,
闫振广¹,
王一喆¹,
朱岩²,
刘征涛¹

1.
环境基准与风险评估国家重点实验室,中国环境科学研究院,北京 100012
2.
桂林理工大学环境科学与工程学院,广西桂林 541004

详细信息

作者简介:
曹莹(1983—),女,工程师,硕士,主要从事环境风险评估研究, caoyingyeah@sina.com

通讯作者:
张亚辉 E-mail: zhangyahui@craes.org.cn

中图分类号: X826
计量
- 文章访问数: 1811
- HTML全文浏览量: 86
- PDF下载量: 1623
- 被引次数: 0
出版历程
- 收稿日期: 2016-05-17
- 刊出日期: 2017-01-20

Ecological risks and control measures of typical perfluorinated compounds PFOS/PFOA

1.
State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Research Academy of Environmental Sciences, Beijing 100012, China
2.
College of environmental Science and Engineering, Guilin University of TechnoLogy, Guilin 541004, China

More Information

Corresponding author: Yahui ZHANG E-mail: zhangyahui@craes.org.cn

摘要

摘要: 环境中最常见的2种全氟化合物(PFCs)污染物为全氟辛烷磺酸(PFOS)和全氟辛烷羧酸(PFOA)。综述了国内外推荐的有关的PFOS/PFOA环境安全阈值,结合我国部分流域及典型区域PFOS/PFOA的污染现状,分析了现阶段我国PFCs生态风险管理面临的问题,提出了制订我国PFOS/PFOA环境质量基准/标准,加强典型区域2种PFCs的生态风险评估,增强其物质替代品的监控、生态毒性监管,以及替代品的风险防控等方面的建议。
- 全氟辛烷磺酸(PFOS) /
- 全氟辛烷羧酸(PFOA) /
- 生态风险 /
- 对策
Abstract: The two most common PFCs pollutants found in nature were perfluorooctane sulfonate (PFOS) and perfluorooctane acid (PFOA). The recommendations of environmental safety thresholds of PFOS and PFOA were reviewed at home and abroad. Based on the pollution status of PFOS and PFOA in some basins and typical areas in China, the problems of the ecological risk management of PFCs in China were analyzed. Some suggestions were proposed, including formulating the PFOS and PFOA environmental quality criteria/standards, strengthening the ecological risk assessment of typical regional PFCs, and enhancing the material substitutes monitoring, ecological toxicity supervision and substitutes risk prevention and control, etc.
- PFOS /
- PFOA /
- ecological risk /
- control measures

HTML全文

参考文献(45)

[1]	郭睿, 蔡亚岐, 江桂斌 , 等. 全氟辛烷磺酰基化合物(PFOS)的污染现状与研究趋势[J]. 化学进展, 2006,18(6):808-813. GUO R, CAI Y Q, JIANG G B , et al. Current research of perfluorooctane sulfonate[J]. Progress in Chemistry, 2006,18(6):808-813.
[2]	潘媛媛, 史亚利, 王杰明 , 等. 北京市污水处理厂中全氟化合物的污染水平[J]. 中国科学:化学, 2011,41(6):1095. doi: 10.1007/s11426-010-4093-x
[3]	金一和, 刘晓, 秦红梅 , 等. 我国部分地区自来水和不同水体中的PFOS污染[J]. 中国环境科学, 2004,24(2):166-169. JIN Y H, LIU X, QIN H M , et al. The status quo of perfluorooctane sulfonate(PFOS) pollution in tap water and different waters in partial areas of China[J]. China Environmental Science, 2004,24(2):166-169.
[4]	吴澄, 李子卉, 程金平 , 等. 水体及人体中全氟辛烷磺酸基化合物的污染及其影响因素[J]. 环境与健康杂志, 2009,26(2):180-182. WU C, LI Z H, CHENG J P , et al. Research progress on water perfluorooctanesulfonate pollution,human body burden and influencing factors[J]. Journal Environmental Health, 2009,26(2):180-182.
[5]	杨永亮, 路国慧, 杨伟贤 , 等. 沈阳地区水环境和生物样品中全氟化合物的污染分布特征[J]. 环境科学学报, 2010,30(10):2097-2107. YANG Y L, LU G H, YANG W X , et al. Levels and distribution of perfluorinated compounds in water and biological samples from the Shenyang area,China[J]. Acta Scientiae Circumstantiae, 2010,30(10):2097-2107.
[6]	SO M K, YAMASHITA N, TANIYASU S , et al. Health risks in infants associated with exposure to perfluorinated compounds in human breast milk from Zhoushan,China[J]. Environmental Science & Technology, 2006,40(9):2924-2929. doi: 10.1021/es060031f pmid: 16719092
[7]	王亚韡, 江桂斌 . 斯德哥尔摩公约新增持久性有机污染物的一些研究进展[J]. 中国科学:化学, 2010,40(2):99-123.
[8]	陈荣圻 . PFOS和PFOA替代品取向新进展[J]. 印染助剂, 2012,29(12):1-10. CHEN R Q . Development and trend of substitutes to PFOS and PFOA[J]. Textile Auxiliaries, 2012,29(12):1-10.
[9]	BROOKE D, FOOTITT A, NWAOGU T A , et al. Environmental risk evaluation report:perfluorooctane sulphonate(PFOS)[R]. London:UK Environment Agency, 2004.
[10]	THOMAS G, MARIE B, NICHOLAS G , et al. Technical review and reassessment of the UK environmental risk evaluation report for perfluorooctanesulfonate(PFOS)[R]. Minnesota:3M Company, 2010.
[11]	ZUSHI Y, HOGARH J N, MASUNAGA S . Progress and perspective of perfluorinated compound risk assessment and management in various countries and institutes[J]. Clean Technologiesand Environmental Policy, 2012,14(1):9-20.
[12]	BOTS J, BRUYN L D, SNIJKERS T , et al. Exposure to perfluorooctane sulfonic acid(PFOS) adversely affects the life-cycle of the damselfly enallagma cyathigerum[J]. Environmental Pollution, 2010,158(3):901-905. doi: 10.1016/j.envpol.2009.09.016 pmid: 19811863
[13]	JI K, KIM Y, OH S , et al. Toxicity of perfluorooctane sulfonic acid and perfluorooctanoic acid on freshwater macroinvertebrates(daphnia magna and moina macrocopa)and fish(oryzias latipes)[J]. Environmental Toxicology and Chemistry, 2008,27(10):2159-2168. doi: 10.1897/07-523.1 pmid: 18593212
[14]	张亚辉, 曹莹, 周腾耀 , 等. 我国环境中PFOS的预测无效应浓度[J]. 中国环境科学, 2013,33(9):1392-1398. ZHANG Y H, CAO Y, ZHOU T Y , et al. Predicted non-effect concentrations for PFOS of environment in China[J]. China Environmental Science, 2013,33(9):1392-1398.
[15]	曹莹, 周腾耀, 刘秀华 , 等. 我国环境中PFOA的预测无效应浓度推导[J]. 环境化学, 2013,32(7):1180-1187. CAO Y, ZHOU T Y, LIU X H , et al. Predicted non-effect concentrations of perfluorooctanoic acid(PFOA) in the environment of China[J]. Enivironmental Chemistry, 2013,32(7):1180-1187.
[16]	van der PUTTE I, MURIN M, van VELTHOVEN M , et al. Analysis of the risks arising from the industrial use of perfuorooctanoic acid(PFOA)and ammonium perfluorooctanoate (APFO) and from their use in consumer articles[R]. Delft:RPS Advies, 2010.
[17]	COLOMBO I, WOLF W D, THOMPSON R S , et al. Acute and chronic aquatic toxicity of ammonium perfluorooctanoate(APFO) to freshwater organisms[J]. Ecotoxicology and Environmental Safety, 2008,71(3):749-756. doi: 10.1016/j.ecoenv.2008.04.002 pmid: 18538392
[18]	Norwegian Pollution Control Authority. Screening of polyfluorinated organic compounds at four fire training facilities in norway[R]. Oslo:Norwegian Pollution Control Authority, 2008.
[19]	JIN Y H, LIU W, SATO I , et al. PFOS and PFOA in environmental and tap water in China[J]. Chemosphere, 2009,77(5):605-611. doi: 10.1016/j.chemosphere.2009.08.058 pmid: 19775722
[20]	YANG L P, ZHU L Y, LIU Z T , et al. Occurrence and partition of perfluorinated compounds in water and sediment from Liao River and Taihu Lake,China[J]. Chemosphere, 2011,83(6):806-814. doi: 10.1016/j.chemosphere.2011.02.075 pmid: 21435686
[21]	ZHAO L X, ZHU L Y, YANG L P , et al. Distribution and desorption of perfluorinated compounds in fractionated sediments[J]. Chemosphere, 2012,88(11):1390-1397. doi: 10.1016/j.chemosphere.2012.05.062 pmid: 22704205
[22]	SHAN G Q, WEI M C, LIU Z T , et al. Concentration profiles and spatial distribution of perfluoroalkyl substances in an industrial center with condensed fluorochemical facilities[J]. Science of the Total Environment, 2014,490:351-359. doi: 10.1016/j.scitotenv.2014.05.005 pmid: 24867700
[23]	魏明翠, 钟文珏, 赵丽霞 . 南方某氟化学工业园周围环境中全氟化合物的分布研究[J]. 环境科学学报, 2013,33(7):1989-1995. WEI M C, ZHONG W J, ZHAO L X . Distribution and profile of perfluorinated compounds in the environment around a fluorine chemistryindustrial park in South China[J]. Acta Scientiae Circumstantiae, 2013,33(7):1989-1995.
[24]	OSPAR Commission. Perfluorooctane sulphonate (PFOS):hazardous substances series[R]. [2016-04-13]. .
[25]	ROSTKOWSKI P, YAMASHITA N, SO I M K , et al. Perfluorinated compounds in streams of the Shihwa industrial zone and Lake Shihwa,South Korea[J]. Environmental Toxicology and Chemistry, 2006,25(9):2374-2380. doi: 10.1897/05-627r.1 pmid: 16986792
[26]	张亚辉, 曹莹, 覃璐玫 , 等. PFOS对太湖水体中典型鱼和食鱼鸟的次生毒性风险[J]. 环境科学学报, 2014,34(10):2718-2723. ZHANG Y H, CAO Y, QIN L M , et al. Secondary poisoning risk of PFOS for typical fish and fish-eating bird in Taihu Lake[J]. Acta Scientiae Circumstantiae, 2014,34(10):2718-2723.
[27]	US EPA . Revised draft hazard assessment of perfluorooctanoic acid and its salts[R].Washington DC:US Environmental Protection Agency. Office of Pollution Prevention and Toxics Risk Assessment Division, 2002.
[28]	US EPA . Draft risk assessment of the potential human health effects associated with exposure to perfluorooctanoic acid and its salts[R].Washington DC:US Environmental Protection Agency. Office of Pollution Prevention and Toxics Risk Assessment Division, 2005.
[29]	GIESY J P, NAILE J E, KHIM J S , et al. Aquatic toxicology of perfluorinated chemicals[J]. Reviews of Environmental Contamination & Toxicology, 2010,202:1-52. doi: 10.1007/978-1-4419-1157-5_1 pmid: 19898760
[30]	HOKE R A, BOUCHELLE L D, FERRELL B D , et al. Comparative acute freshwater hazard assessment and preliminary PNEC development for eight fluorinated acids[J]. Chemosphere, 2012,87(7):725-733. doi: 10.1016/j.chemosphere.2011.12.066 pmid: 22280982
[31]	JEFFREY B . Surface water quality criterion for perfluorooctanoic acid[R]. Minnesota:Minnesota Pollution Control Agency, 2007.
[32]	Environment Canada, Health Canada . Screening assessment report:perfluorooctanoic acid,its salts,and its precursors[R]. Ottawa:Environment Canada,Health Canada, 2012.
[33]	CCME. Canadian environmental quality guidelines[R]. Winnipeg:Canadian Council of Ministers of the Environment, 1999.
[34]	任东凯, 苏红巧, 刘芃岩 , 等. 全氟烷基磺酸盐(PFOS)及其替代品对两栖类胚胎的发育毒性[J]. 生态毒理学报, 2012,7(5):561-564. REN D K, SU H Q, LIU P Y , et al. Developmental toxicity of perfluorooctane sulfonate (PFOS) and its substitutes to amphibian embryos[J]. Asian Journal of Ecotoxicology, 2012,7(5):561-564.
[35]	王贺威, 马胜伟, 张喆 , 等. 全氟辛烷磺酸盐(PFOS)胁迫对翡翠贻贝抗氧化酶的影响[J]. 生态毒理学报, 2012,7(5):508-516. WANG H W, MA S W, ZHANG Z , et al. Effects of perfluorooctane sulfonate(PFOS) exposure on antioxidant enzymes of Perna viridis[J]. Asian Journal of Ecotoxicology, 2012,7(5):508-516.
[36]	苏红巧, 任东凯, 曹闪 , 等. 全氟辛烷磺酸盐(PFOS)及替代品对两栖类蝌蚪的急性毒性[J]. 生态毒理学报, 2012,7(5):521-524. SU H Q, REN D K, CAO S , et al. Acute toxicity of perfluorooctane sulfonate(PFOS) and its substitutes to Amphibian tadpoles[J]. Asian Journal of Ecotoxicology, 2012,7(5):521-524.
[37]	徐冬梅, 李婵丹, 王艳花 . 全氟辛酸(PFOA)对蚯蚓的毒性作用[J]. 生态毒理学报, 2012,7(5):532-536. XU D M, LI C D, WANG Y H . Toxicity of perfluorooctanoic acid to earthworms(Eisenia foetida)[J]. Asian Journal of Ecotoxicology, 2012,7(5):532-536.
[38]	徐冬梅, 文岳中, 李立 , 等. PFOS对蚯蚓急性毒性和回避行为的影响[J]. 应用生态学报, 2011,22(1):215-220. pmid: 21548311 XU D M, WEN Y Z, LI L , et al. Effects of perfluorooctane sulfonate on acute lethality and avoidance behavior of earthworm[J]. Chinese Journal of Applied Ecology, 2011,22(1):215-220. pmid: 21548311
[39]	林加华, 祝凌燕 . 全氟辛酸的污染状况及环境行为研究进展[J]. 应用生态学报, 2008,19(5):1149-1157. pmid: 18655607 LIN J H, ZHU L Y . Pollution trend and environmental behavior of perfluorooctanoic acid:a review[J]. Chinese Journal of Applied Ecology, 2008,19(5):1149-1157. pmid: 18655607
[40]	杨莉莉, 金芬, 李敏洁 , 等. 食品和食品包装材料中全氟化合物(PFCS)的研究进展[J]. 食品工业科技, 2014,35(8):367-372. YANG L L, JIN F, LI M J , et al. Research progress in advance of perfluorochemicals in food[J]. Science and Technology of Food Industry, 2014,35(8):367-372.
[41]	梅胜放 . 我国PFOS/PFOA的生产,应用以及国内外标准现状[J]. 有机氟工业, 2008(1):21-25.
[42]	UNECE. Overview of existing information on PFOS production, use, emissions and pathways to the environment and cost∕benefits with alternatives∕substitutes[EB∕OL].( 2006-01-25). .
[43]	US EPA. Perfluoroalkyl sulfonates,significant new use rule,final and supplemental proposed rule:Federal register 67[EB∕OL]. (2002-03-11). .
[44]	UNEP. 2010/15 PFOA stewardship program:overview and update[EB/OL]. (2009-02-12). .
[45]	张轩, 张偲, 王光鹏 , 等. 全氟辛烷磺酸盐(PFOS)对土壤跳虫的生态毒性[J]. 生态毒理学报, 2012,7(5):525-529. ZHANG X, ZHANG C, WANG G P , et al. Ecotoxicity of perfluorooctane sulfonate (PFOS) to springtails in soils[J]. Asian Journal of Ecotoxicology, 2012,7(5):525-529.