苏州某塑料厂土壤砷修复目标值确定方法研究

Study on the method of determining the target value of arsenic remediation in soil of a plastic factory in Suzhou City

  • 摘要: 砷作为土壤中广泛存在的重金属,可通过经口摄入、皮肤接触、吸入颗粒物等途径进入人体,对健康构成威胁。在污染地块环境管理中,基于健康风险推算的修复目标值远低于我国各地区的土壤背景值,直接以此作为修复目标值会造成过度修复和经济浪费。以苏州某塑料厂地块为研究对象,采用健康风险模型推导、等效允许摄入量反推、多证据分析技术确定环境背景上限等方法确定土壤砷修复目标值,并分析其适用性。结果表明:1)采用风险评估方法推算的GB 36600—2018《土壤环境质量 建设用地土壤污染风险管控标准(试行)》中划分的第一类用地情景下砷土壤风险控制值为0.45 mg/kg,即使引入土壤砷经口暴露途径下的生物可给性推荐系数0.65,计算结果0.64 mg/kg仍远低于GB 36600—2018规定的土壤污染风险筛选值(20 mg/kg),不宜直接作为修复目标值;2)根据不同环境介质允许摄入量等效原则,采用GB 5749—2022《生活饮用水卫生标准》中推荐参数,由饮用水标准限值对应的砷允许摄入量反推出土壤砷修复目标值为35 mg/kg。进一步对敏感参数儿童平均每日饮水量进行本地化赋值(华东地区为0.78 L/d),计算得到修复目标值为39 mg/kg。该方法制定的砷土壤修复目标值具有一定合理性,在实际场地中也有所应用,但难以区分超标点位的具体成因,且由于计算结果低于高背景地区背景值,该方法并不适用于高背景地区修复目标值的确定;3)采用相对累积频率分布曲线推算出地块土壤砷环境背景上限值为41 mg/kg,此值可作为地块土壤砷筛选值或修复目标值。结合地块生产历史、土壤砷空间分布等多证据分析,可判定此场地并非砷污染地块,尽管个别数据超过土壤砷筛选值或修复目标值,仍无需修复。研究结果对于指导科学合理制定地块土壤重金属修复目标值,避免过度修复具有借鉴意义。

     

    Abstract: Arsenic, as a heavy metal widely present in soil, can enter the human body through oral, skin contact, respiratory particulate matter and other pathways, thereby posing a threat to health. The remediation target value based on health risk projection in the environmental management of contaminated plots is far lower than the soil background value in various regions of China. Directly using these as remediation target values would lead to over-remediation and economic waste. This study took a plastic factory plot in Suzhou as the research object, determining the target value of soil arsenic remediation and analyzing its applicability by using three techniques (health risk model derivation, the inverse deduction of the equivalent allowable intake, and multi-evidence analysis) to determine the upper limit of the environmental background. The results showed that: 1) The risk control value of arsenic soil in a category of land use scenario deduced by the risk assessment method was 0.45 mg/kg. Even if the recommended coefficient of bioavailability of 0.65 under the oral exposure pathway of soil arsenic was introduced, the calculation result was 0.64 mg/kg, far lower than the screening value of 20 mg/kg for soil pollution risk specified in Soil Environmental Quality - Risk Control Standards for Soil Contamination of Development Land (for trial implementation) (GB 36600-2018), making it unsuitable as the remediation target. 2) According to the principle of "equivalence of allowable intake of different environmental media", using the recommended parameters in Standards for Drinking Water Quality(GB 5749-2022), the arsenic remediation target value of soil arsenic was inverted to be 35 mg/kg from the arsenic allowable intake corresponding to the drinking water standard limit value. The value was further localized for the sensitive parameter of children's average daily drinking water (0.78 L/d in East China), which was calculated to be 39 mg/kg. The target values for arsenic soil remediation developed by this method were reasonable and had been applied in real sites. However, it was not easy to distinguish the specific causes of the points exceeding the remediation target value, and since the calculation results were lower than the background values in high background areas, this method was inapplicable to the determination of remediation target values in high background areas. 3) Using the relative cumulative frequency curve, the upper limit of the environmental background of arsenic in the soil of the plot was determined to be 41 mg/kg, which could be used as the screening value or remediation target value of soil arsenic of the plot. Combined with multiple evidence analyses of plot production history and spatial distribution of soil arsenic, it could be determined that this site was not an arsenic-contaminated plot and that remediation was not required despite individual data exceeding soil arsenic screening values or remediation target values. The study is of great significance in guiding the scientific and rational formulation of the target values for soil heavy metal remediation and avoiding excessive remediation.

     

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