二氧化碳转化制取燃料及高值化学品研究进展

王瑞; 许义榕; 孟渴欣; 唐伟; 杨紫怡; 王雯

doi:10.12153/j.issn.1674-991X.20190179

二氧化碳转化制取燃料及高值化学品研究进展

doi: 10.12153/j.issn.1674-991X.20190179

北京化工大学生物质能源与环境工程研究中心

详细信息

作者简介:
王瑞(1999—),女,研究方向为CO₂的资源化利用,wangrui_buct@163.com

通讯作者:
王雯 E-mail: wangwen@mail.buct.edu.cn

中图分类号: X131
计量
- 文章访问数: 555
- HTML全文浏览量: 132
- PDF下载量: 161
- 被引次数: 0
出版历程
- 收稿日期: 2019-10-22
- 刊出日期: 2020-07-20

Development of research on the conversion of carbon dioxide into fuel and high value-added products

Biomass Energy and Environmental Engineering Research Center, Beijing University of Chemical Technology

More Information

Corresponding author: WANG Wen E-mail: wangwen@mail.buct.edu.cn

摘要

摘要: 二氧化碳(CO₂)的捕集及转化技术可将CO₂转化为清洁燃料和高值化学品,是未来缓解能源问题的有效途径之一。基于CO₂的转化机理,结合近几年CO₂转化技术的发展,重点介绍了催化转化、电化学还原、光化学转化、光电催化转化及生物转化技术制备CH₃OH、HCOOH、C₂H₆O、CH₃COOH等一系列高值化学品的研究进展;基于现有技术,通过进一步开发利用新型催化剂,培育优化具有CO₂转化功能的微生物等手段,将CO₂转化技术与多领域技术相结合发展,可为CO₂转化技术的大规模工业化生产及实际应用打下坚实的基础。
- 二氧化碳(CO₂) /
- 高值化学品 /
- 生物转化技术
Abstract: Carbon dioxide(CO₂) can be converted into clean fuel and high value-added products by CO₂ capture and conversion technology, which is one of the effective ways to alleviate energy problems in the future. According to the mechanism of CO₂ conversion, combined with the development of CO₂conversion technology in recent years, the research progress of the preparation of a series of high value-added products, such as methanol, formic acid, ethanol and acetic acid, by catalytic conversion technology, electrochemical reduction technology, photochemical conversion technology, photoelectric catalytic conversion technology and biological conversion technology were mainly introduced. Based on the existing technology, the CO₂ conversion technology would be further developed in combination with many fields such as development of new catalysts, and cultivation and optimization of microorganisms with the function of CO₂ conversion, which could play a solid foundation for large-scale industrial production and practical application of CO₂ conversion technology.
- carbon dioxide(CO₂) /
- high value-added product /
- bioconversion technology

HTML全文

参考文献(56)

[1]	ARESTA M, DIBENEDETTO A, ANGELINI A. Catalysis for the valorization of exhaust carbon:from CO₂ to chemicals,materials,and fuels:technological use of CO₂[J]. Chemical Reviews, 2014,114(3):1709-1742. doi: 10.1021/cr4002758 pmid: 24313306
[2]	关毅. 2017年大气碳水平达80万年以来最高[J]. 自然杂志, 2018,40(5):54.
[3]	王丽敏, 苏连江. 自然科学基础:无机化学卷[M]. 哈尔滨: 哈尔滨地图出版社, 2004: 315.
[4]	张琪, 许武韬, 刘予宇, 等. 二氧化碳电化学还原概述[J]. 自然杂志, 2017,39(4):242-250. ZHANG Q, XU W T, LIU Y Y, et al. An overview of electrochemical reduction of carbon dioxide[J]. Chinese Journal of Nature, 2017,39(4):242-250.
[5]	METTE M, MIKKEL J, FREDERIK C K. The teraton challenge:a review of fixation and transformation of carbon dioxide[J]. Energy Environment Science, 2010,3(1):43-81. doi: 10.1039/B912904A
[6]	王伟建, 郑小慧, 晁会霞, 等. 二氧化碳利用新途径的研究进展评述[J]. 钦州学院学报, 2018,173(5):22-28. WANG W J, ZHENG X H, CHAO H X, et al. Review on the research progress of new approaches to the utilization of carbon dioxide[J]. Journal of Qinzhou University, 2018,173(5):22-28.
[7]	BONURA G, CORDARO M, CANNILLA C, et al. Catalytic behaviour of a bifunctional system for the one step synjournal of DME by CO₂ hydrogenation[J]. Catalysts, 2013,288:51-57.
[8]	GRACA I, GONZALEZ L V, BACARIZA M C, et al. CO₂ hydrogenation into CH₄ on NiHNaUSY zeolites[J]. Applied Catalysts, 2014,147:101-110.
[9]	邵怀启, 钟顺和, 郭俊宝. CO₂氧化丙烷脱氢制丙烯用Pd-Cu/V₂O₅-SiO₂催化剂的研究[J]. 催化学报, 2004,25(2):143-148. SHAO H Q, ZHONG S H, GUO J B. Pd-Cu/V2O5-SiO2 catalyst for propane oxidative dehydrogenation with CO2 to propylene[J]. Chinese Journal of Catalysis, 2004,25(2):143-148.
[10]	HUANG W, SUN W Z, LI F. Efficient synjournal of ethanol and acetic acid from methane and carbon dioxide with a continuous,stepwise reactor[J]. American Institute of Chemical Engineers Journal, 2010,56(5):1279-1284.
[11]	BARROS B S, MELO D M, LIBS S, et al. CO₂ reforming of methane over La₂NiO₄/α-Al₂O₃ prepared by microwave assisted self-combustion method[J]. Applied Catalysis A:General, 2010,378(1):69-75. doi: 10.1016/j.apcata.2010.02.001
[12]	BOOGAERTS I, NOLAN S P. Carboxylation of C—H bonds using N-het-erocyclic carbene gold(Ⅰ) complexes[J]. Journal of American Chemical Society, 2010,132(26):8858-8859. doi: 10.1021/ja103429q
[13]	ROSEN B A, SALEHI K A, THORSON M R, et al. Ionic liquid-mediated selective conversion of CO₂ to CO at low overpotentials[J]. Science, 2011,334:643-644. doi: 10.1126/science.1209786 pmid: 21960532
[14]	QIAO J, LIU Y, HONG F, et al. A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels[J]. Chemical Society Reviews, 2014,43(2):631. doi: 10.1039/c3cs60323g pmid: 24186433
[15]	AYD N R, DO A, HULVA Z, et al. Electrochemical reduction of carbondioxide on polypyrrole coated copper electro-catalyst under ambient and high pressure in methanol[J]. Applied Catalysis B:Environmental, 2013,140/141:478.
[16]	LAWRENCE Y S L, WONG K Y. Electrocatalytic reduction of carbon dioxide[J]. Chemistry, 2017,3(5):717-718.
[17]	蒋永, 苏敏, 张尧, 等. 生物电化学系统还原二氧化碳同时合成甲烷和乙酸[J]. 应用与环境生物学报, 2013,19(5):833-837. doi: 10.3724/SP.J.1145.2013.00833 JIANG Y, SU M, ZHANG Y, et al. Simultaneous production of methane and acetate from carbon dioxide with bioelectrochemical systems[J]. Chinese Journal of Applied and Environmental Biology, 2013,19(5):833-837. doi: 10.3724/SP.J.1145.2013.00833
[18]	MARTINDALE B C M, COMPTON R G. Formic acid electro-synjournal from carbon dioxide in a room temperature ionic liquid[J]. Chemical Communications, 2012,48(52):6487. pmid: 22622393
[19]	郑宁来. 二氧化碳一步转化为甲酸和乙醇[J]. 合成技术及应用, 2017(4):58. ZHENG N L. Content control of iso-phthalic acid during bottle PET chips producing[J]. Synthetic Technology & Application, 2017(4):58.
[20]	WEI J, GE Q J, YAO R W, et al. Directly converting CO₂ into a gasoline fuel[J].Nature Communictions, 2017(8):151.
[21]	AZIZ M A A, JALIL A A, TRIWABYONO S, et a1. CO₂ methanation over heterogeneous catalysts:recent progress and future prospects[J]. Green Chemistry, 2015,17:2647-2663. doi: 10.1039/C5GC00119F
[22]	AGARWAL A S, ZHAI Y, HILL D, et al. The electrochemical reduction of carbon dioxide to formate/formic acid:engineering and economic feasibility[J]. ChemSusChem, 2011,4(9):1301-1310. pmid: 21922681
[23]	张现萍, 黄海燕, 靳红利. 水溶液中电化学还原CO₂的研究进展[J]. 化工进展, 2015,34(12):4139-4144. doi: 10.16085/j.issn.1000-6613.2015.12.002 ZHANG X P, HUANG H Y, JIN H L. Research progress of electrochemical reduction of CO2 in aqueous solution[J]. Chemical Progress, 2015,34(12):4139-4144. doi: 10.16085/j.issn.1000-6613.2015.12.002
[24]	ZHANG S J, HUO F. Angstrom science:exploring aggregates from a new viewpoint[J]. Green Energy & Environment, 2016(1):79-82.
[25]	TRAN N H, PHILIPPE S, GWENAELLE R, et al. Porous dendritic copper:an electrocatalyst for highly selective CO₂ reduction to formate in water/ionic liquid electrolyte[J]. Chemical Science, 2017,8(1):742-747. pmid: 28451222
[26]	LINGAMPALLI S R, AYYUB M M, RAO C N R. Recent progress in the photocatalytic reduction of carbon dioxide[J]. ACS Omega, 2017,2(6):2740-2748. doi: 10.1021/acsomega.7b00721 pmid: 31457612
[27]	INOUE T, FUJISHIMA A, KONISHI S, et al. Photoelectrocata-lytie reduetion of carbon dioxide in aqueous suspensions of semiconductor powders[J]. Nature, 1979,277:637-638. doi: 10.1038/277637a0
[28]	LONG R, LI Y, LIU Y, et al. Isolation of Cu atoms in Pd lattice:forming highly selective sites for photocatalytic conversion of CO₂ to CH₄[J]. Journal of the American Chemical Society, 2017,139(12):4486-4492. pmid: 28276680
[29]	WANG D F, TONG H, OUYANG S X, et al. Semiconductor-based artificial photosynjournal for conversion of carbon dioxide into hydrocarbon fuels[J]. Science, 2014(1):62-67. doi: 10.1007/BF02839314 pmid: 14663854
[30]	NEATU S, MACIA A J A, PATRICIA C, et al. Gold-copper nanoalloys supported on TiO₂ as photocatalysts for CO₂ reduction by water[J]. Journal of the American Chemical Society, 2014,136(45):15969-15976. doi: 10.1021/ja506433k pmid: 25329687
[31]	RAMSES S, ANNEMIE B. Plasma technology:a novel solution for CO₂ conversation[J]. Chemical Society Reviews, 2017,46(19):5805-5863. doi: 10.1039/c6cs00066e pmid: 28825736
[32]	WANG C, SUN Z, ZHENG Y, et al. Recent progress in visible light photocatalytic conversion of carbon dioxide[J]. Journal of Materials Chemistry A, 2019,136(45):847-862.
[33]	THOMPSON J F, CHEN B, KUBO M, et al. Artificial photosynjournal device development for CO₂ photoelectrochemical conversion[J].MRS Advance, 2016(6):447-452.
[34]	ONG W J, PUTRI L K, TAN Y C, et al. Unravelling charge carrier dynamics in protonated g-C₃N₄ interfaced with carbon nanodots as co-catalysts toward enhanced photocatalytic CO₂ reduction:a combined experimental and first-principles DFT study[J]. Nano Research, 2017,10(5):1673-1696. doi: 10.1007/s12274-016-1391-4
[35]	SHEN Q, CHEN Z, HUANG X, et al. High-yield and selective photoelectrocatalytic reduction of CO₂ to formate by metallic copper decorated Co₃O₄ nanotube arrays[J]. Environmental Science & Technology, 2015,49:5828-5835. doi: 10.1021/acs.est.5b00066 pmid: 25844931
[36]	IRTEM E, HERNANDEZ A. A photoelectrochemical flow cell design for the efficient CO₂ conversion to fuels[J]. Electrochimica Acta, 2017,240:225-230. doi: 10.1016/j.electacta.2017.04.072
[37]	JIANG M, WU H, LI Z, et al. Highly selective photoelectrochemical conversion of carbon dioxide to formic acid[J]. ACS Sustainable Chemistry & Engineering, 2018(1):82-87.
[38]	LI F, ZHANG L, TONG J, et al. Photocatalytic CO₂ conversion to methanol by Cu₂O/graphene/TNA heterostructure catalyst in a visible-light-driven dual-chamber reactor[J]. Nano Energy, 2016,27:320-329. doi: 10.1016/j.nanoen.2016.06.056
[39]	YUAN J, WANG X, GU C, et al. Photoelectrocatalytic reduction of carbon dioxide to methanol at cuprous oxide foam cathode[J]. RSC Advance, 2017,7:24933-24939. doi: 10.1039/C7RA03347H
[40]	YANG Z, WANG H, SONG W, et al. One dimensional SnO₂ NRs/Fe₂O₃ NTs with dual synergistic effects for photoelectrocatalytic reduction CO₂ into methanol[J]. Journal of Colloid and Interface Science, 2017,486:232-240. doi: 10.1016/j.jcis.2016.09.055 pmid: 27716463
[41]	KAYKOBADR K M, RUEY O H, HAMIDAH A, et al. Photoelectrochemical reduction of carbon dioxide to methanol on p-type CuFe₂O₄ under visible light irradiation[J]. International Journal of Hydrogen Energy, 2018,39(43):18185-18193.
[42]	YUAN J, XIAO B, HAO C. Photoelectrochemical reduction of carbon dioxide to ethanol at Cu₂O foam cathode[J]. International Journal of Electrochemical Science, 2017,12:8288-8294.
[43]	AMPELLI C, PASSALACQUA R, GENOVESE C, et al. A novel photo-electrochemical approach for the chemical recycling of carbon dioxide to fuels[J]. Chemical Engineering Transactions, 2011,25:683-688. doi: 10.3303/CET1125114
[44]	MARTIN M R, FORNERO J J, REBECCA S, et al. A single-culture bioprocess of Methanothermobacter thermautotrophicus to upgrade digester biogas by CO₂-to-CH₄ conversion with H₂[J]. International Microbiological Journal, 2013(7):157529.
[45]	BASSANI I, KOUGIAS P G, TREU L, et al. Biogas upgrading via hydrogenotrophic methanogenesis in two-stage continuous stirred tank reactors atmesophilic and thermophilic conditions[J]. Environmental Science & Technology, 2015,49(20):12585-12593. doi: 10.1021/acs.est.5b03451 pmid: 26390125
[46]	DEMLER M, WEUSTER B D. Reaction engineering analysis of hydrogenotrophic production of acetic acid by Acetobacterium woodii[J]. Biotechnology & Bioengineering, 2011,108(2):470-474. doi: 10.1002/bit.22935 pmid: 20830677
[47]	HU P, RISMANIYAZDI H, TEPHANOPOULOS G. Anaerobic CO₂ fixation by the acetogenic bacterium Moorella thermoacetica[J]. AIChE Journal, 2013,59(9):3176-3183. doi: 10.1002/aic.14127
[48]	FERNANDEZ N A, ABUBACKAR H N, VEIGA M C, et al. Production of chemicals from C1 gases (CO,CO₂) by Clostridium carboxidivorans[J]. World Journal of Microbiology and Biotechnology, 2017,33(3):43. doi: 10.1007/s11274-016-2188-z pmid: 28160118
[49]	TANNER R S, MILLER L M, YANG D C. Clostridium ljungdahlii sp.nov.,an acetogenic species in clostridial rRNA homology group Ⅰ[J]. International Journal of Systematic Bacteriology, 1993,43(2):232-236. doi: 10.1099/00207713-43-2-232 pmid: 7684239
[50]	GUNNARSSON I B, KARAKASHEV D, ANGELIDAKI I. Succinic acid production by fermentation of Jerusalem artichoke tuber hydrolysate with Actinobacillus succinogenes 130Z[J]. Industrial Crops & Products, 2014,62:125-129.
[51]	COK B, TSIROPOULOS I, ROES A L, et al. Succinic acid production derived from carbohydrates:an energy and greenhouse gas assessment of a platform chemical toward a bio-based economy[J]. Biofuels Bioproducts & Biorefining, 2014,8(1):16-29.
[52]	MUZUMDAR A V, PANGARKAR V G. Reduction of maleic acid to succinic acid on titanium cathode[J]. Organic Process Research & Development, 2004,8(4):685-688.
[53]	GUNNARSSON I B, ALVARADO M M, ANGELIDAKI I. Utilization of CO₂ fixating bacterium Actinobacillus succinogenes 130Z for simultaneous biogas upgrading and biosuccinic acid production[J]. Environmental Science & Technology, 2014,48(20):12464. doi: 10.1021/es504000h pmid: 25275929
[54]	陆小青. 藻类生物燃料的研究进展[J]. 城市道桥与防洪, 2012(6):393-398.
[55]	嵇磊, 张利雄, 姚志龙, 等. 利用藻类生物质制备生物燃料研究进展[J]. 石油学报(石油加工), 2007,23(6):1-5. JI L, ZHANG L X, YAO Z L, et al. Review on the progress of producing bio-fuel from microalgae[J]. Acta Petrolei Sinica(Petroleum Processing Section), 2007,23(6):1-5.
[56]	王键, 杨剑, 王中原, 等. 全球碳捕集与封存发展现状及未来趋势[J]. 环境工程, 2012,30(4):118-120. WANG J, YANG J, WANG Z Y, et al. The present status and future trends of global carbon capture and storage[J]. Environmental Engineering, 2012,30(4):118-120.