不同组分对厨余垃圾糊化热解产物特性的影响

Effects of different components on the properties of charring pyrolysis products of kitchen waste

  • 摘要: 为揭示厨余垃圾不同有机组分对其糊化热解产物特性的影响,采用糊化热解技术,在中低温、贫氧条件下,使厨余垃圾中有机组分发生部分碳化,形成具有微碳化结构或碳包被层的固体产物。与传统热解的完全碳化、水热碳化的高压液相反应相比,该技术具有反应条件温和、养分保留率高等显著优势。选取未筛分类、蛋白质类、淀粉类、纤维素类、木质素类五种厨余垃圾原料,在预试验确定的最佳糊化热解条件和贫氧条件下进行糊化热解处理,系统分析了不同组分糊化热解产物产率、理化性质、养分含量间的差异及其对黄瓜幼苗生长的影响。结果表明,不同组分厨余垃圾的糊化热解产物特性存在显著差异。淀粉类产物产率最高(83.89%);蛋白质类产物电导率(290.1 μS/cm)及总氮、总钾、速效养分含量均显著高于其他组分产物;纤维素类产物阳离子交换量最高(259.4 cmol/kg),且总磷含量丰富(38.01 g/kg);木质素类产物含水率最高(3.3%);未筛分类产物总有机碳含量最高(632.5 g/kg),碳氮比适中。所有产物均呈弱碱性(pH为7.50~8.36)。黄瓜种子发芽与幼苗生长试验表明,未筛分类产物在株高、叶面积、叶绿素含量及生物量积累上的促进效果最佳,蛋白质类产物因盐分过高而抑制种子萌发。源头分类可定向调控厨余垃圾糊化热解产物的特性,为生产专性化有机肥或土壤改良剂提供依据。

     

    Abstract: To reveal the effects of different organic components of kitchen waste on the properties of their charring pyrolysis products, this study employed charring pyrolysis technology to partially carbonize the organic components of kitchen waste under moderate to low temperatures and oxygen-limited conditions, producing solid residues with micro-carbonized structures or carbon-coated layers. Compared with conventional pyrolysis (which involves complete carbonization) and hydrothermal carbonization (which requires high-pressure liquid-phase reactions), this technology offers significant advantages including mild reaction conditions and high nutrient retention rates. Five types of kitchen-waste raw materials, namely, unsorted, protein, starch, cellulose, and lignin categories, were selected and subjected to charring pyrolysis under the optimal conditions determined in the preliminary experiments and in an oxygen-deficient environment. The differences in the yields, physicochemical properties, and nutrient contents of the charring pyrolysis products of different components and their effects on the growth of cucumber seedlings were systematically analyzed. The results showed that there were significant differences in the properties of the charring pyrolysis products of different components of kitchen waste. The yield of starch products was the highest (83.89%); the electrical conductivity (290.1 μS/cm), total nitrogen, total potassium, and available nutrient contents of protein products were significantly higher than those of other component products; the cation exchange capacity of cellulose products was the highest (259.4 cmol/kg), and the total phosphorus content was high (38.01 g/kg); the moisture content of lignin products was the highest (3.3%). The total organic carbon content of unsorted products was the highest (632.5 g/kg), and the carbon-nitrogen ratio was moderate. All products were weakly alkaline (pH 7.50-8.36). The cucumber seed germination and seedling growth experiments showed that the unsorted products had the most pronounced promoting effect on plant height, leaf area, chlorophyll content, and biomass accumulation; the protein products inhibited seed germination due to excessive salt content. The study indicates that source classification can tailor the properties of charring pyrolysis products of kitchen waste, providing a basis for producing specialized organic fertilizers or soil conditioners.

     

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