Volume 7 Issue 6
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Article Navigation >  Journal of Environmental Engineering Technology  > 2017  >  7(6): 712-717
SHANG Xiaofu, MA Jianli, ZHANG Jian, XU Danyu, ZHANG Liangyun, ZHOU Jinqian, DUAN Xiaoyu, ZHANG Xiaomin. Research status and prospects of utilization technologies of slag from coal gasification[J]. Journal of Environmental Engineering Technology, 2017, 7(6): 712-717. doi: 10.3969/j.issn.1674-991X.2017.06.098
Citation: SHANG Xiaofu, MA Jianli, ZHANG Jian, XU Danyu, ZHANG Liangyun, ZHOU Jinqian, DUAN Xiaoyu, ZHANG Xiaomin. Research status and prospects of utilization technologies of slag from coal gasification[J]. Journal of Environmental Engineering Technology, 2017, 7(6): 712-717. doi: 10.3969/j.issn.1674-991X.2017.06.098
shu

Research status and prospects of utilization technologies of slag from coal gasification

doi: 10.3969/j.issn.1674-991X.2017.06.098

  • 1. Tianjin Academy of Environmental Science, Tianjin 300191, China

  • 2. Tianjin Huankelijia Environment Remediation Technology Co., Ltd., Tianjin 300191, China

  • 3. Yancon Group Co., Ltd., Jining 273500, China

More Information
  • Corresponding author: Jianli MA E-mail: majianguang@163.com
  • Received Date: 2017-05-21
  • Publish Date: 2017-11-20
    Abstract
  • Coal gasification technology has become an important part in China's energy strategy. However, a great amount of slag has been generated due to this technology, which requires urgent development of resource utilization technology to consume and reuse the slag largely. Considering that different mineral phases of coal ash content will change with the temperature in the gasifier, and based on the investigation and summarization of this change, the physicochemical reaction process of various mineral phases in gasifier is described and the decisive impact of coal ash content on final morphological characteristics of slag from coal gasification is also revealed. The research on the constituents of carbon residue in the slag and their features of change shows that final utilization approaches of the slag are significantly influenced by carbon residue. Additionally, by analyzing current research status of utilization technology of coal gasification slag, it is pointed out that the utilization as building material and mixed combustion with circulating fluid-bed raw material are the most popular approaches for slag utilization. Finally, the prospects of utilization technology for slag from coal gasification are proposed and some utilization approaches are suggested, including using as raw material of concrete or cement and being backfilled underground.

     

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    • References(34)
  • [1]
    赵永彬, 吴辉, 蔡晓亮 , 等. 煤气化残渣的基本特性研究[J].洁净煤技术, 2015(3):110-113.

    ZHAO Y B, WU H, CAI X L , et al. Basic characteristics of coal gasification residual[J].Clean Coal Technology, 2015(3):110-113.
    [2]
    李风海, 黄戒介, 房倚天 , 等. 晋城无烟煤流化床气化结渣机理的探索[J]. 太原理工大学学报, 2010,41(5):666-669.

    LI F H, HUANG J J, FANG Y T , et al. Exploration on slagging mechanism of Jincheng anthracite during fluidized-bed gasification[J]. Journal of Taiyuan University of Technology, 2010,41(5):666-669.
    [3]
    梁国治 . 煤灰中矿物组成分析[J].矿业科学技术, 2005(4):27-29.
    [4]
    MATJIE R H, ALPHEN C V . Mineralogical features of size and density fractions in Sasol coal gasification ash,South Africa and potential by-products[J]. Fuel, 2008,87(8/9):1439-1445.
    doi: 10.1016/j.fuel.2007.08.017
    [5]
    须藤俊男. 黏土矿物学[M]. 北京: 地质出版社, 1981.
    [6]
    DYK J C V, MELZER S, SOBIECKI A . Mineral matter transformation during Sasol-Lurgi fixed bed dry bottom gasification-utilization of HT-XRD and FactSage modelling[J]. Minerals Engineering, 2006,19(10):1126-1135.
    doi: 10.1016/j.mineng.2006.03.008
    [7]
    SONG W, TANG L, ZHU X , et al. Fusibility and flow properties of coal ash and slag[J]. Fuel, 2009,88(2):297-304.
    doi: 10.1016/j.fuel.2008.09.015
    [8]
    丰芸, 李寒旭, 丁立明 . 利用XRD分析高温下淮南煤灰矿物质变化[J]. 安徽建筑工业学院学报(自然科学版), 2008,16(5):53-57.

    FENG Y, LI H X, DING L M . Study of huainan coal ash mineral variation under high temperature with XRD[J]. Journal of Anhui Institute of Architecture(Natural Science), 2008,16(5):53-57.
    [9]
    杨鑫, 黄戒介, 房倚天 , 等. 无烟煤流化床气化飞灰的结渣特性[J]. 燃料化学学报, 2013,41(1):1-8.

    YANG X, HUANG J J, FANG Y T , et al. Slagging characteristics of fly ash from anthracite gasification in fluidized bed[J]. Journal of Fuel Chemistry and Technology, 2013,41(1):1-8.
    [10]
    饶东生 . 硅酸盐物理化学[M]. 北京: 冶金工业出版社, 1991.
    [11]
    李继炳, 汤永新, 芦涛 , 等. 皖北刘二煤在Shell气流床气化过程中熔渣形成机理初探[J]. 化工时刊. 2009,23(5):42-46.

    LI J B, TANG Y X, LU T , et al. Study of slag melt mechanism of liuer coal in shell gasifier by X-ray diffraction(XRD)[J]. Chemical Industry Times, 2009,23(5):42-46.
    [12]
    HUFFMAN G P, HUGGINS F E, SHAH N , et al. Behavior of basic elements during coal combustion[J]. Progress in Energy & Combustion Science, 1990,16(4):243-251.
    doi: 10.1016/j.ijbiomac.2019.12.171 pmid: 31874273
    [13]
    周俊虎, 赵晓辉, 杨卫娟 , 等. 神华煤结渣倾向和结渣机制研究[J]. 中国电机工程学报, 2007,27(8):31-36.

    ZHOU J H, ZHAO X H, YANG W J , et al. Study on the ash deposition propensity and mechanism of shenhua coal[J]. Proceedings of the Chinese Society for Electrical Engineering, 2007,27(8):31-36.
    [14]
    毛燕东, 李克忠, 孙志强 , 等. 小型流化床燃煤自供热煤催化气化特性研究[J].高校化学工程学报, 2013(5):798-804.

    MAO Y D, LI K Z, SUN Z Q , et al. Characteristics of catalytic coal gasification in lab scale autothermal fluidized bed[J].Journal of Chemical Engineering of Chinese Universities, 2013(5):798-804.
    [15]
    杨力远 . 现代水泥生产知识概要[M]. 郑州: 郑州大学出版社, 2009.
    [16]
    李刚健 . 煤化工气化滤饼组份分析与综合利用简述[J].科技信息, 2012(35):466.
    [17]
    毛兆锋, 李志祥, 刘泽 . GE水煤浆气化装置渣水分离问题探讨[J].中氮肥, 2015(4):31-33.
    [18]
    高旭霞, 郭晓镭, 龚欣 . 气流床煤气化渣的特征[J]. 华东理工大学学报(自然科学版), 2009,35(5):677-683.

    GAO X X, GUO X L, GONG X . Characterization of slag from entrained-flow coal gasificaion[J]. Journal of East China University of Science and Technology(Natural Science Edition), 2009,35(5):677-683.
    [19]
    WAGNER N J, MATJIE R H, SLAGHUIS J H , et al. Characterization of unburned carbon present in coarse gasification ash[J]. Fuel, 2008,87(6):683-691.
    doi: 10.1016/j.fuel.2007.05.022
    [20]
    肖忠明, 王昕 . 工业废渣在水泥生产中的应用[M]. 北京: 中国建材工业出版社, 2009.
    [21]
    王迎春, 苏英, 周世华 . 水泥混合材和混凝土掺合料[M]. 北京: 化学工业出版社, 2011.
    [22]
    ACOSTA A, IGLESIAS I, AINETO M , et al. Utilisation of IGCC slag and clay steriles in soft mud bricks (by pressing) for use in building bricks manufacturing[J]. Waste Management, 2002,22(8):887-891.
    doi: 10.1016/s0956-053x(02)00075-2 pmid: 12423050
    [23]
    尹洪峰, 汤云, 任耘 , 等. Texaco气化炉炉渣基本特性与应用研究[J]. 煤炭转化, 2009,32(4):30-33.

    YIN H F, TANG Y, REN Y , et al. Study on the characteristic and application of gasification slag from Texaco gasifier[J]. Coal Conversion, 2009,32(4):30-33.
    [24]
    云正, 于鹏超, 尹洪峰 . 气化炉渣对铁尾矿烧结墙体材料性能的影响[J].金属矿山, 2010(11):183-186.

    YUN Z, YU P C, YIN H F . Effect of gasification slag on the properties of sintered wall materials with iron ore tailings[J].Metal Mine, 2010(11):183-186.
    [25]
    章丽萍, 温晓东, 史云天 , 等. 煤间接液化灰渣制备免烧砖研究[J]. 中国矿业大学学报, 2015,44(2):354-358.

    ZHANG L P, WEN X D, SHI Y T , et al. Reserch on making non-burnt brick from indirect coal liquefaction residues[J]. Journal of China University of Mining & Technology, 2015,44(2):354-358.
    [26]
    TAO W, MEI G, LESTER E , et al. Characterisation of residual carbon from entrained-bed coal water slurry gasifiers[J]. Fuel, 2007,86(7/8):972-982.
    doi: 10.1016/j.fuel.2006.09.033
    [27]
    王伟, 王继征 . 气化渣煤泥白泥在循环流化床锅炉的综合利用[J].科技致富向导, 2011(31):64.
    [28]
    杨帅, 石立军 . 煤气化细渣组分分析及其综合利用探讨[J]. 煤化工, 2013,41(4):29-31.

    YANG S, SHI L J . Composition analysis of the fine slag from coal gasification and its comprehensive utilization[J]. Coal Chemical Industry, 2013,41(4):29-31.
    [29]
    高继光, 马银亮, 刘锐杰 . 水煤浆气化灰渣综合利用和效益分析[J].节能与环保, 2014(2):72-73.
    [30]
    晁岳建, 王洪记 . 循环流化床锅炉掺烧气化渣和煤泥的可行性研究[J].化肥工业, 2015(3):48-50.

    CHAO Y J, WANG H J . Feasibility study of circulating fluidized bed boiler blending burning gasification slag and coal slime[J].Chemical Fertilizer Industry, 2015(3):48-50.
    [31]
    KENNEDY C R, KREIS S W, POEPPEL R B , et al. Utilization of coal slag from pressurized coal-gasification plants[J]. Journal of Materials for Energy Systems, 1980,2(1):51-54.
    [32]
    ACOSTA A, AINETO M, IGLESIAS I , et al. Physico-chemical characterization of slag waste coming from GICC thermal power plant[J]. Materials Letters, 2001,50(4):246-250.
    doi: 10.1016/S0167-577X(01)00233-6
    [33]
    何绪文, 崔炜, 王春荣 , 等. 气化炉渣的重金属浸出特性及化学形态分析[J]. 化工环保, 2014,34(5):499-502.

    HE X W, CUI W, WANG C R , et al. Analysis on leaching characteristics and chemical speciation of heavy metals in gasification slag[J]. Environmental Protection of Chemical Industry, 2014,34(5):499-502.
    [34]
    章丽萍, 刘青, 陈傲蕾 , 等. 煤间接液化固体废物污染特性研究[J].中国矿业大学学报, 2015(5):931-936.

    ZHANG L P, LIU Q, CHEN A L , et al. Pollution characteristics of residues from indirect coal liquefaction[J].Journal of China University of Mining & Technology, 2015(5):931-936.
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