苏州某塑料厂土壤砷修复目标值确定方法研究

Study on the method of determining the target value of arsenic remediation in soil of a plastic factory in Suzhou, China

  • 摘要: 砷作为一种土壤中广泛存在的重金属,可通过经口摄入、皮肤接触、吸入颗粒物等途径进入人体,对健康构成威胁。在污染地块环境管理中,基于健康风险推算的修复目标值远远低于我国各地区的土壤背景值。以苏州某塑料厂地块为研究对象,采用健康风险模型推导、多证据分析技术确定环境背景上限、等效允许摄入量反推等方法确定了土壤砷修复目标值,并分析了其适用性。结果表明:1)采用风险评估方法推算的一类用地情景下砷土壤风险控制值为0.45 mg/kg,即使引入土壤砷经口暴露途径下的生物可给性推荐系数0.65,计算结果0.64 mg/kg仍远低于GB 36600—2018《土壤环境质量 建设用地土壤污染风险管控标准(试行)》规定的土壤污染风险筛选值20 mg/kg,不宜直接作为修复目标值;2)采用相对累积频率分布曲线确定地块土壤砷环境背景上限值为41 mg/kg,此值可作为地块土壤砷筛选值或修复目标值。结合地块生产历史、土壤砷空间分布等多证据分析,可判定此场地并非砷污染地块,尽管个别数据超过土壤砷筛选值或修复目标值,但仍无需修复;3)依据“不同环境介质允许摄入量等效”原则,采用导则推荐参数,由饮用水标准限值对应的砷允许摄入量反推出土壤砷修复目标值为35 mg/kg,进一步对敏感参数“儿童平均每日饮水量”进行本地化赋值(华东地区0.78 L/d)计算,修复目标值为39 mg/kg。此方法制定的砷土壤修复目标值具有一定合理性,在实际场地中也有所应用,但无法判断超过修复目标值的点位是由背景异常还是人为生产活动所致。研究对于指导科学合理制定地块土壤重金属修复目标值,避免过度修复具有重要借鉴意义。

     

    Abstract: Arsenic, as a heavy metal widely present in soil, can enter the human body through oral, skin contact, respiratory particulate matter and other pathways posing a threat to health, and the remediation target value based on health risk projection in the environmental management of contaminated plots is far lower than the soil background value in various regions of China. Taking a plastic factory plot in Suzhou as the research object, the target value of soil arsenic remediation was determined and its applicability was analyzed by using the health risk model derivation, the relative cumulative frequency distribution curve to determine the upper limit of the environmental background, and the inverse deduction of the equivalent allowable intake. The results show that: 1) The risk control value of arsenic soil in a category of land use scenario deduced by the risk assessment method is 0.45 mg/kg, and even if the recommended coefficient of bioavailability of 0.65 under the oral exposure pathway of soil arsenic is introduced, the calculation result is 0.64 mg/kg, which is still far lower than the screening value of 20 mg/kg for soil pollution risk specified in GB 36600-2018 Quality of soil environment Risk control standards for soil contamination of construction land (for trial implementation), it is not suitable to be directly used as the target value for remediation; 2) The relative cumulative frequency curve is used to determine the upper limit of the environmental background of arsenic in the soil of the plot is 41 mg/kg, which can be used as the screening value of arsenic in the soil of the plot or as the target value for remediation. Combined with the production history of this plot, soil arsenic spatial distribution and other evidence analysis, it can be determined that this plot is not arsenic contaminated land, although there are individual data exceeding the soil arsenic screening value or remediation target value, but still do not need to be remediated; 3) According to the principle of equivalence of the allowable intake of different environmental media, the use of the guidelines recommended by the drinking water standards limit value, The soil arsenic remediation target value is 35 mg/kg, and the sensitive parameter(average daily water intake of children) is set to 0.78 L/d in East China, which is calculated to be 39 mg/kg.This method has a certain degree of rationality and has been applied in actual sites, but it is not possible to judge whether the points exceeding the remediation target value are caused by background anomalies or anthropogenic production activities. The study is of great significance in guiding the scientific and reasonable formulation of soil heavy metal remediation target values and avoiding excessive remediation.

     

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