Screening and identification of priority control chemicals based on the comprehensive evaluation of hazards: taking a city in the south as an example
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摘要: 基于层次分析法,构建了包含化学品毒性效应和环境效应2类危害性影响因素、共8项指标的化学品危害性综合评价体系;将该评价体系应用于南方某市优先控制化学品,梳理了该市相关法律法规、污染源普查数据和美国有毒物质数据库,对化学品的原辅材料及其实际使用情况进行分析,确定了优先控制化学品初选清单;对化学品危害性进行了计算,最终确定了环境管控风险值,从而筛选识别出该市优先控制化学品清单。结果表明,该市化学品初选清单共包括23种化学品,环境管控风险值较大的优先控制化学品包括十溴二苯醚、六溴环十二烷、壬基酚、短链氯化石蜡4种,主要涉及橡胶、塑料、纤维、电子产品、金属加工等行业或领域。建议针对该市优先控制化学品深入开展全生命周期环境影响评价,并将源头减量、过程控制和末端治理相结合,减少优先控制化学品的环境风险。Abstract: A comprehensive evaluation system of chemical hazard including 2 hazardous influencing factors, i.e. toxic effects and environmental effects, and 8 indicators was constructed based on the analytic hierarchy process. This evaluation system was applied to the priority control chemicals of a city in southern China. The relevant laws and regulations of the city, US toxic substance database and pollution source survey data were sorted out. The raw and auxiliary materials of chemicals and their actual use were analyzed. And the primary list of priority control chemicals was determined. The calculation of the hazards of chemicals was carried out, and the environmental priority control risk values were finally determined, so as to screen and identify the city’s priority control chemical list. The results showed that there were 23 chemicals in the primary list of chemicals in the city, and the chemicals with higher risk values for environmental priority control were decabromodiphenyl ether, hexabromocyclododecane, nonylphenol, and short-chain chlorinated paraffins, which were mainly involved in rubber, plastics, fiber, electronic products, metal processing and other industries or fields. It was recommended to conduct an in-depth full life cycle environmental impact assessment for the city’s priority chemicals, and combine source reduction, process control and end treatment to reduce the environmental risks of priority chemicals.
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[1] 环境保护部, 工业和信息化部, 国家卫生和计划生育委员会. 关于发布《优先控制化学品名录(第一批)》的公告:公告2017年第83号[A/OL].( 2017-12-29)[2020-06-15]. http://www.mee.gov.cn/gkml/hbb/bgg/201712/t20171229_428832.htm. [2] 刘叶新, 周志洪, 区晖, 等. 珠江广州河段沉积物中典型抗生素的污染特征[J]. 华南师范大学学报(自然科学版), 2018, 50(4):48-54.LIU Y X, ZHOU Z H, OU H, et al. Occurrence of typical antibiotics in sediments of Guangzhou section of the Pearl River[J]. Journal of South China Normal University (Natural Science Edition), 2018, 50(4):48-54. [3] LIU A F, SHI J B, QU G B, et al. Identification of emerging brominated chemicals as the transformation products of tetrabromobisphenol A (TBBPA) derivatives in soil[J]. Environmental Science & Technology, 2017, 51(10):5434-5444.
doi: 10.1021/acs.est.7b01071[4] SHI Z X, ZHANG L, ZHAO Y F, et al. A national survey of tetrabromobisphenol-A,hexabromocyclododecane and decabrominated diphenyl ether in human milk from China:occurrence and exposure assessment[J]. Science of the Total Environment, 2017, 599/600:237-245.
doi: 10.1016/j.scitotenv.2017.04.237[5] ZHANG Q Q, ZHAO J L, YING G G, et al. Emission estimation and multimedia fate modeling of seven steroids at the river basin scale in China[J]. Environmental Science & Technology, 2014, 48(14):7982-7992.
doi: 10.1021/es501226h[6] 严清, 张怡昕, 高旭, 等. 典型医药活性物质在污水处理厂中的归趋及其风险评估[J]. 中国环境科学, 2014, 34(3):672-680.YAN Q, ZHANG Y X, GAO X, et al. Fate of pharmaceutically active compounds in a municipal wastewater treatment plantand risk assessment[J]. China Environmental Science, 2014, 34(3):672-680. [7] MAITI S, SINHA S S, SINGH M. Microbial decolorization and detoxification of emerging environmental pollutant:cosmetic hair dyes[J]. Journal of Hazardous Materials, 2017, 338:356-363.
doi: 10.1016/j.jhazmat.2017.05.034[8] 邓洋慧. 太湖流域典型新兴污染物污染特征及风险评价[D]. 南昌:南昌大学, 2020. [9] TLILI A, CORCOLL N, ARRHENIUS Å, et al. Tolerance patterns in stream biofilms link complex chemical pollution to ecological impacts[J]. Environmental Science & Technology, 2020, 54(17):10745-10753.
doi: 10.1021/acs.est.0c02975[11] KHAN F I, SADIQ R. Risk-based prioritization of air pollution monitoring using fuzzy synthetic evaluation technique[J]. Environmental Monitoring and Assessment, 2005, 105(1/2/3):261-283.
doi: 10.1007/s10661-005-3852-1[12] 李沫蕊, 王韦舒, 任姝娟, 等. 运用改进综合评分法筛选典型污染物的研究:以大武水源地地下水典型污染物筛选为例[J]. 环境污染与防治, 2014, 36(11):72-77.LI M R, WANG W S, REN S J, et al. Screening typical pollutants by modified comprehensive evaluation method:a case study of typical pollutants screening in groundwater of Dawu water source[J]. Environmental Pollution & Control, 2014, 36(11):72-77. [13] KANG S M. A sensitivity analysis of the Korean composite environmental index[J]. Ecological Economics, 2002, 43(2/3):159-174.
doi: 10.1016/S0921-8009(02)00207-0[14] CHIANG C M, LAI C M. A study on the comprehensive indicator of indoor environment assessment for occupants’ health in Taiwan[J]. Building and Environment, 2002, 37(4):387-392.
doi: 10.1016/S0360-1323(01)00034-8[15] AMENTA P, LUCADAMO A, MARCARELLI G. On the choice of weights for aggregating judgments in non-negotiable AHP group decision making[J]. European Journal of Operational Research, 2021, 288(1):294-301.
doi: 10.1016/j.ejor.2020.05.048[16] National Library of Medicine.Explore chemistry[EB/OL].[2020-06-15]. https://pubchem.ncbi.nlm.nih.gov/. [17] 生态环境部. 国家危险废物名录(修订稿)[A/OL].( 2019-09-05)[2020-06-15]. http://www.mee.gov.cn/xxgk2018/xxgk/xxgk06/201909/t20190910_733172.html. [18] HE K, BORTHWICK A G, LIN Y C, et al. Sale-based estimation of pharmaceutical concentrations and associated environmental risk in the Japanese wastewater system[J]. Environment International, 2020, 139:105690.
doi: 10.1016/j.envint.2020.105690[19] 陈旭雯, 黄蕾, 袁增伟. 化工园企业环境风险分级评估与管理方法研究[J]. 环境保护科学, 2015, 41(3):144-148.CHEN X W, HUANG L, YUAN Z W. Assessment and management of enterprise environment risk ranking in chemical industrial park[J]. Environmental Protection Science, 2015, 41(3):144-148.
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