铅污染场地土壤异位淋洗修复技术碳排放特征案例研究

A case study on carbon emission characteristics of soil remediation using ex-situ soil washing technology in lead contaminated site

  • 摘要: 开展土壤修复技术的碳排放评估与优化是破解资源环境约束、推动修复技术进步的基础。淋洗修复技术可有效治理复杂的污染土壤,但其实施过程中的碳排放特征尚缺乏系统研究。以某铅污染场地修复案例为对象,采用IPCC排放因子法评估异位淋洗修复技术的碳排放水平,探究修复过程中碳排放分布规律及其关键影响因素。结果表明:异位淋洗修复案例的碳排放强度为32.68 kg/m3,其中直接碳排放强度和间接碳排放强度分别占17.91%和82.09%。各修复阶段的碳排放量贡献差异明显,造浆淋洗阶段是主要排放环节,占总碳排放量的70.56%。材料投入是淋洗修复技术碳排放的主要来源,淋洗剂乙二胺四乙酸产生的碳排放量占总排放量的67.10%。敏感性分析显示,异位淋洗修复技术的碳排放水平对淋洗剂用量变化具有较高的敏感性,而电力生产结构优化有助于降低修复工程的碳排放量,未来淋洗修复的碳减排研究应重点关注药剂减量化与可再生能源应用措施。研究结果可为推动土壤污染修复技术低碳化发展提供科技支撑。

     

    Abstract: The assessment and optimization of carbon emission levels of remediation technologies is essential for overcoming the resource and environmental constraints and promoting the development of technologies. Ex-situ soil washing technology can effectively remediate complex contaminated soils, but systematic analysis of its carbon emission characteristics during the implementation process is still lacking. Taking a lead-contaminated site as a case study, we evaluated the carbon emission level of ex-situ soil washing technology by using the IPCC emission factor method, and explored the distribution patterns and key influencing factors of carbon emission during the remediation process. The results showed that the carbon emission intensity of the ex-situ soil washing case was 32.68 kg/m3, and the fractions of direct and indirect carbon emission intensity accounted for 17.91% and 82.09%, respectively. There were different contributions in carbon emissions across various processes, with the slurry washing stage being the largest contributor, accounting for 70.56% of the total emission. Material consumption was the primary source of carbon emission, and the amount came from ethylenediamine tetraacetic acid (EDTA) flushing agent occupied 67.10% of the total emission. Sensitivity analysis revealed that the carbon emission level was highly sensitive to changes in the washing agent dosage, and optimizing the power production structure could also help to reduce the total carbon emission. Therefore, the decrease of agent dose and the measures for applying renewable energy shall be further emphasized to optimize the carbon emission of ex-situ soil washing method. The findings offer support for the development of low-carbon remediation technology for soil contamination.

     

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