留言板

尊敬的读者、作者、审稿人, 关于本刊的投稿、审稿、编辑和出版的任何问题, 您可以本页添加留言。我们将尽快给您答复。谢谢您的支持!

姓名
邮箱
手机号码
标题
留言内容
验证码

饮用水处理厂锰砂滤料对苯酚的吸附性能及影响因素

孙晓玲,  杨昱,  马志飞,  姜永海,  董子萱,  廉新颖

downloadPDF
文章导航 > 环境工程技术学报  > 2018 >  8(5): 510-518
孙晓玲, 杨昱, 马志飞, 姜永海, 董子萱, 廉新颖. 饮用水处理厂锰砂滤料对苯酚的吸附性能及影响因素[J]. 环境工程技术学报, 2018, 8(5): 510-518. doi: 10.3969/j.issn.1674-991X.2018.05.067
引用本文: 孙晓玲, 杨昱, 马志飞, 姜永海, 董子萱, 廉新颖. 饮用水处理厂锰砂滤料对苯酚的吸附性能及影响因素[J]. 环境工程技术学报, 2018, 8(5): 510-518. doi: 10.3969/j.issn.1674-991X.2018.05.067
shu
SUN Xiaoling, YANG Yu, MA Zhifei, JIANG Yonghai, DONG Zixuan, LIAN Xinying. Adsorption performance and influencing factors of manganese sand filter media on phenol removal in drinking water treatment plant[J]. Journal of Environmental Engineering Technology, 2018, 8(5): 510-518. doi: 10.3969/j.issn.1674-991X.2018.05.067
Citation: SUN Xiaoling, YANG Yu, MA Zhifei, JIANG Yonghai, DONG Zixuan, LIAN Xinying. Adsorption performance and influencing factors of manganese sand filter media on phenol removal in drinking water treatment plant[J]. Journal of Environmental Engineering Technology, 2018, 8(5): 510-518. doi: 10.3969/j.issn.1674-991X.2018.05.067
shu

饮用水处理厂锰砂滤料对苯酚的吸附性能及影响因素

doi: 10.3969/j.issn.1674-991X.2018.05.067

  • 1. 上海大学环境化学与工程学院,上海 200444

  • 2. 中国环境科学研究院,北京 100012

  • 3. 同济大学环境科学与工程学院,上海 200092

详细信息
    作者简介:

    孙晓玲(1992—),女,硕士研究生,主要从事地下水污染修复技术研究

  • 中图分类号: X703

Adsorption performance and influencing factors of manganese sand filter media on phenol removal in drinking water treatment plant

  • 1. School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, China

  • 2. Chinese Research Academy of Environmental Sciences, Beijing 100012, China

  • 3. College of Environmental Science and Engineering, Tongji University, Shanghai 200092, China

    摘要
  • 摘要: 为了解锰砂滤料对苯酚的吸附性能和影响因素,以生物锰砂滤池运行结束后产生的废料为吸附剂,研究了不同初始pH、温度和溶解氧条件下锰砂滤料对苯酚的吸附性能,通过吸附动力学模型和吸附等温线模型研究其吸附规律。结果表明:锰砂滤料对苯酚的吸附过程符合内扩散动力学模型和Temkin吸附等温线模型,每单分子层吸附,吸附效果主要受苯酚扩散速率影响。通过对吸附等温线n值的计算发现,锰砂滤料容易吸附苯酚。pH对锰砂滤料去除苯酚的影响最大,初始pH为3.0时,苯酚可完全去除,随着初始pH的升高,苯酚的去除率逐渐减小。中性条件下,溶解氧浓度对苯酚的吸附作用影响不大,低温时可通过增加锰砂滤料投加量提高苯酚去除率,每增加1.5倍锰砂滤料,苯酚去除率约增加20个百分点。锰砂滤料可应用于地下水中的苯酚去除,达到废料再利用,不产生二次污染。

     

    Abstract: In order to understand the adsorption performance and influencing factors of manganese sand filter material on phenol, the waste material produced after the operation of biological manganese sand filter was used as adsorbent. The adsorption performance of manganese sand filter material on phenol under different pH, temperature and dissolved oxygen conditions was studied respectively. The adsorption law of manganese sand filter material was studied by adsorption kinetic model and adsorption isotherm model. The results showed that the adsorption process of manganese sand media for phenol was in accordance with the internal diffusion kinetic model and Temkin isothermal adsorption model, being the monolayer adsorption. The adsorption effect was mainly affected by the diffusion rate of phenol. Through the calculation of n value of adsorption isotherm, it is found that manganese sand filter material is easy to adsorb phenol. The pH had the greatest effect on the removal of phenol from manganese sand filter. When pH=3.0, phenol could be removed completely. The removal rate of phenol decreased gradually with the increase of pH. The effect of hypoxia on phenol adsorption was not significant under neutral condition. The removal rate of phenol was increased by increasing the dosage of manganese sand filter material under low temperature condition. The removal rate of phenol was increased 20 percent for every 1.5 times of manganese sand filter material. When that manganese sand filter material is applied to remove phenol from the underground water, the method should achieve the good effect of recycling waste and repairing phenol pollute water body, does not generate secondary pollution phenomenon, and has good application prospects.

     

    • HTML全文
    • 参考文献(53)
  • [1] MENG X, ZHANG Z . Synjournal and characterization of plasmonic and magnetically separable Ag∕AgCl-Bi2WO6@Fe3O4@SiO2 core-shell composites for visible light-induced water detoxification[J]. Journal of Colloid & Interface Science, 2017,485:296-307.
    [2] NA J G, LEE M K, YUN Y M , et al. Microbial community analysis of anaerobic granules in phenol-degrading UASB by next generation sequencing[J]. Biochemical Engineering Journal, 2016,112:241-248.
    [3] ZHAO H P, WU Q S, WANG L , et al. Degradation of phenanthrene by bacterial strain isolated from soil in oil refinery fields in Shanghai China[J]. Journal of Hazardous Materials, 2009,164(2):863-869.
    doi: 10.1016/j.jhazmat.2008.08.098 pmid: 18930349
    [4] LIU N, LIANG G, DONG X , et al. Stabilized magnetic enzyme aggregates on graphene oxide for high performance phenol and bisphenol-A removal[J]. Chemical Engineering Journal, 2016,306:1026-1034.
    doi: 10.1016/j.cej.2016.08.012
    [5] LEFEBVRE O, MOLETTA R . Treatment of organic pollution in industrial saline wastewater:a literature review[J]. Water Research, 2006,40(20):3671-3682.
    doi: 10.1016/j.watres.2006.08.027 pmid: 17070895
    [6] NUHOGLU A, YALCIN B . Modelling of phenol removal in a batch reactor[J]. Process Biochemistry, 2005,40(3∕4):1233-1239.
    doi: 10.1016/j.procbio.2004.04.003
    [7] 地下水质量标准:GB∕T 14848—2017[S] 下水质量标准: GB∕T 14848—2017[S].北京:中国标准出版社, 2017.
    [8] EICHELBERGER J W, MUNCH J W, SHOEMAKER J A . Determination of organic compounds in drinking water by liquid-solid extraction and capillary column gas chromatography∕mass spectrometry[M]. Cincinnati:US Environmental Protection Agency, 1994.
    [9] NAIR C I, JAYACHANDRAN K, SHASHIDHAR S . Biodegradation of phenol[J]. African Journal of Biotechnology, 2008,7(25):4951-4958.
    [10] 刘佳露, 卢伟, 张凤君 , 等. 活化过硫酸盐氧化地下水中苯酚的动力学研究[J]. 中国环境科学, 2015,35(9):2677-2681.

    LIU J L, LU W, ZHANG F J , et al. Kinetics study of activated persulfate oxidation of phenol in ground water[J]. China Environmental Science, 2015,35(9):2677-2681.
    [11] GAO X, ZHAI X, WANG Z , et al. Effective adsorption of phenol from aqueous solutions on activated semi-coke[J]. Journal of Physics & Chemistry of Solids, 2017,102:142-150.
    doi: 10.1007/s10853-015-8971-7
    [12] MA J, LI H, CHI L , et al. Changes in activation energy and kinetics of heat-activated persulfate oxidation of phenol in response to changes in pH and temperature[J]. Chemosphere, 2017,189:86-93.
    doi: 10.1016/j.chemosphere.2017.09.051 pmid: 28934658
    [13] SARAVANAKUMAR K, MUTHURAJ V . Fabrication of sphere like plasmonic Ag∕SnO2,photocatalyst for the degradation of phenol[J]. Optik-International Journal for Light and Electron Optics, 2016,131:754-763.
    doi: 10.1016/j.ijleo.2016.11.127
    [14] XU B, CHEN L, XING B , et al. Physicochemical properties of Hebi semi-coke from underground coal gasification and its adsorption for phenol[J]. Process Safety & Environmental Protection, 2017,107:147-152.
    doi: 10.1016/j.psep.2017.02.007
    [15] CHENG W P, GAO W, CUI X , et al. Phenol adsorption equilibrium and kinetics on zeolite X∕activated carbon composite[J]. Journal of the Taiwan Institute of Chemical Engineers, 2016,62:192-198.
    doi: 10.1016/j.jtice.2016.02.004
    [16] YANG K, ZHU L, YANG J , et al. Adsorption and correlations of selected aromatic compounds on a KOH-activated carbon with large surface area[J]. Science of the Total Environment, 2017,618:1677-1684.
    doi: 10.1016/j.scitotenv.2017.10.018 pmid: 29054641
    [17] 刘晓红, 王芳, 王任震 , 等. 核桃果皮基活性炭对苯酚吸附的热力学研究[J]. 安全与环境学报, 2015,15(4):236-239.

    LIU X H, WANG F, WANG R Z , et al. On the thermodynamic principle for the walnut peel-activated carbon to adsorb phenol[J]. Journal of Safety and Environment, 2015,15(4):236-239.
    [18] 杨晓霞, 郭延红, 郑小峰 , 等. 活性炭的制备及其对苯酚的吸附[J]. 环境工程学报, 2016,10(12):7030-7034.

    YANG X X, GUO Y H, ZHENG X F , et al. Preparation of activated carbon and its adsorption of phenol[J]. Chinese Journal of Environmental Engineering, 2016,10(12):7030-7034.
    [19] 陈焕利, 邢宝林, 谌伦建 , 等. 有机膨润土对模拟废水中苯酚的吸附特性[J]. 化工进展, 2017,36(2):735-741.

    CHEN H L, XING B L, CHAN L J , et al. Adsorption of phenol from simulated wastewater by organic bentonite[J]. Chemical Industry and Engineering Progress, 2017,36(2):735-741.
    [20] MOSHE S B, RYTWO G . Thiamine-based organoclay for phenol removal from water[J]. Applied Clay Science, 2018,155:50-56.
    doi: 10.1016/j.clay.2018.01.003
    [21] 林森, 杨维, 施爽 , 等. OH-Fe-有机柱撑膨润土的制备及其对苯酚的吸附试验研究[J]. 华中师范大学学报(自科版), 2010,44(2):264-268.

    LIN S, YANG W, SHI S , et al. Research on manufacture of the OH-Fe-organo pillaring bentonite and its absorption properties to phenol[J]. Journal of Central China Normal University(Natural Sciences), 2010,44(2):264-268.
    [22] TOURNASSAT C, CHARLET L, BOSBACH D , et al. Arsenic(Ⅲ) oxidation by birnessite and precipitation of manganese(Ⅱ)arsenate[J]. Environmental Science & Technology, 2002,36(3):493-500.
    doi: 10.1021/es0109500 pmid: 11871566
    [23] BRUINS J H, PETRUSEVSKI B, SLOKAR Y M , et al. Biological and physico-chemical formation of Birnessite during the ripening of manganese removal filters[J]. Water Research, 2015,69:154.
    doi: 10.1016/j.watres.2014.11.019 pmid: 25463936
    [24] ASMALY H A, ABUSSAUD B , IHSANULLAH,et al.Evaluation of micro and nano carbon-based adsorbents for the removal of Phenol from aqueous solutions[J]. Toxicological & Environmental Chemistry, 2015,97(9):1164-1179.
    doi: 10.1080/02772248.2015.1092543
    [25] 杨柳燕, 周治, 肖琳 , 等. HDTMA改性蒙脱土吸附苯酚后的化学和生物再生[ C] ∕∕南京科技学术年会.南京市科协:南京:南京科学技术协会, 2005.
    [26] 谷峥, 高芒来, 罗忠新 , 等. 系列双吡啶盐改性膨润土的制备及其对苯酚的吸附性能研究[J]. 硅酸盐通报, 2012,31(5):309-315.

    GU Z, GAO M L, LUO Z X , et al. Preparation of bentonite modified by a series of bis-pyridinium dibromides and their adsorption of phenol for aqueous solution[J]. Bulletin of the Chinese Ceramic Society, 2012,31(5):309-315.
    [27] VRIES D, BERTELKAMP C, SCHOONENBERG K F , et al. Iron and manganese removal:recent advances in modelling treatment efficiency by rapid sand filtration[J]. Water Research, 2016,109:35-45.
    doi: 10.1016/j.watres.2016.11.032 pmid: 27865171
    [28] 李博瑶, 罗彤, 李欣 . 不同锰砂滤料除锰吸附特性研究[J]. 供水技术, 2014,8(3):13-16.

    LI B Y, LUO T, LI X . Adsorption characteristics of different manganese sand filter media[J]. Water Technology, 2014,8(3):13-16.
    [29] 梁冠男, 廉新颖, 贾永锋 , 等. 化学合成及废物基锰氧化物对不同形态砷的去除转化机制[J]. 环境科学研究, 2017,30(10):1622-1629.

    LIANG G N, LIAN X Y , JIA Y F,et.al.Removal and species transformation mechanism of arsenic by chemical synthetic and waste-based manganese oxides[J]. Research of Environmental Sciences, 2017,30(10):1622-1629.
    [30] BAI Y, CHANG Y, LIANG J , et al. Treatment of groundwater containing Mn(Ⅱ),Fe(Ⅱ),As(Ⅲ)and Sb(Ⅲ)by bioaugmented quartz-sand filters[J]. Water Research, 2016,106:126-134.
    [31] GÜRSES A, DO G ̆ AR C , YALÇIN M , et al. The adsorption kinetics of the cationic dye,methylene blue,onto clay[J]. Journal of Hazardous Materials, 2006,131(1):217-228.
    doi: 10.1016/j.jhazmat.2005.09.036 pmid: 16257117
    [32] CHEN M, XU P, ZENG G , et al. Bioremediation of soils contaminated with polycyclic aromatic hydrocarbons,petroleum,pesticides,chlorophenols and heavy metals by composting:applications,microbes and future research needs[J]. Biotechnology Advances, 2015,33(6):745.
    doi: 10.1016/j.biotechadv.2015.05.003 pmid: 26008965
    [33] BANERJEE P . Phenol adsorption onto various soil composite membranes:insight into process kinetics,modelling and optimisation using response surface methodolog[J]. Astrophysical Journal, 2015,207(2):414-424.
    [34] ALKARAM U F, MUKHLIS A A, ALDUJAILI A H . The removal of phenol from aqueous solutions by adsorption using surfactant-modified bentonite and kaolinite[J]. Journal of Hazardous Materials, 2009,169(1∕2∕3):324.
    doi: 10.1016/j.jhazmat.2009.03.153 pmid: 19464105
    [35] SONG W, GAO B, XU X , et al. Adsorption-desorption behavior of magnetic amine∕Fe3O4 functionalized biopolymer resin towards anionic dyes from wastewater[J]. Bioresource Technology, 2016,210(1):123.
    doi: 10.1016/j.biortech.2016.01.078 pmid: 26852273
    [36] WRIGHT M H, FAROOQUI S M, WHITE A R , et al. Production of manganese oxide nanoparticles by shewanella species[J]. Applied & Environmental Microbiology, 2016,82(17):5402.
    doi: 10.1128/AEM.00663-16 pmid: 4988204
    [37] DUCKWORTH O W, RIVERA N A, GARDNER T G , et al. Morphology,structure,and metal binding mechanisms of biogenic manganese oxides in a superfund site treatment system[J]. Environmental Science Processes & Impacts, 2017,19(1):50.
    doi: 10.1039/c6em00525j pmid: 27942631
    [38] MURRAY J W . Surface chemistry of hydrous manganese dioxide[J]. Journal of Colloid & Interface Science, 1974,46(3):357-371.
    doi: 10.1016/0021-9797(74)90045-9
    [39] 董子萱, 廉新颖, 姜永海 , 等. 水羟锰矿去除地下水中苯酚的影响因素及机理[J]. 环境工程学报, 2017,11(8):4481-4488.

    DONG Z X, LIAN X Y, JIANG Y H , et al. Impact factors and mechanism of phenol removal in groundwater by vernadite[J]. Chinese Journal of Environmental Engineering, 2017,11(8):4481-4488.
    [40] HAMMOUDA S B, ZHAO F, SAFAEI Z , et al. Reactivity of novel Ceria-Perovskite composites CeO2-LaMO3,(M,Cu,Fe)in the catalytic wet peroxidative oxidation of the new emergent pollutant‘bisphenol F’:characterization,kinetic and mechanism studies[J]. Applied Catalysis B:Environmental, 2017,218:119-136.
    [41] BHAVNA S, RITESH T, AJAY S . Equilibrium,kinetics,and breakthrough curve of phenol sorption on zeolitic material derived from BFA[J]. Journal of Dispersion Science & Technology, 2012,33(1):41-51.
    doi: 10.1080/01932691.2010.530079
    [42] YANG G, CHEN H, QIN H , et al. Amination of activated carbon for enhancing phenol adsorption:effect of nitrogen-containing functional groups[J]. Applied Surface Science, 2014,293(3):299-305.
    doi: 10.1016/j.apsusc.2013.12.155
    [43] CHEN Z, ZHANG J, FU J , et al. Adsorption of methylene blue onto poly(cyclotriphosphazene-co-4,4sulfonyldiphenol)nanotubes:kinetics,isotherm and thermodynamics analysis[J]. Journal of Hazardous Materials, 2014,273:263-271.
    doi: 10.1016/j.jhazmat.2014.03.053 pmid: 24751492
    [44] RATCLIFF R, SMITH P L, BROWN S D , et al. Diffusion decision model:current issues and history[J]. Trends in Cognitive Sciences, 2016,20(4):260-281.
    doi: 10.1016/j.tics.2016.01.007 pmid: 26952739
    [45] NGUYEN T H, LANOISELLÃ J L, ALLAF T , et al. Experimental and fundamental critical analysis of diffusion model of airflow drying[J]. Drying Technology, 2016,34(15):1884-1899.
    doi: 10.1080/07373937.2016.1155052
    [46] ISLAM M T, AIMONE F, FERRI A , et al. Use of N-methylformanilide as swelling agent for meta-aramid fibers dyeing:kinetics and equilibrium adsorption of Basic Blue 41[J]. Dyes & Pigments, 2015,113(2):554-561.
    [47] 李亚娟, 赵传起, 洪沛东 , 等. 磁性还原石墨烯的制备及其对抗生素的吸附性能[J]. 环境工程学报, 2018,12(1):15-24.

    LI Y J, ZHAO C Q, HONG P D , et al. Fabrication of magnetic reduced graphene and its adsorption performance for antibiotics[J]. Chinese Journal of Environmental Engineering, 2018,12(1):15-24.
    [48] 熊劲芳, 刘晓春, 李国希 . 溶解氧对活性炭纤维吸附酚类化合物的影响[J]. 湖南大学学报(自然科学版), 2004,31(5):5-8.

    XIONG J F, LIU X C, LI G X . Impact of dissolved oxygen on the adsorption of phenolic compounds by activated carbon fiber[J]. Journal of Hunan University(Natural Sciences), 2004,31(5):5-8.
    [49] 宋忠来, 徐东彦, 张宇松 , 等. 煤质活性炭对苯酚吸附动力学研究[J]. 山东化工, 2015,44(3):4-5.

    SONG Z L, XU D Y, ZHANG Y S , et al. Adsorption kinetics of activated carbon for phenol[J]. Shandong Chemical Industry, 2015,44(3):4-5.
    [50] 张中路, 田志红, 黄佳佳 , 等. 含氧超高交联树脂制备及对苯胺和苯酚的吸附性能研究[J].离子交换与吸附, 2017(4):301-312.

    ZHANG Z L, TIAN Z H, HUANG J J , et al. Synjournal of hypercrosslinked resin containing oxygen and its adsorption for phenol and aniline[J].Ion Exchange and Adsorption, 2017(4):301-312.
    [51] HUANG R, YANG B, LIU Q , et al. Multifunctional activated carbon∕chitosan composite preparation and its simultaneous adsorption of phenol and Cr(Ⅵ)from aqueous solutions[J]. Environmental Progress & Sustainable Energy, 2014,33(3):814-823.
    doi: 10.1002/ep.11844
    [52] LUO Z, GAO M, YANG S , et al. Adsorption of phenols on reduced-charge montmorillonites modified by bispyridinium dibromides:mechanism,kinetics and thermodynamics studies[J]. Colloids & Surfaces A:Physicochemical & Engineering Aspects, 2015,482:222-230.
    doi: 10.1016/j.colsurfa.2015.05.014
    [53] ABDELGHANI N T, ELCHAGHABY G A, HELAL F S . Individual and competitive adsorption of phenol and nickel onto multiwalled carbon nanotubes[J]. Journal of Advanced Research, 2015,6(3):405.
    doi: 10.1016/j.jare.2014.06.001 pmid: 4522546
    • 相关文章
    • 施引文献
  • 资源附件(0)
  • 加载中
WeChat 点击查看大图
计量
  • 文章访问数:  598
  • HTML全文浏览量:  95
  • PDF下载量:  485
  • 被引次数: 0
出版历程
  • 收稿日期:  2018-04-16
  • 刊出日期:  2018-09-20

目录

    /

    返回文章
    返回

    版权所有 © 《环境工程技术学报》编辑部 京ICP备05031605号-2

    本系统由 北京仁和汇智信息技术有限公司 设计开发