体相纳米气泡的消除与尺寸调控研究进展

张睿毅; 陈岚; 葛广路

doi:10.12153/j.issn.1674-991X.20210853

体相纳米气泡的消除与尺寸调控研究进展

doi: 10.12153/j.issn.1674-991X.20210853

张睿毅^{1, 2,},
陈岚^1, ,,
葛广路^1, ,

1.
中国科学院纳米标准与检测重点实验室, 中国科学院纳米科学卓越创新中心, 国家纳米科学中心
2.
中国科学院大学

基金项目: 中国科学院战略性先导科技专项（B类）（XDB36000000）

详细信息

作者简介:
张睿毅（1998—），男，博士研究生，主要从事纳米材料界面物理化学性质的研究，zhangry2018@nanoctr.cn

通讯作者:
陈岚（1974—），男，博士，研究员，主要从事纳米材料界面物理化学性质的研究，chenlan@nanoctr.cn

葛广路（1970—），男，博士，研究员，主要从事纳米标准测试方法研究，gegl@nanoctr.cn

中图分类号: X52,O35
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出版历程
- 收稿日期: 2021-12-22

Research progress on elimination and size control of bulk nanobubbles

ZHANG Ruiyi^{1, 2
,},
CHEN Lan^{1
, ,},
GE Guanglu^{1
, ,}

1.
CAS Key Laboratory of Standardization and Measurement for Nanotechnology, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology
2.
University of Chinese Academy of Sciences

摘要

摘要:
不同方法发生的体相纳米气泡尺寸与数量浓度相差悬殊。气泡尺寸的多分散性及数量浓度的本征差异性给体相纳米气泡的性能研究及效能比较带来了不便，同时也不利于纳米气泡技术的标准化、产业化。因此，体相纳米气泡尺寸及数量浓度的调控十分重要。对近年来体相纳米气泡尺寸和数量浓度的调控技术进行了总结及综合评估。主要分析对比了循环均化法、微流控技术和膜技术等尺寸调控方法与冻融去除法、超声消减法等数量浓度调控方法的优劣，从可调控性、设备依赖性、工艺难易度、可拓展性及成本等方面对各方法进行了评估，并结合本课题组已发表研究成果对体相纳米气泡的尺寸和数量浓度调控提出新的认识与思路，以期为深入了解纳米气泡的尺寸效应和超常稳定机制以及体相纳米气泡定量分析与应用，特别是与尺寸相关的性质、效应和应用提供新思考。
- 体相纳米气泡 /
- 发生方法 /
- 气泡消除 /
- 尺寸调控 /
- 尺寸效应
Abstract:
There are various bubble generation methods which can produce bulk nanobubbles with different sizes and different number concentrations. However, the polydispersity of bubble size and the intrinsic difference of number concentration are inconvenient to the performance research and efficiency comparison of bulk nanobubbles, and it is also not conducive to the standardization and industrialization of nanobubble technology. Therefore, the size control and number concentration adjustment for the bulk nanobubbles are very important. The technologies for controlling the size and number concentration of the bulk nanobubbles in recent years were summarized and comprehensively evaluated. The advantages and disadvantages of size control methods such as cyclic homogenization, microfluidic technology and membrane technology, and number concentration control methods such as freeze-thaw removal method and ultrasonication reduction method were analyzed and compared. All methods were evaluated in terms of controllability, equipment dependence, process difficulty, scalability and cost, and new understandings and ideas for the regulation of nanobubble size and concentration were proposed combined with the published research results. It helped to deeply understand the size effect of the nanobubbles and extra stabilization mechanism and provide new ideas for the quantitative analysis and applications of bulk nanobubbles, especially for the nanobubble size-related properties, effects and applications.
- bulk nanobubbles /
- generation method /
- bubble elimination /
- size control /
- size effect

HTML全文

图 1 冻融前后纳米气泡数量浓度的变化^[10]

Figure 1. Change of number concentration of the nanobubbles before and after freezing and thawing

下载: 全尺寸图片幻灯片

图 2 纳米气泡的超声消减

Figure 2. Ultrasonic elimination of nanobubbles

下载: 全尺寸图片幻灯片

图 3 文丘里型水动力空化装置中通过循环使纳米气泡尺寸均化^[38]

Figure 3. The size homogenization of the nanobubbles by circulation through Venturi-type hydrodynamic cavitation device

下载: 全尺寸图片幻灯片

图 4 通过微流控技术发生纳米气泡示意^[47]

Figure 4. Schematic for the nanobubbles generated by microfluidic technology

下载: 全尺寸图片幻灯片

图 5 使用多孔膜发生纳米气泡及孔尺寸对气泡粒径的影响

Figure 5. Generation of nanobubbles using porous membranes and the influence of the pore size on the nanobubbles size

下载: 全尺寸图片幻灯片

图 6 使用多孔氧化铝生成体相纳米气泡的示意及气泡尺寸分布^[9]

Figure 6. Schematic for the bulk nanobubbles generated by porous alumina and their bubble size distributions

下载: 全尺寸图片幻灯片

图 7 纳米气泡的尺寸调控与数量浓度调控技术综合评估结果

Figure 7. Comprehensive evaluation results on the size and concentration control methods for bulk nanobubbles.

下载: 全尺寸图片幻灯片

表 1 体相纳米气泡尺寸和数量浓度调控方法分类

Table 1. Classification of bulk nanobubbles size and number concentration control methods

调控参数	一次调控方法	二次调控方法
尺寸	循环均化法^[38-39,45]、微流控技术^[36,47-48]、膜技术^[6-9]	膜技术^[49]
数量浓度	循环均化法^[46]	超声消减法^[41-42]、超速离心法和冻融去除法^[10]

下载: 导出CSV

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