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摘要: 以沸石分子筛为吸附剂,采用批次试验,研究静态吸附对水中2,4-二甲基苯酚(2,4-DMP)的吸附去除效果,比较了3种不同类型的沸石分子筛对2,4-DMP的吸附性能,选择其中吸附性能最好的沸石分子筛FAU-Y为吸附剂,分别考察了溶液初始pH、吸附剂投加量对吸附效果的影响,并对吸附动力学和吸附等温线进行了分析。结果表明,FAU-Y对2,4-DMP具有较大的吸附量,在2,4-DMP初始浓度为250 mg/L,溶液初始pH为5.2,吸附剂投加量为5.0 g/L时,室温条件下反应24 h可以达到吸附平衡状态,饱和吸附容量为48.22 mg/g;初始pH为2.0~9.3时,对FAU-Y吸附2,4-DMP没有明显影响;吸附动力学和吸附等温线分析结果表明,二级动力学能更好地描述FAU-Y对2,4-DMP的吸附,Langmuir-Freundlich吸附等温线对吸附平衡数据的拟合优于Langmuir吸附等温线和Freundlich吸附等温线。Abstract: The adsorption removal of 2,4-dimethyphenol (2,4-DMP) in aqueous phase was investigated by using zeolite in a batch statistic adsorption system. The 2,4-DMP adsorption capabilities of three different zeolites were compared, and FAU-Y zeolite was chosen as the adsorbent for its best adsorption capabilities. The effects of initial pH and adsorbent dosage on 2,4-DMP adsorption were investigated respectively, and the adsorption kinetics and isotherms analyzed. The results showed that FAU-Y zeolite had high adsorption ability for 2,4-DMP. The equilibrium of the adsorption process was established in about 24.0 h under the conditions of initial 2,4-DMP concentration 250 mg/L, initial pH 5.2, FAU-Y zeolite dosage 5.0 g/L and temperature 20 oC, with a saturated adsorption capability of 48.22 mg/g. The initial pH from 2.0 to 9.3 had no significant influence on 2,4-DMP adsorption removal. The comparison of adsorption kinetic models showed that the adsorption process was better described by a second-order adsorption kinetic model. The isotherm analysis showed that the adsorption equilibrium data fit better with Langmuir-Freundlich isotherm than with the Langmuir isotherm and Freundlich isotherm.
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Key words:
- adsorption /
- zeolite /
- 2,4-dimethyphenol /
- kinetics /
- isotherm
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