山西某焦化场地土壤和地下水中特征污染物的空间分布和相关性分析

Spatial distribution and correlation analysis of characteristic pollutants in soil and groundwater of a coking plant site in Shanxi, China

  • 摘要: 焦化场地土壤和地下水中残留高浓度的有机污染物,对周边人类健康及生态系统构成严重威胁。为探究焦化场地特征污染物在土壤和地下水中的迁移规律及污染来源,以山西省某具有30余年生产历史的焦化场地为研究对象,运用可视化地质统计学和Pearson相关性分析等方法,系统研究土壤和地下水中特征污染物的空间分布特征,并探讨不同土层与地下水中污染物之间的相关性。结果表明:该场地土壤中的主要污染物为多环芳烃、苯和石油烃,最大浓度分别为268、1 110和20 134 mg/kg,污染主要集中于焦化厂的生产、储存及污水处理区域。污染物主要分布于表层土壤和砾砂层,最大迁移深度依次为苯(20 m)>多环芳烃(15 m)>石油烃(13 m)。污染物浓度随土壤深度递减,其中粉质黏土层对污染物迁移具有较好的阻隔作用。该场地地下水中的主要污染物为苯、萘和菲,最大浓度分别为177、7.85 mg/L和67.20 μg/L。土壤与地下水污染之间存在较强的关联性,地下水中的苯、萘和菲主要来源于土壤中粉土层的污染迁移。

     

    Abstract: High concentrations of organic pollutants persist in the soil and groundwater of coking plant sites, posing significant threats to human health and the surrounding ecosystem. To investigate the migration patterns and sources of characteristic pollutants in the soil and groundwater of coking plant sites, this study focuses on a coking plant site in Shanxi Province with a production history of over 30 years. By employing geostatistical visualization techniques and Pearson correlation analysis, we systematically examined the spatial distribution of characteristic pollutants in the soil and groundwater and explored the correlations between contaminants in different soil layers and groundwater. The results indicate that the primary pollutants in the soil are polycyclic aromatic hydrocarbons (PAHs), benzene, and petroleum hydrocarbons, with maximum concentrations of 268, 1 110, and 20 134 mg/kg, respectively. Contamination is predominantly concentrated in production, storage, and wastewater treatment areas. Pollutants are mainly distributed in surface soil and gravel layers, with maximum migration depths following the order: benzene (20 m) > PAHs (15 m) > petroleum hydrocarbons (13 m). Pollutant concentrations decrease with depth, and the silty clay layer exhibits a strong barrier effect against contaminant migration. In groundwater, the major pollutants are benzene, naphthalene, and phenanthrene, with maximum concentrations of 177, 7.85 mg/L, and 67.20 μg/L, respectively. A strong correlation exists between soil and groundwater contamination, with benzene, naphthalene, and phenanthrene in groundwater primarily originating from the migration of pollutants in the silty soil layer.

     

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