金属表面处理工艺危险废物产生节点和处置现状

刘婷婷; 赵彤; 王健; 黄泽春; 傅海辉

doi:10.12153/j.issn.1674-991X.20210082

金属表面处理工艺危险废物产生节点和处置现状

doi: 10.12153/j.issn.1674-991X.20210082

刘婷婷^1,2,,
赵彤^1,2,
王健^1,2,
黄泽春^1,2,
傅海辉^1,2,*, ,

1.
环境基准与风险评估国家重点实验室,中国环境科学研究院
2.
国家环境保护危险废物鉴别与风险控制重点实验室,中国环境科学研究院

详细信息

作者简介:
刘婷婷(1989—),女,助理研究员,博士,主要从事固体废物管理及风险管控研究, liutt@craes.org.cn

通讯作者:
傅海辉 E-mail: fu_haihui123@126.com

中图分类号: X705
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- 被引次数: 0
出版历程
- 收稿日期: 2021-03-23
- 刊出日期: 2021-09-20

Generation nodes and disposal status of hazardous wastes from metal surface treatment process

Tingting LIU^{1,2
,},
Tong ZHAO^1,2,
Jian WANG^1,2,
Zechun HUANG^1,2,
Haihui FU^{1,2,*
, ,}

1.
State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Research Academy of Environmental Sciences
2.
State Environmental Protection Key Laboratory of Hazardous Waste Identification and Risk Control, Chinese Research Academy of Environmental Sciences

More Information

Corresponding author: Haihui FU E-mail: fu_haihui123@126.com

摘要

摘要: 金属表面处理行业危险废物种类多、危害大,加上生产企业对危险废物产生节点识别不清以及危险废物管理意识薄弱,加剧了金属表面处理行业危险废物的管理难度。选取金属表面处理工艺中应用最为广泛的电镀、化学镀、阳极氧化、磷化和钝化处理工艺,通过工艺流程梳理,结合《国家危险废物名录(2021版)》,分析各工艺的危险废物产生节点、产生特点和规律;调研其中主要危险废物的产生量、处置工艺和处置现状,并对未来金属表面处理工艺危险废物的管理和处置工作提出合理建议。研究结果对实现金属表面处理行业危险废物的源头减量化和无害化处置具有重要的借鉴意义。
- 金属表面处理 /
- 危险废物 /
- 电镀 /
- 阳极氧化 /
- 化学镀 /
- 磷化 /
- 钝化
Abstract: It is difficult to manage hazardous wastes in the metal surface treatment industry because of the wide variety of hazardous wastes, the great hazards, the unclear identification of hazardous waste production nodes and the weak awareness of hazardous waste management in the production enterprises. The most used technologies including electroplating, electroless plating, anodic oxidation, phosphating, and passivation processes were selectedand analyzed. By combing the process flow and comparing with National Hazardous Waste List (version 2021), the production nodes, characteristics, and rules of hazardous waste in each process were analyzed. In addition, the generation, disposal process and disposal status of main hazardous wastes were investigated, and reasonable suggestions were put forward for the management and disposal of hazardous wastes in metal surface treatment process in the future. The research results had important reference significance for the realization of source reduction and harmless disposal of hazardous wastes in metal surface treatment industry.
- metal surface treatment /
- hazardous waste /
- electroplating /
- anodic oxidation /
- electroless plating /
- phosphating /
- passivation

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参考文献(25)

[1]	苗景国. 金属表面处理技术[M]. 北京: 机械工业出版社, 2018.
[2]	张宇婷, 朱国强, 崔芙红. 表面处理技术的种类和发展[J]. 化工管理, 2019(31):4-5.
[3]	LIU J, ZHANG X H, TRAN H, et al. Heavy metal contamination and risk assessment in water,paddy soil,and rice around an electroplating plant[J]. Environmental Science and Pollution Research, 2011, 18(9):1623-1632. doi: 10.1007/s11356-011-0523-3
[4]	赖柳锋. 浅谈电镀工艺的发展[J]. 当代化工研究, 2017(5):101-102. LAI L F. Discussion of the electroplating technology development[J]. Modern Chemical Research, 2017(5):101-102.
[5]	冯立明. 电镀工艺与设备[M]. 北京: 化学工业出版社, 2005.
[6]	国家危险废物名录(生态环境部令第15号)[A/OL]. [2020-11-27]. http://www.mee.gov.cn/xxgk2018/xxgk/xxgk02/202011/t20201127_810202.html .
[7]	王克和. 电镀加工量与产生的废水量及废渣量之关系[J]. 电镀与精饰, 2010, 32(6):40-44. WANG K H. Relationship between amount of resultant waste water and waste sludge and processing amount in electroplating process[J]. Plating & Finishing, 2010, 32(6):40-44.
[8]	花莉, 党海迪, 张浏, 等. 巢湖流域电镀危险废物产污系数研究[J]. 电镀与涂饰, 2017, 36(13):715-719. HUA L, DANG H D, ZHANG L, et al. Study on pollutant-producing coefficient of hazardous waste discharged from electroplating industry in Chao Lake Basin[J]. Electroplating & Finishing, 2017, 36(13):715-719.
[9]	杨冠华, 王洪涛, 张鲲, 等. 施镀工艺对铝合金化学镀镍的影响[J]. 材料保护, 2020, 53(11):55-61. YANG G H, WANG H T, ZHANG K, et al. Effect of plating process on electroless nickel plating of aluminum alloy[J]. Materials Protection, 2020, 53(11):55-61.
[10]	徐捷. 镁和镁合金的阳极氧化膜染色[J]. 染料与染色, 2020, 57(5):13-26. XU J. Anodized film dyeing of magnesium and magnesium alloy[J]. Dyestuffs and Coloration, 2020, 57(5):13-26.
[11]	张伟华, 衣淑丽, 张颖超. 碳钢常温磷化工艺及磷化膜性能的研究[J]. 化工管理, 2020(25):169-170.
[12]	叶永梅, 蔡河山, 徐颂. 金属表面处理类项目环境影响评价实例分析[J]. 广东化工, 2015, 42(3):105-106. YE Y M, CAI H S, XU S. Analysis of the example project environmental impact evaluation of surface treatment of metals[J]. Guangdong Chemical Industry, 2015, 42(3):105-106.
[13]	王佳莹. 铝合金金属阳极氧化废水处理改造项目案例分析[J]. 工程建设与设计, 2017(4):125-126. WANG J Y. Case study on the treatment of aluminum anodic oxidation wastewater[J]. Construction & Design for Engineering, 2017(4):125-126.
[14]	景媛, 杨荣, 宋振华, 等. 电镀锌三价铬黑色钝化及其耐蚀性[J]. 电镀与涂饰, 2019, 38(19):1045-1050. JING Y, YANG R, SONG Z H, et al. Black trivalent chromium passivation of electroplated zinc coating and its corrosion resistance[J]. Electroplating & Finishing, 2019, 38(19):1045-1050.
[15]	郭瑞, 矫云阳, 杨强威, 等. 我国电镀行业危险废物环境管理对策[J]. 环境与可持续发展, 2020, 45(3):112-115. GUO R, JIAO Y Y, YANG Q W, et al. Environmental management of hazardous waste of electroplating industry in China[J]. Environment and Sustainable Development, 2020, 45(3):112-115.
[16]	陈昊, 叶飞, 李兵, 等. 江苏省表面处理行业废酸处置利用现状及其问题分析[J]. 环境工程技术学报, 2017, 7(6):718-725. CHEN H, YE F, LI B, et al. Waste acid disposal and utilization status and existing problems of surface treatment industry in Jiangsu Province[J]. Journal of Environmental Engineering Technology, 2017, 7(6):718-725.
[17]	ESPINOSA D C R, TENORIO J A S. Thermal behavior of chromium electroplating sludge[J]. Waste Management, 2001, 21(4):405-410. doi: 10.1016/S0956-053X(00)00056-8
[18]	张仲仪. 电镀工业园区危险废物的回收与处置[J]. 电镀与精饰, 2009, 31(8):40-42. ZHANG Z Y. Hazardous wastes recovery and disposal for electroplating industry district[J]. Plating & Finishing, 2009, 31(8):40-42.
[19]	余昭辉, 康宇洁, 张亚甜, 等. 机械工业工艺危险废物的来源和处置技术研究[J]. 当代化工研究, 2019(10):148-149. YU Z H, KANG Y J, ZHANG Y T, et al. Study on the source and disposal technology of process hazardous waste in machinery industry[J]. Modern Chemical Research, 2019(10):148-149.
[20]	ZHANG M T, CHEN C, MAO L Q, et al. Use of electroplating sludge in production of fired clay bricks:characterization and environmental risk evaluation[J]. Construction and Building Materials, 2018, 159:27-36. doi: 10.1016/j.conbuildmat.2017.10.130
[21]	杨晓冰. 西安市金属表面处理行业现状调查与环保对策研究[D]. 西安: 西安建筑科技大学, 2011.
[22]	JAMES M G, BEATTIE J K, KENNEDY B J. Recovery of chromate from electroplating sludge[J]. Waste Management and Research, 2000, 18(4):380-385. doi: 10.1177/0734242X0001800410
[23]	张焕然, 王俊娥. 电镀污泥资源化利用及处置技术进展[J]. 矿产保护与利用, 2016(3):73-78. ZHANG H R, WANG J E. Status of resource utilization and disposal technology of electroplating sludge[J]. Conservation and Utilization of Mineral Resources, 2016(3):73-78.
[24]	张滨, 韩文爱, 王占文, 等. 电镀酸洗液资源化的中试研究[J]. 石家庄职业技术学院学报, 2015, 27(2):49-51.
[25]	AGRAWAL A, SAHU K K. An overview of the recovery of acid from spent acidic solutions from steel and electroplating industries[J]. Journal of Hazardous Materials, 2009, 171(1/2/3):61-75. doi: 10.1016/j.jhazmat.2009.06.099