Volume 11 Issue 6
Nov.  2021
Turn off MathJax
Article Contents
SHI Xiaocui, PALIDA Yahefu, SONG Sixing. Characteristics and source analysis of water-soluble ions in PM2.5 in Urumqi City[J]. Journal of Environmental Engineering Technology, 2021, 11(6): 1049-1056. doi: 10.12153/j.issn.1674-991X.20210045
Citation: SHI Xiaocui, PALIDA Yahefu, SONG Sixing. Characteristics and source analysis of water-soluble ions in PM2.5 in Urumqi City[J]. Journal of Environmental Engineering Technology, 2021, 11(6): 1049-1056. doi: 10.12153/j.issn.1674-991X.20210045

Characteristics and source analysis of water-soluble ions in PM2.5 in Urumqi City

doi: 10.12153/j.issn.1674-991X.20210045
More Information
  • Corresponding author: PALIDA Yahefu E-mail: 1474672291@qq.com
  • Received Date: 2021-02-24
  • Publish Date: 2021-11-20
  • In order to explore the pollution characteristics and sources of water-soluble ions in PM2.5 during the heating and non-heating periods in Urumqi, PM2.5 samples were collected in October and December, 2019. Nine water-soluble ions, including K+, Na+, Ca2+, Mg2+, $NH_4^+$,$SO_4^{2-}$, $NO_3^-$, Cl-, F-, in PM2.5 were analyzed and determined by using the ion chromatography and inductively coupled plasma (ICP) emission spectrometer. The principal component analysis (PCA) and positive matrix factorization (PMF) models were used to carry out ion source analysis. The results showed that the average mass concentration of total water-soluble ions at sampling points of Xinjiang Agricultural University, Xiaoximen, Santunbei, and Midong District was (100.8±59.0), (61.1±18.4), (53.1±22.5) and (103.1±67.4) μg/m3, respectively, accounting for 57.9%, 56.7%, 44.0% and 54.1% of PM2.5, respectively. $NH_4^+$, $SO_4^{2-}$ and $NO_3^-$ were the main water-soluble ions in PM2.5. The average values of SOR and NOR at each sampling point in Urumqi were higher than 0.1, which indicated that there was an obvious secondary transformation process in the atmospheric during the study period. The results of PCA and PMF analysis indicated that the water-soluble ions at each sampling point mainly originated from secondary conversion, dust and combustion activities.

     

  • loading
  • [1]
    ISLEY C F, NELSON P F, TAYLOR M P, et al. PM2.5 and aerosol black carbon in Suva,Fiji[J]. Atmospheric Environment, 2017, 150:55-66.
    doi: 10.1016/j.atmosenv.2016.11.041
    [2]
    朱常琳, 马丽. 西安地区供暖初期颗粒物及气态污染物的污染状况及其相关性分析[J]. 环境工程, 2017, 35(8):81-86.

    ZHU C L, MA L. Contamination status and correlation analysis of particulate matter and gaseous pollutants in the early heating period in Xi’an[J]. Environmental Engineering, 2017, 35(8):81-86.
    [3]
    CALDERÓN-GARCIDUEÑAS L, ENGLE R, MORA-TISCAREÑO A, et al. Exposure to severe urban air pollution influences cognitive outcomes,brain volume and systemic inflammation in clinically healthy children[J]. Brain and Cognition, 2011, 77(3):345-355.
    doi: 10.1016/j.bandc.2011.09.006
    [4]
    CALDERÓN-GARCIDUEÑAS L, SOLT A C, HENRÍQUEZ-ROLDÁN C, et al. Long-term air pollution exposure is associated with neuroinflammation,an altered innate immune response,disruption of the blood-brain barrier,ultrafine particulate deposition,and accumulation of amyloid beta-42 and alpha-synuclein in children and young adults[J]. Toxicologic Pathology, 2008, 36(2):289-310.
    doi: 10.1177/0192623307313011
    [5]
    RANFT U, SCHIKOWSKI T, SUGIRI D, et al. Long-term exposure to traffic-related particulate matter impairs cognitive function in the elderly[J]. Environmental Research, 2009, 109(8):1004-1011.
    doi: 10.1016/j.envres.2009.08.003
    [6]
    LING S A. Particulate matter air pollution exposure:role in the development and exacerbation of chronic obstructive pulmonary disease[J]. International Journal of Chronic Obstructive Pulmonary Disease, 2009(4):233-243.
    [7]
    GRAFF D W, CASCIO W E, RAPPOLD A, et al. Exposure to concentrated coarse air pollution particles causes mild cardiopulmonary effects in healthy young adults[J]. Environmental Health Perspectives, 2009, 117(7):1089-1094.
    doi: 10.1289/ehp.0900558
    [8]
    von KLOT S, WÖLKE G, TUCH T, et al. Increased asthma medication use in association with ambient fine and ultrafine particles[J]. The European Respiratory Journal, 2002, 20(3):691-702.
    doi: 10.1183/09031936.02.01402001
    [9]
    WILLIAMS R C III. Environmental tax interactions when pollution affects health or productivity[J]. Journal of Environmental Economics and Management, 2002, 44(2):261-270.
    doi: 10.1006/jeem.2001.1237
    [10]
    张娟, 王炜, 赵颖. 北京市延庆区PM2.5中主要水溶性无机离子特征及来源解析[J]. 环境工程技术学报, 2020, 10(2):173-182.

    ZHANG J, WANG W, ZHAO Y. Characteristics and source analysis of water-soluble inorganic ions in PM2.5 in Yanqing District,Beijing[J]. Journal of Environmental Engineering Technology, 2020, 10(2):173-182.
    [11]
    梁琼, 尹辉, 牟书勇, 等. 乌鲁木齐市采暖期大气PM2.5特征分析[J]. 干旱区研究, 2015, 32(3):543-550.

    LIANG Q, YIN H, MU S Y, et al. Characteristics of PM2.5 during the period of heating in Urumqi[J]. Arid Zone Research, 2015, 32(3):543-550.
    [12]
    亚力昆江·吐尔逊, 迪丽努尔·塔力甫, 阿布力孜·伊米提, 等. 乌鲁木齐市可吸入颗粒物水溶性离子特征及来源解析[J]. 中国环境监测, 2012, 28(1):72-77.
    [13]
    魏明娜, 谢海燕, 邓文叶, 等. 乌鲁木齐市采暖期与非采暖期大气PM2.5和PM10中水溶性离子特征分析[J]. 安全与环境学报, 2017, 17(5):1986-1991.

    WEI M N, XIE H Y, DENG W Y, et al. Water-soluble ions pollution characteristics of the atmospheric particles(PM2.5 and PM10) in Urumqi during the heating and non-heating periods[J]. Journal of Safety and Environment, 2017, 17(5):1986-1991.
    [14]
    徐虹, 肖致美, 陈魁, 等. 天津市2017年重污染过程二次无机化学污染特征分析[J]. 环境科学, 2019, 40(6):2519-2525.

    XU H, XIAO Z M, CHEN K, et al. Secondary inorganic pollution characteristics during heavy pollution episodes of 2017 in Tianjin[J]. Environmental Science, 2019, 40(6):2519-2525.
    [15]
    张夏夏, 袁自冰, 郑君瑜, 等. 大气污染物监测数据不确定度评估方法体系建立及其对PMF源解析的影响分析[J]. 环境科学学报, 2019, 39(1):95-104.

    ZHANG X X, YUAN Z B, ZHENG J Y, et al. Establishment of an uncertainty assessment framework for atmospheric pollutant monitoring data and its impact on PMF source apportionment[J]. Acta Scientiae Circumstantiae, 2019, 39(1):95-104.
    [16]
    US Environmental Protection Agency.Positive matrix factorization(PMF)5.0 fundamentals and user guide[EB/OL].[2021-02-04].https://www.epa.gov/air-research/epa-positive-matrixfactorization-50-fundamentals-and-user-guide .
    [17]
    HE K, ZHAO Q, MA Y, et al. Spatial and seasonal variability of PM2.5 acidity at two Chinese megacities:insights into the formation of secondary inorganic aerosols[J]. Atmospheric Chemistry and Physics, 2012, 12(3):1377-1395.
    [18]
    肖以华, 习丹, 佟富春, 等. 广州市城乡梯度森林公园雨季空气PM2.5浓度及水溶性离子特征[J]. 应用生态学报, 2013, 24(10):2905-2911.

    XIAO Y H, XI D, TONG F C, et al. Characteristics of rain season atmospheric PM2.5 concentration and its water-soluble ions contents in forest Parks along an urban-rural gradient in Guangzhou City of South China[J]. Chinese Journal of Applied Ecology, 2013, 24(10):2905-2911.
    [19]
    刘素, 马彤, 杨艳, 等. 太原市冬季PM2.5化学组分特征与来源解析[J]. 环境科学, 2019, 40(4):1537-1544.

    LIU S, MA T, YANG Y, et al. Chemical composition characteristics and source apportionment of PM2.5 during winter in Taiyuan[J]. Environmental Science, 2019, 40(4):1537-1544.
    [20]
    程渊, 吴建会, 毕晓辉, 等. 武汉市大气PM2.5中水溶性离子污染特征及来源[J]. 环境科学学报, 2019, 39(1):189-196.

    CHENG Y, WU J H, BI X H, et al. Characteristics and source apportionment of water-soluble ions in ambient PM2.5 in Wuhan,China[J]. Acta Scientiae Circumstantiae, 2019, 39(1):189-196.
    [21]
    范美益, 曹芳, 张园园, 等. 徐州市冬季大气细颗粒物水溶性无机离子污染特征及来源解析[J]. 环境科学, 2017, 38(11):4478-4485.

    FAN M Y, CAO F, ZHANG Y Y, et al. Characteristics and sources of water soluble inorganic ions in fine particulate matter during winter in Xuzhou[J]. Environmental Science, 2017, 38(11):4478-4485.
    [22]
    伍潘. 成都市PM2.5水溶性无机离子及气态前体物污染特征分析[D]. 成都:西南交通大学, 2019.
    [23]
    林昕, 曹芳, 翟晓瑶, 等. 中国典型城市冬季大气细颗粒物水溶性离子特征及来源分析[J]. 生态环境学报, 2019, 28(2):307-315.

    LIN X, CAO F, ZHAI X Y, et al. Characterization and sources of water soluble inorganic ions in PM2.5 in winter in typical cities of China[J]. Ecology and Environmental Sciences, 2019, 28(2):307-315.
    [24]
    杨懂艳, 刘保献, 张大伟, 等. 2012—2013年间北京市PM2.5中水溶性离子时空分布规律及相关性分析[J]. 环境科学, 2015, 36(3):768-773.

    YANG D Y, LIU B X, ZHANG D W, et al. Correlation,seasonal and temporal variation of water-soluble ions of PM2.5 in Beijing during 2012-2013[J]. Environmental Science, 2015, 36(3):768-773.
    [25]
    HUANG X J, LIU Z R, ZHANG J K, et al. Seasonal variation and secondary formation of size-segregated aerosol water-soluble inorganic ions during pollution episodes in Beijing[J]. Atmospheric Research, 2016, 168:70-79.
    doi: 10.1016/j.atmosres.2015.08.021
    [26]
    TRUEX T J, PIERSON W R, MCKEE D E. Sulfate in diesel exhaust[J]. Environmental Science & Technology, 1980, 14(9):1118-1121.
    doi: 10.1021/es60169a013
    [27]
    ZHANG Y, HUANG W, CAI T Q, et al. Concentrations and chemical compositions of fine particles (PM2.5) during haze and non-haze days in Beijing[J]. Atmospheric Research, 2016, 174/175:62-69.
    doi: 10.1016/j.atmosres.2016.02.003
    [28]
    韩力慧, 张鹏, 张海亮, 等. 北京市大气细颗粒物污染与来源解析研究[J]. 中国环境科学, 2016, 36(11):3203-3210.

    HAN L H, ZHANG P, ZHANG H L, et al. Pollution and source apportionment of atmospheric fine particles in Beijing[J]. China Environmental Science, 2016, 36(11):3203-3210.
    [29]
    王国祯, 任万辉, 于兴娜, 等. 沈阳市冬季大气PM2.5中水溶性离子污染特征及来源解析[J/OL]. 环境科学.[2020-10-20].https://doi.org/10.13227/j.hjkx.202006249 .
    [30]
    李星, 赵文吉, 熊秋林, 等. 北京采暖季PM2.5水溶性无机离子污染特征及其影响因素[J]. 生态环境学报, 2018, 27(1):93-100.

    LI X, ZHAO W J, XIONG Q L, et al. The pollution characteristics and influencing factors of PM2.5 inorganic water-soluble ions in Beijing during heating season[J]. Ecology and Environmental Sciences, 2018, 27(1):93-100.
    [31]
    SHEN Z X, CAO J J, ARIMOTO R, et al. Ionic composition of TSP and PM2.5 during dust storms and air pollution episodes at Xi’an,China[J]. Atmospheric Environment, 2009, 43(18):2911-2918.
    doi: 10.1016/j.atmosenv.2009.03.005
    [32]
    KHARE P, BARUAH B P. Elemental characterization and source identification of PM2.5 using multivariate analysis at the suburban site of North-East India[J]. Atmospheric Research, 2010, 98(1):148-162.
    doi: 10.1016/j.atmosres.2010.07.001
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Article Metrics

    Article Views(435) PDF Downloads(61) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return