Volume 13 Issue 4
Jul.  2023
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ZHAO Z Y,ZHOU X,WANG T F,et al.Feasibility, technical status and prospects of lithium recovery from produced water in oil and gas fields[J].Journal of Environmental Engineering Technology,2023,13(4):1434-1443 doi: 10.12153/j.issn.1674-991X.20221190
Citation: ZHAO Z Y,ZHOU X,WANG T F,et al.Feasibility, technical status and prospects of lithium recovery from produced water in oil and gas fields[J].Journal of Environmental Engineering Technology,2023,13(4):1434-1443 doi: 10.12153/j.issn.1674-991X.20221190

Feasibility, technical status and prospects of lithium recovery from produced water in oil and gas fields

doi: 10.12153/j.issn.1674-991X.20221190
  • Received Date: 2022-11-29
    Available Online: 2023-07-19
  • The contradiction between high demand and low production of lithium resources makes it urgent to develop new lithium resources. The produced water of oil and gas fields is rich in lithium elements, which is a potential liquid lithium resource. Therefore, it is of great practical significance to analyze the feasibility of lithium extraction from produced water of oil and gas field and propose a feasible technical route. First, the composition of produced water in oil and gas fields was analyzed, and the water quality characteristics of the produced water in oil and gas fields were defined. Then, the lithium resource endowment of major basins in China was analyzed, and the challenges of lithium extraction due to the high concentration of organic matter and rich ion composition in the complex organic-inorganic hybrid system were emphasized. Finally, the water characteristics, water treatment technology and high-efficient lithium extraction technology were comprehensively analyzed and the applicability of those lithium recovery technologies (precipitation, adsorption, extraction and membrane separation) for produced water was discussed. Combined with the practice of lithium extraction and the current situation of the industry, it was recommended to develop a lithium extraction technical route of "pretreatment + enrichment concentration (adsorption/extraction-membrane separation) + precipitation".

     

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  • [1]
    韩佳欢, 乜贞, 方朝合, 等.中国锂资源供需现状分析[J]. 无机盐工业,2021,53(12):61-66. doi: 10.19964/j.issn.1006-4990.2021-0002

    HAN J H, NIE Z, FANG C H, et al. Analysis of existing circumstance of supply and demand on China's lithium resources[J]. Inorganic Chemicals Industry,2021,53(12):61-66. doi: 10.19964/j.issn.1006-4990.2021-0002
    [2]
    OFFICE G P. Mineral commodity summaries 2020[M]. Washiton DC: Government Printing Office, 2021.
    [3]
    王浩, 黄根红, 陈瑞英, 等.全球锂资源供需展望及锂产品价格预测[J]. 中国有色冶金,2022,51(6):1-11. doi: 10.19612/j.cnki.cn11-5066/tf.2022.06.001

    WANG H, HUANG G H, CHEN R Y, et al. Supply and demand outlook of lithium resources and price forecast of lithium products[J]. China Nonferrous Metallurgy,2022,51(6):1-11. doi: 10.19612/j.cnki.cn11-5066/tf.2022.06.001
    [4]
    王艺博, 郭玉文, 孙峙, 等.我国废动力电池回收处理过程环境风险及其管理对策探讨[J]. 环境工程技术学报,2019,9(2):207-212. doi: 10.12153/j.issn.1674-991X.2018.10.090

    WANG Y B, GUO Y W, SUN Z, et al. Discussion on environmental risk analysis and management countermeasures of waste power batteries recovery in China[J]. Journal of Environmental Engineering Technology,2019,9(2):207-212. doi: 10.12153/j.issn.1674-991X.2018.10.090
    [5]
    TIAN L, LIU Y H, TANG P, et al. Lithium extraction from shale gas flowback and produced water using H1.33Mn1.67O4 adsorbent[J]. Resources, Conservation and Recycling,2022,185:106476. doi: 10.1016/j.resconrec.2022.106476
    [6]
    王秋舒, 元春华, 许虹.全球锂矿资源分布与潜力分析[J]. 中国矿业,2015,24(2):10-17. doi: 10.3969/j.issn.1004-4051.2015.02.005

    WANG Q S, YUAN C H, XU H. Analysis of the global lithium resource distribution and potential[J]. China Mining Magazine,2015,24(2):10-17. doi: 10.3969/j.issn.1004-4051.2015.02.005
    [7]
    崔晓林. 中国锂矿资源需求预测及供需分析[D]. 北京: 中国地质大学(北京), 2017.
    [8]
    马哲, 李建武.中国锂资源供应体系研究: 现状、问题与建议[J]. 中国矿业,2018,27(10):1-7.

    MA Z, LI J W. Analysis of China's lithium resources supply system: status, issues and suggestions[J]. China Mining Magazine,2018,27(10):1-7.
    [9]
    PEIRÓ L T, MÉNDEZ G V, AYRES R U. Lithium: sources, production, uses, and recovery outlook[J]. JOM,2013,65(8):986-996. doi: 10.1007/s11837-013-0666-4
    [10]
    HOU J, ZHANG H C, THORNTON A W, et al. Lithium extraction by emerging metal-organic framework-based membranes[J]. Advanced Functional Materials,2021,31(46):2105991. doi: 10.1002/adfm.202105991
    [11]
    TASKER T L, WARNER N R, BURGOS W D. Geochemical and isotope analysis of produced water from the Utica/Point Pleasant Shale, Appalachian Basin[J]. Environmental Science:Processes & Impacts,2020,22(5):1224-1232.
    [12]
    李维东.油田采出水的资源化方向[J]. 新疆地质,2002,20(2):175.

    LI W D. Resource utilization direction of oilfield produced water[J]. Xinjiang Geology,2002,20(2):175.
    [13]
    SALEM F, THIEMANN T. Produced water from oil and gas exploration: problems, solutions and opportunities[J]. Journal of Water Resource and Protection,2022,14(2):142-185. doi: 10.4236/jwarp.2022.142009
    [14]
    LIU Y Q, LU H, LI Y D, et al. A review of treatment technologies for produced water in offshore oil and gas fields[J]. Science of the Total Environment,2021,775:145485. doi: 10.1016/j.scitotenv.2021.145485
    [15]
    XIAO F. Characterization and treatment of Bakken oilfield produced water as a potential source of value-added elements[J]. Science of the Total Environment,2021,770:145283. doi: 10.1016/j.scitotenv.2021.145283
    [16]
    LI J S, CHEN F K, LING Z Y, et al. Lithium sources in oilfield waters from the Qaidam Basin, Tibetan Plateau: geochemical and Li isotopic evidence[J]. Ore Geology Reviews,2021,139:104481. doi: 10.1016/j.oregeorev.2021.104481
    [17]
    XIE W C, TIAN L, TANG P, et al. Shale gas wastewater characterization: comprehensive detection, evaluation of valuable metals, and environmental risks of heavy metals and radionuclides[J]. Water Research,2022,220:118703. doi: 10.1016/j.watres.2022.118703
    [18]
    高娟琴, 王登红, 王伟, 等.国内外主要油(气)田水中锂提取现状及展望[J]. 地质学报,2019,93(6):1489-1500. doi: 10.3969/j.issn.0001-5717.2019.06.024

    GAO J Q, WANG D H, WANG W, et al. Current status and prospects of lithium extraction in major domestic and foreign oil (gas) field waters[J]. Acta Geologica Sinica,2019,93(6):1489-1500. doi: 10.3969/j.issn.0001-5717.2019.06.024
    [19]
    矿产资源工业要求手册: 2014年修订本[M]. 北京: 地质出版社, 2010.
    [20]
    蔡春芳, 梅博文, 李伟.塔里木盆地油田水文地球化学[J]. 地球化学,1996,25(6):614-623. doi: 10.3321/j.issn:0379-1726.1996.06.012

    CAI C F, MEI B W, LI W. The hydrogeochemistry of oil-fields in Tarim Basin[J]. Geochimica,1996,25(6):614-623. doi: 10.3321/j.issn:0379-1726.1996.06.012
    [21]
    樊馥, 郑绵平, 张永生, 等.靖边气田富Br、I、Li+、K+油田水的发现及对找钾的启示[J]. 吉林大学学报(地球科学版),2012,42(增刊 2):141-147.

    FAN F, ZHENG M P, ZHANG Y S, et al. Discovery of oil field water with high content of Br, I, Li+, K+ as the indication of finding potash in Jingbian gas field[J]. Journal of Jilin University (Earth Science Edition),2012,42(Suppl 2):141-147.
    [22]
    SUN Y, WU M H, TONG T Z, et al. Organic compounds in Weiyuan shale gas produced water: identification, detection and rejection by ultrafiltration-reverse osmosis processes[J]. Chemical Engineering Journal,2021,412:128699. doi: 10.1016/j.cej.2021.128699
    [23]
    XIE W C, TANG P, WU Q D, et al. Solar-driven desalination and resource recovery of shale gas wastewater by on-site interfacial evaporation[J]. Chemical Engineering Journal,2022,428:132624. doi: 10.1016/j.cej.2021.132624
    [24]
    WANG B, XIONG M Y, WANG P J, et al. Chemical characterization in hydraulic fracturing flowback and produced water (HF-FPW) of shale gas in Sichuan of China[J]. Environmental Science and Pollution Research,2020,27(21):26532-26542. doi: 10.1007/s11356-020-08670-y
    [25]
    韩佳君, 周训, 姜长龙, 等.柴达木盆地西部地下卤水水化学特征及其起源演化[J]. 现代地质,2013,27(6):1454-1464. doi: 10.3969/j.issn.1000-8527.2013.06.025

    HAN J J, ZHOU X, JIANG C L, et al. Hydrochemical characteristics, origin and evolution of the subsurface brines in western Qaidam Basin[J]. Geoscience,2013,27(6):1454-1464. doi: 10.3969/j.issn.1000-8527.2013.06.025
    [26]
    李洪普, 郑绵平, 侯献华, 等.柴达木西部南翼山构造富钾深层卤水矿的控制因素及水化学特征[J]. 地球学报,2015,36(1):41-50. doi: 10.3975/cagsb.2015.01.05

    LI H P, ZHENG M P, HOU X H, et al. Control factors and water chemical characteristics of potassium-rich deep brine in nanyishan structure of western Qaidam Basin[J]. Acta Geoscientica Sinica,2015,36(1):41-50. doi: 10.3975/cagsb.2015.01.05
    [27]
    丁鹏元, 党伟, 王莉莉, 等.油田采出水回注处理技术现状及展望[J]. 现代化工,2019,39(3):21-25. doi: 10.16606/j.cnki.issn0253-4320.2019.03.005

    DING P Y, DANG W, WANG L L, et al. Review and prospect of technologies for reinjection treatment of oilfield produced water[J]. Modern Chemical Industry,2019,39(3):21-25. doi: 10.16606/j.cnki.issn0253-4320.2019.03.005
    [28]
    张亮, 杨卉芃, 柳林, 等.全球提锂技术进展[J]. 矿产保护与利用,2020,40(5):24-31. doi: 10.13779/j.cnki.issn1001-0076.2020.05.004

    ZHANG L, YANG H P, LIU L, et al. Global technology trends of lithium extraction[J]. Conservation and Utilization of Mineral Resources,2020,40(5):24-31. doi: 10.13779/j.cnki.issn1001-0076.2020.05.004
    [29]
    EPSTEIN J A, FEIST E M, ZMORA J, et al. Extraction of lithium from the dead sea[J]. Hydrometallurgy,1981,6(3/4):269-275.
    [30]
    葛涛, 徐亮, 孟金伟, 等.盐湖卤水提锂工艺技术研究进展[J]. 有色金属工程,2021,11(2):55-62.

    GE T, XU L, MENG J W, et al. Research progress of lithium extraction technology from salt lake brine[J]. Nonferrous Metals Engineering,2021,11(2):55-62.
    [31]
    崔小琴, 程芳琴, 张爱华, 等.盐湖卤水镁锂沉淀分离工艺研究[J]. 无机盐工业,2012,44(7):33-35. doi: 10.3969/j.issn.1006-4990.2012.07.011

    CUI X Q, CHENG F Q, ZHANG A H, et al. Study on precipitation separating technique for magnesium and lithium from salt lake brine[J]. Inorganic Chemicals Industry,2012,44(7):33-35. doi: 10.3969/j.issn.1006-4990.2012.07.011
    [32]
    ZHANG Y, HU Y H, WANG L, et al. Systematic review of lithium extraction from salt-lake brines via precipitation approaches[J]. Minerals Engineering,2019,139:105868. doi: 10.1016/j.mineng.2019.105868
    [33]
    张梦龙, 田欢, 魏昊, 等.锂资源提取工艺现状及发展趋势[J]. 稀有金属与硬质合金,2018,46(4):11-19.

    ZHANG M L, TIAN H, WEI H, et al. Present situation and development trend of lithium resource extraction process[J]. Rare Metals and Cemented Carbides,2018,46(4):11-19.
    [34]
    吴俊文.氢氧化铝沉淀法提锂的工艺研究[J]. 魅力中国,2013(17):243-244.

    WU J W. Study on the process of extracting lithium by aluminum hydroxide precipitation[J]. Charming China,2013(17):243-244.
    [35]
    刘东帆, 孙淑英, 于建国.盐湖卤水提锂技术研究与发展[J]. 化工学报,2018,69(1):141-155.

    LIU D F, SUN S Y, YU J G. Research and development on technique of lithium recovery from salt lake brine[J]. CIESC Journal,2018,69(1):141-155.
    [36]
    谢朝新, 孙一博, 刘杰.纳滤膜的改性研究进展[J]. 当代化工,2020,49(5):993-996. doi: 10.3969/j.issn.1671-0460.2020.05.057

    XIE C X, SUN Y B, LIU J. Research progress of nanofiltration membrane modification[J]. Contemporary Chemical Industry,2020,49(5):993-996. doi: 10.3969/j.issn.1671-0460.2020.05.057
    [37]
    王小留, 刘稳廷, 王晓明, 等.黄淮地区纳滤膜苦咸水软化分离性能研究[J]. 环境工程技术学报,2019,9(3):269-274. doi: 10.12153/j.issn.1674-991X.2019.01.090

    WANG X L, LIU W T, WANG X M, et al. Nanofiltration membrane performance during softening process of simulated brackish groundwater in the Huang-Huai region[J]. Journal of Environmental Engineering Technology,2019,9(3):269-274. doi: 10.12153/j.issn.1674-991X.2019.01.090
    [38]
    LU D, YAO Z K, JIAO L, et al. Separation mechanism, selectivity enhancement strategies and advanced materials for mono-/multivalent ion-selective nanofiltration membrane[J]. Advanced Membranes,2022,2:100032. doi: 10.1016/j.advmem.2022.100032
    [39]
    LI X H, ZHANG C J, ZHANG S N, et al. Preparation and characterization of positively charged polyamide composite nanofiltration hollow fiber membrane for lithium and magnesium separation[J]. Desalination,2015,369:26-36. doi: 10.1016/j.desal.2015.04.027
    [40]
    LI W, SHI C, ZHOU A Y, et al. A positively charged composite nanofiltration membrane modified by EDTA for LiCl/MgCl2 separation[J]. Separation and Purification Technology,2017,186:233-242. doi: 10.1016/j.seppur.2017.05.044
    [41]
    邢红, 王肖虎, 毛新宇.膜法盐湖卤水提锂工艺研究[J]. 盐业与化工,2016,45(1):24-26. doi: 10.16570/j.cnki.issn1673-6850.2016.01.006

    XING H, WANG X H, MAO X Y. Lithium technology research of salt lake brine by membrane[J]. Journal of Salt and Chemical Industry,2016,45(1):24-26. doi: 10.16570/j.cnki.issn1673-6850.2016.01.006
    [42]
    陈亦力, 李天玉, 唐娜, 等. 应用于盐湖水碳酸根分离与回收的装置: CN114477375A[P]. 2022-05-13.
    [43]
    陈亦力, 莫恒亮, 刘涛, 等. 一种锂吸附剂、膜元件、其制备方法及锂提取方法与装置: CN114272914A[P]. 2022-04-05.
    [44]
    ZHANG T, ZHENG W J, WANG Q Y, et al. Designed strategies of nanofiltration technology for Mg2+/Li+ separation from salt-lake brine: a comprehensive review[J]. Desalination,2023,546:116205. doi: 10.1016/j.desal.2022.116205
    [45]
    WEN X M, MA P H, ZHU C L, et al. Preliminary study on recovering lithium chloride from lithium-containing waters by nanofiltration[J]. Separation and Purification Technology,2006,49(3):230-236. doi: 10.1016/j.seppur.2005.10.004
    [46]
    AN J W, KANG D J, TRAN K T, et al. Recovery of lithium from Uyuni Salar Brine[J]. Hydrometallurgy,2012,117/118:64-70. doi: 10.1016/j.hydromet.2012.02.008
    [47]
    马培华, 邓小川, 温现民. 从盐湖卤水中分离镁和浓缩锂的方法: CN1626443A[P]. 2006-10-25.
    [48]
    GE L, WU B, LI Q H, et al. Electrodialysis with nanofiltration membrane (EDNF) for high-efficiency cations fractionation[J]. Journal of Membrane Science,2016,498:192-200. doi: 10.1016/j.memsci.2015.10.001
    [49]
    NIE X Y, SUN S Y, SUN Z, et al. Ion-fractionation of lithium ions from magnesium ions by electrodialysis using monovalent selective ion-exchange membranes[J]. Desalination,2017,403:128-135. doi: 10.1016/j.desal.2016.05.010
    [50]
    CHITRAKAR R, KANOH H, MIYAI Y, et al. A new type of manganese oxide (MnO2·0.5H2O) derived from Li1.6Mn1.6O4 and its lithium ion-sieve properties[J]. Chemistry of Materials,2000,12(10):3151-3157. doi: 10.1021/cm0000191
    [51]
    JANG Y, CHUNG E. Influence of alkanes on lithium adsorption and desorption of a H2TiO3 ion sieve adsorbent in synthetic shale gas-produced water[J]. Industrial & Engineering Chemistry Research,2019,58(48):21897-21903.
    [52]
    MAGUIRE-BOYLE S J, BARRON A R. Organic compounds in produced waters from shale gas wells[J]. Environmental Science:Processes & Impacts,2014,16(10):2237-2248.
    [53]
    邓红梅, 王耀龙, 吴宏海, 等.γ-MnO2对Tl(Ⅰ)的吸附性能[J]. 环境科学研究,2015,28(1):103-109.

    DENG H M, WANG Y L, WU H H, et al. Characteristics of Tl(Ⅰ) adsorption on γ-MnO2[J]. Research of Environmental Sciences,2015,28(1):103-109.
    [54]
    JANG Y, CHUNG E. Adsorption of lithium from shale gas produced water using titanium based adsorbent[J]. Industrial & Engineering Chemistry Research,2018,57(25):8381-8387.
    [55]
    KIM S, KIM J, KIM S, et al. Electrochemical lithium recovery and organic pollutant removal from industrial wastewater of a battery recycling plant[J]. Environmental Science:Water Research & Technology,2018,4(2):175-182.
    [56]
    LEE J, CHUNG E. Lithium recovery by solvent extraction from simulated shale gas produced water: impact of organic compounds[J]. Applied Geochemistry,2020,116:104571.
    [57]
    赵汝真, 魏琦峰, 任秀莲.盐湖提锂的萃取分离研究现状与展望[J]. 应用化工,2021,50(6):1690-1693. doi: 10.3969/j.issn.1671-3206.2021.06.049

    ZHAO R Z, WEI Q F, REN X L. Research status and prospects of extraction and separation of lithium extracted from salt lake[J]. Applied Chemical Industry,2021,50(6):1690-1693. doi: 10.3969/j.issn.1671-3206.2021.06.049
    [58]
    LIU G, ZHAO Z W, GHAHREMAN A. Novel approaches for lithium extraction from salt-lake brines: a review[J]. Hydrometallurgy,2019,187:81-100. doi: 10.1016/j.hydromet.2019.05.005
    [59]
    XU P, HONG J, QIAN X M, et al. Materials for lithium recovery from salt lake brine[J]. Journal of Materials Science,2021,56(1):16-63. doi: 10.1007/s10853-020-05019-1
    [60]
    韦笑余. 高镁锂比盐湖卤水提锂新型萃取体系的开发及应用基础研究[D]. 北京: 北京化工大学, 2021.
    [61]
    ZHANG L C, LI L J, SHI D, et al. Recovery of lithium from alkaline brine by solvent extraction with β-diketone[J]. Hydrometallurgy,2018,175:35-42. doi: 10.1016/j.hydromet.2017.10.029
    [62]
    JANG E, JANG Y, CHUNG E. Lithium recovery from shale gas produced water using solvent extraction[J]. Applied Geochemistry,2017,78:343-350. doi: 10.1016/j.apgeochem.2017.01.016
    [63]
    ZANTE G, TRÉBOUET D, BOLTOEVA M. Solvent extraction of lithium from simulated shale gas produced water with a bifunctional ionic liquid[J]. Applied Geochemistry,2020,123:104783. doi: 10.1016/j.apgeochem.2020.104783
    [64]
    CHUNG K S, LEE J C, KIM W K, et al. Inorganic adsorbent containing polymeric membrane reservoir for the recovery of lithium from seawater[J]. Journal of Membrane Science,2008,325(2):503-508. doi: 10.1016/j.memsci.2008.09.041
    [65]
    MESHRAM P, PANDEY B D, MANKHAND T R. Extraction of lithium from primary and secondary sources by pre-treatment, leaching and separation: a comprehensive review[J]. Hydrometallurgy,2014,150:192-208. doi: 10.1016/j.hydromet.2014.10.012
    [66]
    张哲浩, 李洁, 詹鹏超. 盐湖提“锂”: 记西安建筑科技大学王磊创新团队[N]. 光明日报, 2022-06-11(4).
    [67]
    熊福军, 张许, 王肖虎, 等. 一种碳酸型卤水制备碳酸锂的装置: CN216427370U[P]. 2022-05-03.
    [68]
    张许, 裘慕贤, 郭中伟, 等. 碳酸型盐湖吸附法提锂工艺及装置: CN114836621A[P]. 2022-08-02.
    [69]
    FAKHRU'L-RAZI A, PENDASHTEH A, ABDULLAH L C, et al. Review of technologies for oil and gas produced water treatment[J]. Journal of Hazardous Materials,2009,170(2/3):530-551.
    [70]
    陈家庆, 刘涛, 王春升, 等.海上油气田采出水处理技术的现状与展望[J]. 石油机械,2021,49(7):66-76. doi: 10.16082/j.cnki.issn.1001-4578.2021.07.010

    CHEN J Q, LIU T, WANG C S, et al. Development status and prospect of produced water treatment technology for offshore oil & gas field[J]. China Petroleum Machinery,2021,49(7):66-76. doi: 10.16082/j.cnki.issn.1001-4578.2021.07.010
    [71]
    西南油气田提锂试验获突破[EB/OL]. [2023-02-20]. http://www.ccin.com.cn/detail/0a0619d7482229c859a876cf193026e7/news.
    [72]
    李丽, 李宇, 金艳, 等.高硫高硬气田采出水提锂过程关键技术及应用[J]. 无机盐工业,2023,55(1):74-80. doi: 10.19964/j.issn.1006-4990.2022-0608

    LI L, LI Y, JIN Y, et al. Key technology and application of lithium extraction from produced water in high sulfur and high hardness gas fields[J]. Inorganic Chemicals Industry,2023,55(1):74-80. ◇ doi: 10.19964/j.issn.1006-4990.2022-0608
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