基于沉积柱的渤海湾金属垂向分布特征及来源分析

Vertical distribution and source analysis of metals in Bohai Bay based on sedimentary cores

  • 摘要: 渤海湾作为我国北方典型半封闭海湾,高强度人类活动与自然沉积过程共同作用导致金属来源复杂化。为厘清20世纪70年代重大水利工程(如闸坝建设)对近岸金属的调控,基于渤海湾西部近岸沉积柱粒度、常量金属元素(Al、Ca、Fe、K、Mg、Mn、Na)及重金属(Cr、Cu、Zn、Cd、Pb、Sb、Hg)含量,结合主成分分析与归一化方法,揭示了海河建闸工程对金属来源及沉积模式的长期影响。结果表明,渤海湾西部近岸沉积柱以粉砂质黏土为主(粒径Φ值为4.83~6.69),呈现跃移主导的输运特征;沉积柱金属垂向分布存在显著峰值波动。因子分析以及归一化分析表明,20世纪70年代前入海河口海岸带附近表层沉积物中的金属分布格局受到沿海地区以及入海河流潮汐段沉积柱自然搬运和再悬浮-沉积过程的共同影响(累积方差贡献率>70%)。随着海河流域入海河流防潮闸陆续完成,从20世纪70年代初开始,入海口附近海域金属分布格局转为以自然地球化学过程为主导,仅有邻近工业区局部地区表现出人为污染的特征。因此,渤海湾大部分地区表层沉积柱中金属的迁移主要受控于湾内沉积柱的再悬浮-沉积过程,部分沿岸工业区附近海域人为排放等仍是主要金属的主要来源。研究阐明了自然因素与人类活动对渤海湾沉积环境的复合影响,该影响是沉积物中金属时空差异的主要控制因素,这一认识为海岸带环境管理提供了科学依据。

     

    Abstract: Bohai Bay, a representative semi-enclosed gulf in northern China, exhibits complex metal sources due to coupled effects of intensive anthropogenic activities and natural sedimentation processes. To clarify the regulation of nearshore metals by major water conservancy projects in the 1970s (e.g. sluice-gate and dam constructions), we examined the particle size, major metal elements (Al、Ca、Fe、K、Mg、Mn、Na) and heavy metal (Cr、Cu、Zn、Cd、Pb、Sb、Hg) contents of the nearshore sedimentary cores in the western Bohai Bay. By integrating the principal component analysis (PCA) with data normalization methods, we revealed the long-term impact of the Haihe River sluice construction projects in the 1970s on the metal sources and sedimentary patterns. Results indicated that the sedimentary cores in Bohai Bay were predominantly composed of silt and clay with particle size (Ф value) ranging from 4.83 to 6.69, and the sediment transport exhibited a saltation-dominated mode. There were significant peak fluctuations in the vertical distribution of the metals in the sedimentary cores. Factor analysis and normalization analysis indicated that the distribution pattern of metals in the surface sediments near the coastal zone of estuaries flowing into the sea before the 1970s was jointly influenced by the natural transport of sedimentary cores and the resuspension-deposition process in coastal areas and tidal sections of rivers flowing into the sea (cumulative variance contribution>70%). However, with the completion of the flood-control gates of the rivers flowing into the sea in Haihe River Basin one after another, since the early 1970s, the metal distribution patterns in the near-shore waters in the estuary had been dominated by natural geochemical processes, and only some local areas near the industrial zone had shown the characteristics of anthropogenic pollution. Therefore, the metal migration in the surface sediments in most areas of Bohai Bay was mainly controlled by the resuspension-deposition process of the sedimentary cores within the bay. In some coastal industrial areas, anthropogenic emissions and other factors remained the main sources of major metals. The research has revealed the dual impact of natural and human activities on the sedimentary environment, which has had a long-term effect on the temporal and spatial differences of metals in the sediments of Bohai Bay. These findings provide a scientific basis for the environmental management of the coastal zone.

     

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