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水环境中污染物同位素溯源的研究进展

马文娟,  刘丹妮,  杨芳,  王鹤立,  王希欢,  李崇蔚,  廖海清

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文章导航 > 环境工程技术学报  > 2020 >  10(2): 242-250
马文娟, 刘丹妮, 杨芳, 王鹤立, 王希欢, 李崇蔚, 廖海清. 水环境中污染物同位素溯源的研究进展[J]. 环境工程技术学报, 2020, 10(2): 242-250. doi: 10.12153/j.issn.1674-991X.20190081
引用本文: 马文娟, 刘丹妮, 杨芳, 王鹤立, 王希欢, 李崇蔚, 廖海清. 水环境中污染物同位素溯源的研究进展[J]. 环境工程技术学报, 2020, 10(2): 242-250. doi: 10.12153/j.issn.1674-991X.20190081
shu
MA Wenjuan, LIU Danni, YANG Fang, WANG Heli, WANG Xihuan, LI Chongwei, LIAO Haiqing. Research progress in isotope methods for tracing contaminants in water environment[J]. Journal of Environmental Engineering Technology, 2020, 10(2): 242-250. doi: 10.12153/j.issn.1674-991X.20190081
Citation: MA Wenjuan, LIU Danni, YANG Fang, WANG Heli, WANG Xihuan, LI Chongwei, LIAO Haiqing. Research progress in isotope methods for tracing contaminants in water environment[J]. Journal of Environmental Engineering Technology, 2020, 10(2): 242-250. doi: 10.12153/j.issn.1674-991X.20190081
shu

水环境中污染物同位素溯源的研究进展

doi: 10.12153/j.issn.1674-991X.20190081

  • 1. 中国环境科学研究院流域水环境污染综合治理研究中心

  • 2. 中国地质大学(北京)水资源与环境学院

详细信息
    作者简介:

    马文娟(1995—),女,硕士研究生,主要研究方向为流域水污染源解析,mwj1550125@163.com。

    通讯作者:

    杨芳 E-mail: ffff.yyyy@sina.com

    廖海清 E-mail: liaohq@craes.org.cn

  • 中图分类号: X502

Research progress in isotope methods for tracing contaminants in water environment

  • 1. Watershed Water Environment Research Center, Chinese Research Academy of Environmental Sciences

  • 2. School of Water Resources and Environment, China University of Geosciences (Beijing)

More Information
    Corresponding author: YANG Fang E-mail: ffff.yyyy@sina.com; LIAO Haiqing E-mail: liaohq@craes.org.cn

    摘要
  • 摘要: 水环境中污染物的源辨识及污染过程控制是当前流域水污染治理的难题,利用同位素示踪技术对污染物来源及污染过程进行追踪是解决该问题的有效手段之一。综述了近几年同位素技术在国内外水环境污染源解析研究中的应用状况,简要介绍了同位素技术的基本原理与特点,重点总结了稳定同位素技术在示踪水环境中不同污染物及其迁移转化过程的研究进展;提出同位素示踪技术与传统水化学方法相比,有其独特的优势,但也存在一些不足,结合传统水化学分析和荧光光谱等技术,可提高同位素技术的示踪效率及环境友好程度;对同位素示踪技术的应用前景进行了展望。

     

    Abstract: The sources identification and pollution process control of contaminants in aquatic environment is still a challenge in watershed pollution management. Isotope technology for tracing pollutants sources and the pollution processes is one of the effective methods to solve this problem. The application situations of isotope technology in water pollution sources research at home and abroad in recent years were summarized. The basic principles and characteristics of isotope technology were introduced briefly. The research progresses in stable isotope technology for tracing different pollutants, as well as the corresponding migration and transformation processes in water environment were summarized. Compared with the traditional methods, e.g. hydrochemistry, it was proposed that isotope technology had its unique advantages, while limitations still existed. Combined with the traditional hydrochemistry and fluorescence spectroscopy, the efficiency and environmental friendliness of isotope technology could be greatly improved. The prospects for the application of isotope tracing technology in aquatic environment were carefully addressed.

     

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    • 参考文献(64)
  • [1] 潘金珠, 侯宪锋, 尤鸿 , 等. 水污染溯源方法分析[J]. 科技广场, 2014(9):10-13.

    PAN J Z, HOU X F, YOU H , et al. Analysis of source identification method for water pollution[J]. Science Mosaic, 2014(9):10-13.
    [2] 苏丹, 唐大元, 刘兰岚 , 等. 水环境污染源解析研究进展[J]. 生态环境学报, 2009,18(2):749-755.

    SU D, TANG D Y, LIU L L , et al. Reviews on source apportionment of pollutions in water environment[J]. Ecology and Environmental Sciences, 2009,18(2):749-755.
    [3] 陈丽, 钟欣平, 喻阳华 . 喀斯特区河流型水源地水化学分析[J]. 贵阳学院学报(自然科学版), 2019(1):58-64.

    CHEN L, ZHONG X P, YU Y H . Hydrochemical analysis of fluvial water source in karst area[J].Journal of Guiyang University(Natural Sciences), 2019(1):58-64.
    [4] GONZÁLEZ S O, ALMEIDA C A, CALDERÁN M , et al. Assessment of the water self-purification capacity on a river affected by organic pollution:application of chemometrics in spatial and temporal variations[J]. Environmental Science and Pollution Research, 2014,21(18):10583-10593.
    [5] SHARIFI S, HAGHSHENAS M M, DEKSISSA T , et al. Storm water pollution source identification in Washington DC,using Bayesian chemical mass balance modeling[J]. Journal of Environmental Engineering, 2013,140(3):04013015.
    [6] DIMZON I K D, MORATA A S, MÜLLER J , et al. Trace organic chemical pollutants from the lake waters of San Pablo City,Philippines by targeted and non-targeted analysis[J]. Science of the Total Environment, 2018,639:588-595.
    [7] 胡红岩, 陈鸿汉, 毕二平 . 濮阳东北部金堤河两岸地下水污染状况分析[J]. 水资源保护, 2012(2):12-16.
    [8] 胡成, 王彤, 苏丹 , 等. 水环境中污染物的源解析方法及其应用[J]. 水资源保护, 2010,26(1):57-62.
    [9] NIGRO A, SAPPA G, BARBIERI M . Strontium isotope as tracers of groundwater contamination[J]. Procedia Earth and Planetary Science, 2017,17:352-355.
    [10] 王锦国, 李群, 王碧莹 , 等. 奎河两岸污灌区浅层地下水氮污染特征及同位素示踪分析[J]. 长江科学院院报, 2017,34(4):15-19.

    WANG J G, LI Q, WANG B Y , et al. Characteristics of nitrogen pollution and isotopic tracer analysis of shallow groundwater in the sewage irrigation area of Kuihe River[J]. Journal of Yangtze River Scientific Research Institute, 2017,34(4):15-19.
    [11] ARCHANA A, THIBODEAU B, GEERAERT N , et al. Nitrogen sources and cycling revealed by dual isotopes of nitrate in a complex urbanized environment[J]. Water Research, 2018,142:459-470.
    [12] GARCIA S, NYACHOTI S K, MA L, et al. Tracing anthropogenic salinity inputs to the semi-arid Rio Grande River:a multi-isotope tracer (U,S,B and Sr) approach[C]∕∕ San Francisco: American Geophsical Union Fall Meeting, 2015.
    [13] MEGHDADI A, JAVAR N . Quantification of spatial and seasonal variations in the proportional contribution of nitrate sources using a multi-isotope approach and Bayesian isotope mixing model[J]. Environmental Pollution, 2018,235:207-222.
    [14] 孟志龙, 杨永刚, 秦作栋 , 等. 汾河下游流域水体硝酸盐污染过程同位素示踪[J]. 中国环境科学, 2017,37(3):1066-1072.

    MENG Z L, YANG Y G, QIN Z D , et al. Isotopic tracing for nitrate pollution process of water body in the lower reaches of Fenhe River[J]. China Environmental Science, 2017,37(3):1066-1072.
    [15] 方晶晶, 马传明, 刘存富 . 水土环境中硝酸盐来源与转化的环境同位素示踪研究进展[J]. 国土资源高等职业教育研究, 2017(2):56-61.
    [16] DANNI S O, BOUCHAOU L, ELMOUDEN A , et al. Assessment of water quality and nitrate source in the Massa catchment(Morocco) using δ 15N and δ 18O tracers [J]. Applied Radiation and Isotopes, 2019,154:108859.
    [17] ANORNU G, GIBRILLA A, ADOMAKO D . Tracking nitrate sources in groundwater and associated health risk for rural communities in the White Volta River Basin of Ghana using isotopic approach (δ 15N,δ 18O-N O 3 - and 3H) [J]. Science of the Total Environment, 2017,603:687-698.
    [18] PUIG R, SOLER A, WIDORY D , et al. Characterizing sources and natural attenuation of nitrate contamination in the Baix Ter aquifer system(NE Spain) using a multi-isotope approach[J]. Science of the Total Environment, 2017,580:518-532.
    [19] WIDORY D, PETELET-GIRAUD E, BRENOT A , et al. Improving the management of nitrate pollution in water by the use of isotope monitoring:the δ 15N,δ 18O and δ 11B triptych [J]. Isotopes in Environmental and Health Studies, 2013,49(1):29-47.
    [20] 马燕华, 苏春利, 刘伟江 , 等. 水化学和环境同位素在示踪枣庄市南部地下水硫酸盐污染源中的应用[J]. 环境科学, 2016,37(12):4690-4699.

    MA Y H, SU C L, LIU W J , et al. Identification of sulfate sources in the groundwater system of Zaozhuang:evidences from isotopic and hydrochemical characteristics[J]. Environmental Science, 2016,37(12):4690-4699.
    [21] OSBURN C L, OVIEDO-VARGAS D, BARNETT E , et al. Regional groundwater and storms are hydrologic controls on the quality and export of dissolved organic matter in two tropical rainforest streams,Costa Rica[J]. Journal of Geophysical Research Biogeosciences, 2018,123(3):850-866.
    [22] DERRIEN M, KIM M S, OCK G , et al. Estimation of different source contributions to sediment organic matter in an agricultural-forested watershed using end member mixing analyses based on stable isotope ratios and fluorescence spectroscopy[J]. Science of the Total Environment, 2018,618:569-578.
    [23] 马永祥 . 宁东煤田煤炭开采对区域地下水环境的影响及其特征研究[D]. 长春:吉林大学, 2017.
    [24] 聂泽宇 . 典型农业面源污染河流硝态氮及荧光溶解性有机质的源解析研究[D]. 杭州:浙江大学, 2016.
    [25] SHAKAK N B I . Detection of the nitrate pollution sources in shallow aquifer,using integration of RS & GIS with stable isotopes technologies[J]. ISPRS-International Archives of the Photogrammetry,Remote Sensing and Spatial Information Sciences, 2018,42(3):1511-1517.
    [26] MEGHDADI A, JAVAR N . Evaluation of nitrate sources and the percent contribution of bacterial denitrification in hyporheic zone using isotope fractionation technique and multi-linear regression analysis[J]. Journal of Environmental Management, 2018,222:54-65.
    [27] 张胜 . 同位素示踪技术的原理及应用阐释[J]. 生物学教学, 2018,43(8):79-80.
    [28] 张建尚 . 同位素示踪技术的应用及展望[J]. 生物学教学, 2017(11):56-58.
    [29] 贺晓蕾, 张彦 . 同位素示踪技术在环境领域中的应用研究[J]. 环境科技, 2011,24(5):70-73.

    HE X L, ZHANG Y . Study on application of stable isotope tracer technique in environmental field[J]. Environment Science and Technology, 2011,24(5):70-73.
    [30] 白志鹏, 张利文, 彭林 , 等. 稳定同位素在污染物溯源与示踪中的应用[J]. 城市环境与城市生态, 2006(4):29-32.

    BAI Z P, ZHANG L W, PENG L , et al. Application of stable isotope to trace to the sources and trail pollutants[J]. Urban Environment & Urban Ecology, 2006(4):29-32.
    [31] 颜耕, 周磊, 陈玲 . 同位素技术在环境科学研究中的应用进展[J]. 环境监测管理与技术, 2018(2):1-4.

    YAN G, ZHOU L, CHEN L . Progress of applying isotope technology in the studies of environmental science[J]. The Administration and Technique of Environmental Monitoring, 2018(2):1-4.
    [32] 郑淑蕙 . 稳定同位素地球化学分析[M]. 北京:北京大学出版社 1986.
    [33] 郑永飞 . 稳定同位素地球化学[M]. 北京:科学出版社 2000.
    [34] 郑淑惠, 郑斯成, 莫志超 . 稳定同位素地球化学分析[M]. 北京:北京大学出版社 1986.
    [35] 张炜明 . 稳定核素的应用[M]. 北京:科学出版社 1983.
    [36] 赵墨田 . 稳定同位素分析法[M]. 北京:科学出版社 1985.
    [37] 李冰, 杨红霞 . 电感耦合等离子体质谱(ICP-MS)技术在地学研究中的应用[J]. 地学前缘, 2003,10(2):367-378.

    LI B, YANG H X . Applications of inductively coupled plasma mass spectrometry in earth science[J]. Earth Science Frontiers, 2003,10(2):367-378.
    [38] 丁悌平 . 稳定同位素测试技术与参考物质研究现状及发展趋势[J]. 岩矿测试, 2002,21(4):291-300.

    DING T P . Present status and prospect of analytical techniques and reference materials for stable isotopes[J]. Rock and Mineral Analysis, 2002,21(4):291-300.
    [39] 白志鹏, 张利文, 彭林 , 等. 稳定同位素在环境科学研究中的应用进展[J]. 同位素, 2007,20(1):57.

    BAI Z P, ZHANG L W, PENG L , et al. The status of applying stable isotope in the studies of environmental science[J]. Isotopes, 2007,20(1):57.
    [40] DANNI S O, BOUCHAOU L, ELMOUDEN A , et al. Assessment of water quality and nitrate source in the Massa catchment(Morocco)using δ 15N and δ 18O tracers [J]. Applied Radiation and Isotopes, 2019: 108859.
    [41] GOODDY D C, BOWES M J, LAPWORTH D J , et al. Evaluating the stable isotopic composition of phosphate oxygen as a tracer of phosphorus from waste water treatment works[J]. Applied Geochemistry, 2018,95:139-146.
    [42] NEYMARK L A, PREMO W R, EMSBO P . Combined radiogenic( 87Sr∕ 86Sr, 234U∕ 238U) and stable(δ 88Sr)isotope systematics as tracers of anthropogenic groundwater contamination within the Williston Basin USA [J]. Applied Geochemistry, 2018,96:11-23.
    [43] DIÉDHIOU M, CISSÉFAYE S, DIOUF O C , et al. Tracing groundwater nitrate sources in the Dakar suburban area:an isotopic multi-tracer approach[J]. Hydrological Processes, 2012,26(5):760-770.
    [44] 赵鹏宇, 翟召怀, 步秀芹 , 等. 滹沱河源头地下水硝酸盐污染的氮氧同位素示踪[J]. 水资源与水工程学报, 2017,28(6):83-89.

    ZHAO P Y, ZHAI Z H, BU X Q , et al. Traceability of Nitrogen-oxygen isotope on nitrate-contaminated groundwater of Hutuo River Source[J]. Journal of Water Resources and Water Engineering, 2017,28(6):83-89.
    [45] 赵庆良, 马慧雅, 任玉芬 , 等. 利用δ 15N-N O 3 - 和δ 18O-N O 3 - 示踪北京城区河流硝酸盐来源 [J]. 环境科学, 2016,37(5):1692-1698.

    ZHAO Q L, MA H Y, REN Y F , et al. δ 15N-N O 3 - and δ 18O-N O 3 - tracing of nitrate sources in Beijing Urban Rivers [J]. Environmental Science, 2016,37(5):1692-1698.
    [46] 王静, 叶寅, 王允青 , 等. 利用氮氧同位素示踪技术解析巢湖支流店埠河硝酸盐污染源[J]. 水利学报, 2017,48(10):1195-1205.

    WANG J, YE Y, WANG Y Q , et al. Using δ 15N and δ 18O values to identify sources of nitrate in the Dianbu River in the Chaohu Lake Basin [J]. Journal of Hydraulic Engineering, 2017,48(10):1195-1205.
    [47] 梁越, 肖化云, 刘小真 , 等. 碳氮稳定同位素示踪鄱阳湖流域蚌湖丰水期的氮污染[J]. 湖泊科学, 2018,30(4):957-966.

    LIANG Y, XIAO H Y, LIU X Z , et al. Carbon and nitrogen stable isotopes tracing nitrogen pollution in major flooding season in Lake Bang,Lake Poyang Basin[J]. Journal of Lake Sciences, 2018,30(4):957-966.
    [48] 张秋霞, 周建伟, 康凤新 , 等. 淄博煤矿区地下水污染水动力和同位素解析[J]. 环境科学与技术, 2016,39(8):116-122.

    ZHANG Q X, ZHOU J W, KANG F X , et al. Hydrodynamic analysis and isotope tracing for probing into groundwater pollution of Zibo Mining Area[J]. Environmental Science & Technology, 2016,39(8):116-122.
    [49] 袁丽君, 刘广, 张泽洲 , 等. 滆湖氮污染双同位素溯源与清单统计法对比研究[J]. 土壤, 2018,50(4):738-745.

    YUAN L J, LIU G, ZHANG Z Z , et al. The comparation of dual isotope and budget statistics method for the sources of nitrogen pollution in Gehu Lake,Jiangsu[J]. Soils, 2018,50(4):738-745.
    [50] DOLENEC M, ŽVAB P, MIHELČIćG , et al. Use of stable nitrogen isotope signatures of anthropogenic organic matter in the coastal environment:a case study of the Kosirina Bay(Murter Island,Croatia) [J]. Geologia Croatica, 2011,64(2):143-152.
    [51] 王毛兰 . 鄱阳湖流域氮磷时空分布及其地球化学模拟[D]. 南昌:南昌大学, 2007.
    [52] 王静, 吴丰昌, 黎文 , 等. 云贵高原湖泊颗粒有机物稳定氮同位素的季节和剖面变化特征[J]. 湖泊科学, 2008,20(5):571-578.

    WANG J, WU F C, LI W , et al. Seasonal variation and vertical characteristics of the δ 15N of particulate organic matter in Lake Hongfeng and Lake Baihua,Guizhou Province [J]. Journal of Lake Sciences, 2008,20(5):571-578.
    [53] 李跃飞 . 秦淮河氮、磷时空动态特征及基于硝态氮氮同位素方法的氮源辨别[D]. 南京:南京农业大学, 2013.
    [54] 李军 . 长江中下游地区浅水湖泊生源要素的生物地球化学循环[D]. 贵阳:中国科学院地球化学研究所, 2005.
    [55] 孙玮玮, 毕春娟, 陈振楼 , 等. 稳定性同位素示踪技术在环境领域的应用初探[J]. 环境科学与技术, 2009,32(9):88-92.

    SUN W W, BI C J, CHEN Z L , et al. A preliminary study on application of stable isotope tracer technique in environmental field[J]. Environmental Science & Technology, 2009,32(9):88-92.
    [56] 张东平, 张少欢, 余应新 , 等. 太湖鱼中多不饱和脂肪酸及其与多氯联苯共摄入益害分析[J]. 科学通报, 2012,57(5):324-331.

    ZHANG D P, ZHANG S H, YU Y X , et al. Polyunsaturated fatty acids in fish from Taihu Lake and the associated risk of ingesting polychlorinated biphenyls[J]. Chinese Science Bulletin, 2012,57(5):324-331.
    [57] FISK A T, STERN G A, HOBSON K A , et al. Persistent organic pollutants(POPs) in a small,herbivorous,arctic marine zooplankton(Calanus hyperboreus):trends from April to July and the influence of lipids and trophic transfer[J]. Marine Pollution Bulletin, 2001,43:93-101.
    [58] EVENSET A, CHRISTENSEN G N, SKOTVOLD T , et al. A comparison of organic contaminants in two high Arctic Lake ecosystems,Bear Island Norway[J]. Science of the Total Environment, 2004,318(1∕2∕3):125-141.
    [59] 马红枣, 潘立刚, 李安 , 等. 单体稳定同位素分析技术在有机污染物溯源中的应用研究进展[J]. 农药学学报, 2017(3):15-22.

    MA H Z, PAN L G, LI A , et al. Research progress on the application of compound-specific isotope analysis in the origin traceability of organic pollutants[J]. Chinese Journal of Pesticide Science, 2017(3):15-22.
    [60] O'MALLEY V P, ABRAJANO T A JR, HELLOU J . Determination of the 13C 12C ratios of individual PAH from environmental samples:can PAH sources be apportioned [J]. Organic Geochemistry, 1994,21(6∕7):809-822.
    [61] BLESSING M, JOCHMANN M A, HADERLEIN S B , et al. Optimization of a large-volume injection method for compound-specific isotope analysis of polycyclic aromatic compounds at trace concentrations[J]. Rapid Communications in Mass Spectrometry, 2015,29(24):2349-2360.
    [62] BUCZYHSKA A J, GEYPENS B, van GRIEKEN R , et al. Stable carbon isotopic ratio measurement of polycyclic aromatic hydrocarbons as a tool for source identification and apportionment:a review of analytical methodologies[J]. Talanta, 2013,105:435-450.
    [63] 苑金鹏, 钟宁宁, 吴水平 . 土壤中多环芳烃的稳定碳同位素特征及其对污染源示踪意义[J]. 环境科学学报, 2005,25(1):81-85.

    YUAN J P, ZHONG N N, WU S P . Stable carbon isotopic composition of polycyclic aromatic hydrocarbons in soil and its implications for the pollutants tracing[J]. Acta Scientiae Circumstantiae, 2005,25(1):81-85.
    [64] MIKOLAJCZUK A, GEYPENS B, BERGLUND M , et al. Use of a temperature-programmable injector coupled to gas chromatography-combustion-isotope ratio mass spectrometry for compound-specific carbon isotopic analysis of polycyclic aromatic hydrocarbons.[J]. Rapid Communications in Mass Spectrometry, 2010,23(16):2421-2427.
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