Discussion on thermal desorption remediation technology with rotary kiln for petrochemical contaminated soil
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摘要: 石油化工污染土壤以有机污染物为主,包括苯系物(BTEX)、多环芳烃(PAHs)、多氯联苯(PCBs)、总石油烃(TPH)等,转窑式热解吸修复技术是适合我国石油化工污染土壤修复的高效技术之一,具有良好的应用前景。主要从技术原理、技术特点、技术分类、尾气处理和影响因素等对该类热解吸修复技术进行了详细分析和探讨。该技术在节能降耗和自主集成开发领域仍有较大的技术提升空间,需对回转窑的高温出土和高温烟气余热进一步加以利用,以提高热效率;同时应加快开发适合我国国情且具有自主知识产权的土壤热解吸修复及尾气处理设备。Abstract: Organic contaminants, including BTEX, PAHs, PCBs, TPH, etc., are the main pollutants in the petrochemical contaminated soil. Thermal desorption technology with rotary kiln, which has a good application prospect, is an efficient and suitable technology for the remediation of soil contaminated by petrochemical industry in China. The thermal desorption remediation technology was analyzed and discussed in detail from the aspects of technical principle, technical characteristics, technical classification, tail gas treatment and influence factors. The technology still has a space for enhancement in the areas of energy saving and cost reduction and independent integrated development. It is necessary to improve the thermal efficiency by further utilizing the waste heat in the soil and tail gas with high temperature from the rotary kiln. In addition, the development should be accelerated for the soil thermal desorption recovery and tail gas treatment devices which are suitable for China's national conditions and have independent intellectual property rights.
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Key words:
- petrochemical industry /
- soil remediation /
- thermal desorption /
- rotary kiln
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[1] 廖晓勇, 崇忠义, 阎秀兰 , 等. 城市工业污染场地:中国环境修复领域的新课题[J]. 环境科学, 2011,32(3):784-794.LIAO X Y, CHONG Z Y, YAN X L , et al. Urban industrial contaminated sites:a new issue in the field of environmental remediation in China[J]. Environmental Science, 2011,32(3):784-794. [2] 刘乙敏, 李义纯, 肖荣波 . 西方国家工业污染场地管理经验及其对中国的借鉴[J]. 生态环境学报, 2013,22(8):1438-1443.LIU Y M, LI Y C, XIAO R B . Management experience of industrial contaminated sites in western countries and its implications for China[J]. Ecology and Environmental Sciences, 2013,22(8):1438-1443. [3] 骆永明 . 中国土壤环境污染态势及预防、控制和修复策略[J]. 环境污染与防治, 2009,31(12):27-31.LUO Y M . Trends in soil environment pollution and the prevention-controlling-remediation strategies in China[J]. Environmental Pollution & Control, 2009,31(12):27-31. [4] 姚耀富 . 原“小南化”地块土壤修复将全部完成[J]. 化工安全与环境, 2013(45):19. [5] FALCIGLIA P P, GIUSTRA M G, VAGLIASINDI F G . Low-temperature thermal desorption of diesel polluted soil:influence of temperature and soil texture on contaminant removal kinetics[J]. Journal of Hazardous Materials, 2011,185(1):392-400. [6] HALMEMIES S, GRONDAHL S, ARFFMAN M , et al. Vacuum extraction based response equipment for recovery of fresh fuel spills from soil[J]. Journal of Hazardous Materials, 2003,97(3):127-143. [7] HO S V, SHERIDAN P W, ATHMER C J . Integrated in situ soil remediation technology:the lasagna process[J]. Environmental Science & Technology, 1995,29(10):2528-2534. [8] LOIC K N, HOBBS P J, HALE M D C, et al. Bioremediation of poly-aromatic hydrocarbon (PAH)-contaminated soil by composting[J]. Critical Reviews in Environmental Science & Technology, 2009,39(4):271-332. [9] 耿春雷, 顾军, 於定新 . 高温热解吸在多环芳烃污染土修复中的应用[J]. 材料导报, 2012,26(2):126-129.GENG C L, GU J, YU D X . Application of high temperature thermal decomposition in repairing PAHs polluted soil[J]. Materials Review, 2012,26(2):126-129. [10] 殷甫祥 . 气相抽提法(SVE)去除污染土壤中挥发性有机物(VOCs)的技术研究[D]. 扬州:扬州大学, 2010. [11] 孙燕英, 陈鸿汉, 何炜 , 等. 土壤中石油类污染物的化学氧化去除研究[J]. 土壤, 2008,40(1):130-134.SUN Y Y, CHEN H H, HE W , et al. Removal of petroleum contaminants in soil through chemical oxidation[J]. Soils, 2008,40(1):130-134. [12] 徐春明, 杨朝合 . 石油炼制工程[M]. 4版. 北京: 石油工业出版社, 2011: 1-3. [13] 周启星, 宋玉芳 . 污染土壤修复原理与方法[M]. 北京: 科学出版社, 2004: 376-378. [14] PIÑA J, MERINO J, ERRAZU A F , et al. Thermal treatment of soils contaminated with gas oil: influence of soil composition and treatment temperature[J]. Journal of Hazardous Materials, 2002,94(3):273-290. [15] 黄凯 . 回转窑运行状态巡检系统研究[D]. 武汉:武汉理工大学, 2010. [16] 工业和信息化部. 化工回转窑设计规定:HG/T 20566—2011[S]. 北京: 中国计划出版社, 2011. [17] US Environmental Protection Agency. Remediation case studies:ex situ soil treatment technologies(bioremediation,solventextraction,thermal desorption)[R]. Washington DC:Member Agencies of the Federal Remediation Technologies Roundtable, 1998: 102-103. [18] 中国环境网. 中加合作示范项目“土壤热相分离技术(TSP)工程化应用”[EB/OL].( 2012 -06-29).http://www.hjxf.net/2012/0629/7638.html. [19] 中国江苏网. 毒地“消毒”新生记[EB/OL].( 2012 -07-12).http://jsnews2.jschina.com.ch/system/2012/07/12/013751009-01.shtml. [20] 霍崇 . 土壤中多环芳烃的SPMD辅助鲜吸行为及其生物有效性表征[D]. 天津:南开大学, 2006. [21] 张瑜 . 土壤中有机污染物解吸行为的研究[D]. 天津:南开大学, 2007. [22] BUCALA V, SAITO H, HOWARD J B , et al. Thermal treatment of fuel oil-contaminated soils under rapid heating conditions[J]. Environmental Science and Technology, 1994,28(11):1801-1807. [23] 王瑛, 李扬, 黄启飞 , 等. 污染物浓度与土壤粒径对热脱附修复DDTs污染土壤的影响[J]. 环境科学研究, 2011,24(9):1016-1022.WANG Y, LI Y, HUANG Q F , et al. Effects of different pollutant concentrations and soil particle size on thermal desorption efficiency of DDT-contaminated soil[J]. Research of Environmental Sciences, 2011,24(9):1016-1022. [24] 廖志强, 朱杰, 罗启仕 , 等. 污染土壤中苯系物的热解吸[J]. 环境化学, 2013,32(4):646-650.LIAO Z Q, ZHU J, LUO Q S , et al. Thermodesorption of BTEX-contaminated soil[J]. Environmental Chemistry, 2013,32(4):646-650. [25] LIGHTY J A S, SILCOX G D, PERSHING D W , et al. Fundamentals for the thermal remediation of contaminated soils[J]. Environmental Science & Technology, 1990,24(5):750-757. [26] VINEETAM, SVRCEK W Y, MEHROTRA A K , et al. A study of interactions between soil fractions and PAH compounds in thermal desorption of contaminated soils[J]. Canadian Journal of Chemical Engineering, 1995,73(6):844-853. [27] RISOUL V, PICHON C, TROUVÉ G , et al. Thermogravimetric study of thermal decontamination of soils polluted by hexachlorobenzene,4-chlorobiphenyl,naphthalene,or n-decane[J]. Journal of Hazardous Materials, 1999,64(3):295-311. [28] LEE J K, PARK D, KIM B U , et al. Remediation of petrolecm-contaminated soils by fluidized thermal desorption[J]. Waste Management, 1998,18(6/7/8):503-507. [29] 林芳芳, 丛鑫, 马福俊 , 等. 处理温度和时间对六氯苯污染土壤热解吸修复的影响[J]. 环境科学研究, 2014,27(10):1180-1185.LIN F F, CONG X, MA F J , et al. Effects of treatment temperature and time on thermal desorption remediation of hexachlorobenzene-contaminated soil[J]. Research of Environmental Sciences, 2014,27(10):1180-1185. [30] MERINO J, BUCALÁ V . Effect of temperature on the release of hexadecane from soil by thermal treatment[J]. Journal of Hazardous Materials, 2007,143(1/2):455-461. [31] RISOUL V, RENAULD V, TROUVÉ G , et al. A laboratory pilot study of thermal decontamination of soils polluted by PCBs:comparison with thermogravimetric analysis[J]. Waste Management, 2002,22(1):61-72. [32] 高国龙, 蒋建国, 李梦露 . 有机物污染土壤热脱附技术研究与应用[J]. 环境工程, 2012,30(1):128-131.GAO G L, JIANG J G, LI M L . Study on thermal desorption of organic contaminated soil and its application[J]. Environmental Engineering, 2012,30(1):128-131.
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