改性SCR催化剂对燃煤电厂烟气中汞的催化氧化研究进展
Progress in catalytic oxidation of elemental mercury by modified SCR catalysts
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摘要: 针对燃煤电厂烟气中的单质汞(Hg 0)氧化技术,综述了改性SCR(选择性催化还原法)催化剂对Hg 0催化氧化的研究进展,着重阐述了金属氧化物及氯化物掺杂对改性SCR催化剂催化氧化Hg 0性能的影响;探讨了改性物质、掺杂比、烟气组分、温度等对各改性SCR催化剂催化氧化Hg 0性能的影响;从掺杂元素和烟气气氛两方面综合分析了改性SCR催化剂催化氧化Hg 0的异相反应机理。结合目前研究中存在的问题,提出改性SCR催化剂今后的研究方向,并对试验手段提出建议。Abstract: Targeting the oxidation of elemental mercury (Hg 0) in the flue gas from coal-fired power plant, the research progress of the catalytic oxidation by modified selected catalytic reduction (SCR) catalysts for elemental mercury was reviewed, focusing on the influence of metal oxides or chlorides doped SCR catalysts on elemental mercury oxidation. The activity of modified SCR catalysts for elemental mercury was explored from the effects of dopant, doping ratio, flue gas components and temperature. In addition, the heterogeneous reaction mechanisms between elemental mercury and the modified SCR catalysts were analyzed synthetically with respects to doping elements and flue gas conditions. Finally, considering the current situation of coal-fired plants, the prospects of future studies on modified SCR catalyst and the relevant experimental methods were proposed.