Abstract: It is an important aspect of environmental management to guarantee the industrial pollution emission in compliance with the standards. The compliance assessment needs to adopt the idea of the whole process control and track the emission dynamically. On the basis of projecting the emissions of pollutants, the assessment method for emission compliance feasibility of pollution sources of non-ferrous smelting enterprises was proposed, including the Emission Coefficient and Emission Model methods. The non-ferrous smelting pollution source emission compliance and dynamic management system (N-FSPSECDMS) was developed. The system with Emissions Model method was chosen to evaluate the pollution emission from chimneys of anode stove in enterprise A. The results showed: the SO₂ emission concentration (538 mg/m³) from anode furnace cannot meet with the emission standard requirement, and thus three options to increase the environmental performance were proposed including saving energy, performing clean production audit and establishing environmental management system. According to modeling and optimization of the system, the SO₂ emission concentration of the three options were 370, 365 and 292 mg/m³ respectively, all meeting with the emission standard.