Bibliometric analysis of MOFs in the field of water treatment applications
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摘要:
金属有机框架（MOFs）材料具有比表面积大、孔隙率高，结构和功能可调等优异特性，在水处理领域应用广泛。为深入了解MOFs在水处理应用领域的研究热点和发展趋势，采用文献计量学方法，利用VOSviewer软件对Web of ScienceTM核心合集数据库中MOFs在水处理应用领域相关文献进行定量分析。结果表明：1995—2021年MOFs在水处理应用领域研究发文量共1 281篇，发文量总体呈逐年递增的趋势；中国是该研究领域发文量和总被引次数最高的国家，发文量达800篇，但篇均被引次数相对较低；Jhung S H是该领域最富有成效的作者，其发表的14篇论文总被引次数为1 657次。该领域研究热点为使用MOFs改性复合升级材料（如MOFs衍生碳、MOFs膜等）及运用吸附去除、催化降解等方式处理水中的染料、重金属离子等典型污染物，未来应注重低廉高效合成方法的探索，材料稳定性和可重复性的提升以及改性方式和污染物结构特性的构效关系，复合物或衍生物的作用机制等方面的研究。
Abstract:Metal-organic frameworks (MOFs) are widely used in water treatment due to their excellent properties such as large specific surface area, high porosity, and tunable structure and function. In order to deeply understand the research hotspots and growing trends of MOFs in the field of water treatment applications, the bibliometrics method was used, and the VOSviewer software was used to quantitatively analyze the related papers of MOFs in the field of water treatment applications in the Web of ScienceTM core collection database. The results show that: from 1995 to 2021, MOFs published a total of 1 281 papers in the field of water treatment applications, and the number of papers generally increased year by year; China was the country with the highest total number of papers and total citations in this field, with a total of 800, but with relatively low citations per paper; Jhung S H is the most productive author in the field, with 14 published papers and a total of 1 657 citations. The research hotspot is the modification and compound of MOFs materials (such as MOFs-derived carbon, MOFs membrane, etc.), and the use of adsorption removal, catalytic degradation and other methods to treat typical pollution such as dyes and heavy metal ions in water. In the future, attention should be paid to the exploration of inexpensive and efficient synthesis methods, the improvement of material stability and reproducibility, the structure-activity relationship between modification methods and the structural characteristics of pollutants, and the study of the mechanism of action of complexes or derivatives.
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Key words:
- bibliometric /
- water treatment /
- metal-organic frameworks /
- research hotspot /
- growing trend
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图 1 2006—2021年MOFs在水处理应用领域研究的发文量与被引情况
Figure 1. Annual number of articles and citation conditions of MOFs in the application field of water treatment from 2006 to 2021
图 2 2014—2021年MOFs在水处理应用领域研究论文发展的时空特征
Figure 2. Spatiotemporal characteristics of the development of paper on MOFs in water treatment applications from 2014 to 2021
图 3 MOFs在水处理应用领域作者之间的协作网络
Figure 3. Collaborative network among authors of MOFs in the application field of water treatment
图 4 MOFs在水处理应用领域研究各机构之间的协作网络
Figure 4. Collaborative network between institutions of MOFs in the application field of water treatment
图 5 MOFs在水处理应用领域的热点聚类
Figure 5. Hotspot cluster of MOFs in the application field of water treatment
表 1 MOFs在水处理应用领域研究总被引次数最高的前10篇论文
Table 1. The top 10 most cited papers of MOFs in the application field of water treatment
篇名 作者 发文期刊 被引次
数/次Photocatalytic organic pollutants degradation in metal-organic frameworks Wang C C Energy & Environmental Science 1058 Removal of hazardous organics from water using metal-organic frameworks (MOFs): plausible mechanisms for selective adsorptions Hasan Z Journal of Hazardous Materials 821 Applications of water stable metal-organic frameworks Wang C H Chemical Society Reviews 651 State-of-the-art membrane based CO2 separation using mixed matrix membranes (MMMs): an overview on current status and future directions Rezakazemi M Progress in Polymer Science 539 Recent development of advanced materials with special wettability for selective oil/water separation Ma Q L Small 502 Direct sysnthesis of MOF-derived nanoporous carbon with magnetic Co nanoparticles toward efficient water treatment Torad N L Small 485 Towards the use of metal-organic frameworks for water reuse: a review of the recent advances in the field of organic pollutants removal and degradation and the next steps in the field Dias E M Journal of Materials Chemistry A 396 Nanozymes in bionanotechnology: from sensing to therapeutics and beyond Wang X Y Inorganic Chemistry Frontiers 383 Nanoparticle-templated nanofiltration membranes for ultrahigh performance desalination Wang Z Y Nature Communications 361 Removal of emerging contaminants from the environment by adsorption Sophia A C Ecotoxicology and Environmental Safety 355 
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表 2 MOFs在水处理应用领域研究发文量排名前10的国家
Table 2. Top 10 countries of MOFs in the application field of water treatment
国家 发文量/篇 总被引次数/次 篇均被引次数/次 中国 800 26 067 32.58 美国 119 5 345 44.92 印度 105 2 632 25.07 伊朗 104 2 442 23.48 韩国 83 3 815 45.96 澳大利亚 64 2 613 40.83 新加坡 47 3 078 65.49 西班牙 37 954 25.78 沙特阿拉伯 36 1 233 34.25 英国 35 1 944 55.54
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表 3 MOFs在水处理应用领域发文量排名前10的期刊
Table 3. Top 10 journals of MOFs in the application field of water treatment
期刊 发文量/篇 影响因子 Chemical Engineering Journal 97 11.529 ACS Applied Materials & Interfaces 43 9.57 Journal of Hazardous Materials 42 10.129 Chemosphere 36 6.956 Journal of Environmental Chemical Engineering 35 5.649 RSC Advances 33 3.39 Journal of Membrane Science 30 8.411 Journal of Materials Chemistry A 29 11.995 Journal of Colloid and Interface Science 25 7.211 Separation and Purification Technology 24 6.656
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表 4 MOFs在水处理应用领域发文量排名前10作者
Table 4. Top 10 authors of MOFs in the application field of water treatment
作者 发文量/篇 总被引次数 篇均被引次数/次 Wang Y 30 600 20 Liu Y 22 1 259 52.46 Wang J 20 1 248 62.4 Zeng G M 16 1 661 103.81 Li J 15 736 49.07 Wang H 15 950 63.33 Xiong W P 15 852 56.8 Zhang X 15 188 12.53 Ismail A F 14 853 60.93 Jhung S H 14 1657 118
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表 5 MOFs在水处理应用领域发文量排名前10的机构
Table 5. Top 10 institutions of MOFs in the application field of water treatment
机构 发文
量/篇总被引
次数篇均
被引
次数H指
数英文 中文 Chinese Academy of
Sciences中国科学院 88 3 850 43.75 31 Hunan Univ 湖南大学 43 2 666 62.00 25 National Univ of
Singapore新加坡国立
大学28 1 591 56.82 18 South China Univ of
Technology华南理工大学 27 1 250 46.30 17 Egyptian Knowledge
Bank Ekb埃及知识库 26 549 21.12 13 Kyungpook
National Univ韩国庆北
国立大学24 2 048 85.33 19 Beijing Univ of
Chemical Technology北京化工
大学22 817 37.14 12 Tsinghua Univ 清华大学 21 670 31.90 13 Univ of Chinese Academy
of Sciences中国科学院大学 21 573 27.29 14 Univ of Science and
Technology of China中国科学
技术大学19 1 030 54.21 12 注：H指数即高引用次数，指某研究机构至多有h篇论文被引用了至少h次。
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表 6 2017—2021年MOFs在水处理应用领域各阶段关键词及排序
Table 6. Prevalent keywords of different stages of MOFs in the application field of water treatment from 2017 to 2021
排名 2021年 2020年 2019年 2018年 2017年 关键词 出现次数 关键词 出现次数 关键词 出现频次/次 关键词 出现次数 关键词 出现次数 1 adsorption 70 adsorption 49 adsorption 38 adsorption 26 adsorption 19 2 nanoparticles 31 degradation 27 performance 16 activated carbon 8 performance 8 3 performance 26 nanoparticles 20 degradation 14 nanoparticles 8 acid 6 4 degradation 26 graphene oxide 14 composites 12 stability 7 nanoparticles 6 5 activated carbon 20 oxidation 14 methylene-blue 12 performance 7 ZIF-8 6 6 graphene oxide 18 performance 13 nanoparticles 11 graphene oxide 6 dyes 5 7 advanced oxidation processes 18 personal care products 12 activated carbon 10 composites 6 graphene oxide 5 8 ZIF-8 17 efficient removal 11 mechanism 10 adsorbent 6 activated carbon 4 9 efficient removal 17 advanced oxidation processes 11 adsorbent 9 fabrication 6 UiO-66 4 10 photocatalytic degradation 15 pharmaceuticals 11 graphene oxide 8 methylene-blue 6 nanofiltration 4
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[1] 张统, 李志颖, 董春宏, 等.我国工业废水处理现状及污染防治对策[J]. 给水排水,2020,56(10):1-3.ZHANG T, LI Z Y, DONG C H, et al. Current situation of industrial wastewater treatment and countermeasures of pollution control in China[J]. Water & Wastewater Engineering,2020,56(10):1-3. [2] YAGHI O M, LI G M, LI H L. Selective binding and removal of guests in a microporous metal-organic framework[J]. Nature,1995,378(6558):703-706. doi: 10.1038/378703a0 [3] 陈洁. 染料类金属-有机框架材料对结构相似轻烃的吸附分离性能研究[D]. 杭州: 浙江大学, 2021. [4] 赵怀远. 金属有机框架衍生材料的制备及应用[D]. 杭州: 浙江大学, 2021. [5] WANG D B, JIA F Y, WANG H, et al. Simultaneously efficient adsorption and photocatalytic degradation of tetracycline by Fe-based MOFs[J]. Journal of Colloid and Interface Science,2018,519:273-284. doi: 10.1016/j.jcis.2018.02.067 [6] AHMADIJOKANI F, MOHAMMADKHANI R, AHMADIPOUYA S, et al. Superior chemical stability of UiO-66 metal-organic frameworks (MOFs) for selective dye adsorption[J]. Chemical Engineering Journal,2020,399:125346. doi: 10.1016/j.cej.2020.125346 [7] 张雅然,付正辉,王书航,等.基于Web of Science和CNKI的湖泊沉积物文献计量分析[J]. 环境工程技术学报,2022,12(1):110-118. doi: 10.12153/j.issn.1674-991X.20210113ZHANG Y R,FU Z H,WANG S H,et al. Current situation of research on intersection of fishery resources and ecological environment: bibliometrics and visualization analysis based on Web of Science[J]. Journal of Environmental Engineering Technology,2022,12(1):110-118. doi: 10.12153/j.issn.1674-991X.20210113 [8] Web of Science核心合集[DB/OL]. [2018-08-06]. http://apps.webofknowledge.com. [9] van ECK N, WALTMAN L. VOSviewer: a computer program for bibliometric mapping[J]. ERIM Report Series Research in Management,2009,84(2):523-538. [10] WANG C C, LI J R, LÜ X L, et al. Photocatalytic organic pollutants degradation in metal-organic frameworks[J]. Energy Environmental Science,2014,7(9):2831-2867. doi: 10.1039/C4EE01299B [11] REZAKAZEMI M, EBADI AMOOGHIN A, MONTAZER-RAHMATI M M, et al. State-of-the-art membrane based CO2 separation using mixed matrix membranes (MMMs): an overview on current status and future directions[J]. Progress in Polymer Science,2014,39(5):817-861. doi: 10.1016/j.progpolymsci.2014.01.003 [12] DOHERTY C M, BUSO D, HILL A J, et al. Using functional nano- and microparticles for the preparation of metal-organic framework composites with novel properties[J]. Accounts of Chemical Research,2014,47(2):396-405. doi: 10.1021/ar400130a [13] TORAD N L, HU M, ISHIHARA S, et al. Direct synthesis of MOF-derived nanoporous carbon with magnetic Co nanoparticles toward efficient water treatment[J]. Small,2014,10(10):2096-2107. doi: 10.1002/smll.201302910 [14] HASAN Z, JHUNG S H. Removal of hazardous organics from water using metal-organic frameworks (MOFs): plausible mechanisms for selective adsorptions[J]. Journal of Hazardous Materials,2015,283:329-339. doi: 10.1016/j.jhazmat.2014.09.046 [15] PI Y H, LI X Y, XIA Q B, et al. Adsorptive and photocatalytic removal of Persistent Organic Pollutants (POPs) in water by metal-organic frameworks (MOFs)[J]. Chemical Engineering Journal,2018,337:351-371. doi: 10.1016/j.cej.2017.12.092 [16] BHADRA B N, AHMED I, KIM S, et al. Adsorptive removal of ibuprofen and diclofenac from water using metal-organic framework-derived porous carbon[J]. Chemical Engineering Journal,2017,314:50-58. doi: 10.1016/j.cej.2016.12.127 [17] AHMED I, PANJA T, KHAN N A, et al. Nitrogen-doped porous carbons from ionic Liquids@MOF: remarkable adsorbents for both aqueous and nonaqueous media[J]. ACS Applied Materials & Interfaces,2017,9(11):10276-10285. [18] AN H J, BHADRA B N, KHAN N A, et al. Adsorptive removal of wide range of pharmaceutical and personal care products from water by using metal azolate framework-6-derived porous carbon[J]. Chemical Engineering Journal,2018,343:447-454. doi: 10.1016/j.cej.2018.03.025 [19] BHADRA B N, LEE J K, CHO C W, et al. Remarkably efficient adsorbent for the removal of bisphenol A from water: Bio-MOF-1-derived porous carbon[J]. Chemical Engineering Journal,2018,343:225-234. doi: 10.1016/j.cej.2018.03.004 [20] WANG H, YUAN X Z, WU Y, et al. In situ synthesis of In2S3@MIL-125(Ti) core-shell microparticle for the removal of tetracycline from wastewater by integrated adsorption and visible-light-driven photocatalysis[J]. Applied Catalysis B:Environmental,2016,186:19-29. doi: 10.1016/j.apcatb.2015.12.041 [21] WANG C H, KIM J, MALGRAS V, et al. Metal-organic frameworks and their derived materials: emerging catalysts for a sulfate radicals-based advanced oxidation process in water purification[J]. Small,2019,15(16):1900744. doi: 10.1002/smll.201900744 [22] HUO J B, YU G C, XU L, et al. Porous walnut-like La2O2CO3 derived from metal-organic frameworks for arsenate removal: a study of kinetics, isotherms, and mechanism[J]. Chemosphere,2021,271:129528. doi: 10.1016/j.chemosphere.2020.129528 [23] NAZIR M A, BASHIR M S, JAMSHAID M, et al. Synthesis of porous secondary metal-doped MOFs for removal of Rhodamine B from water: role of secondary metal on efficiency and kinetics[J]. Surfaces and Interfaces,2021,25:101261. doi: 10.1016/j.surfin.2021.101261 [24] SHAHZAD K, NAZIR M A, JAMSHAID M, et al. Synthesis of nanoadsorbent entailed mesoporous organosilica for decontamination of methylene blue and methyl orange from water[J]. International Journal of Environmental Analytical Chemistry, 2021: 1-14. [25] FANG S Y, ZHANG P, GONG J L, et al. Construction of highly water-stable metal-organic framework UiO-66 thin-film composite membrane for dyes and antibiotics separation[J]. Chemical Engineering Journal,2020,385:123400. doi: 10.1016/j.cej.2019.123400 [26] WANG X R, ZHAI L Z, WANG Y X, et al. Improving water-treatment performance of zirconium metal-organic framework membranes by postsynthetic defect healing[J]. ACS Applied Materials & Interfaces,2017,9(43):37848-37855. [27] ZHAO D L, ZHAO Q P, CHUNG T S. Fabrication of defect-free thin-film nanocomposite (TFN) membranes for reverse osmosis desalination[J]. Desalination,2021,516:115230. doi: 10.1016/j.desal.2021.115230 [28] PARK J M, JHUNG S H. Polyaniline-derived carbons: remarkable adsorbents to remove atrazine and diuron herbicides from water[J]. Journal of Hazardous Materials,2020,396:122624. doi: 10.1016/j.jhazmat.2020.122624 [29] AN H J, PARK J M, KHAN N A, et al. Adsorptive removal of bulky dye molecules from water with mesoporous polyaniline-derived carbon[J]. Beilstein Journal of Nanotechnology,2020,11:597-605. doi: 10.3762/bjnano.11.47 [30] BHADRA B N, JHUNG S H. Adsorptive removal of wide range of pharmaceuticals and personal care products from water using bio-MOF-1 derived porous carbon[J]. Microporous and Mesoporous Materials,2018,270:102-108. doi: 10.1016/j.micromeso.2018.05.005 [31] 附青山, 张磊, 张伟, 等.金属-有机框架材料对废水中污染物的吸附研究进展[J]. 材料导报,2021,35(11):11100-11110. doi: 10.11896/cldb.19100039FU Q S, ZHANG L, ZHANG W, et al. Research progress in metal-organic frame materials for adsorptive removal of contamination in wastewater[J]. Materials Reports,2021,35(11):11100-11110. doi: 10.11896/cldb.19100039 [32] 李瑞, 谢光银, 王贤, 等.金属有机框架衍生纳米孔碳材料的研究进展[J]. 合成纤维,2021,50(11):43-49.LI R, XIE G Y, WANG X, et al. Study progress of nanoporous carbon materials derived from metal organic frameworks[J]. Synthetic Fiber in China,2021,50(11):43-49. [33] ZHAO G H, FANG Y Y, DAI W, et al. Copper-containing porous carbon derived from MOF-199 for dibenzothiophene adsorption[J]. RSC Advances,2017,7(35):21649-21654. doi: 10.1039/C7RA02946B [34] AHMED I, BHADRA B N, LEE H J, et al. Metal-organic framework-derived carbons: preparation from ZIF-8 and application in the adsorptive removal of sulfamethoxazole from water[J]. Catalysis Today,2018,301:90-97. doi: 10.1016/j.cattod.2017.02.011 [35] FIROUZJAEI M D, SEYEDPOUR S F, AKTIJ S A, et al. Recent advances in functionalized polymer membranes for biofouling control and mitigation in forward osmosis[J]. Journal of Membrane Science,2020,596:117604. doi: 10.1016/j.memsci.2019.117604 [36] SUN M, YAN L L, ZHANG L H, et al. New insights into the rapid formation of initial membrane fouling after in situ cleaning in a membrane bioreactor[J]. Process Biochemistry,2019,78:108-113. doi: 10.1016/j.procbio.2019.01.004 [37] JACOB L, JOSEPH S, VARGHESE L A. Polysulfone/MMT mixed matrix membranes for hexavalent chromium removal from wastewater[J]. Arabian Journal for Science and Engineering,2020,45(9):7611-7620. doi: 10.1007/s13369-020-04711-3 [38] LI J, WANG H, YUAN X Z, et al. Metal-organic framework membranes for wastewater treatment and water regeneration[J]. Coordination Chemistry Reviews,2020,404:213116. doi: 10.1016/j.ccr.2019.213116 [39] DECOSTE J B, DENNY M S Jr, PETERSON G W, et al. Enhanced aging properties of HKUST-1 in hydrophobic mixed-matrix membranes for ammonia adsorption[J]. Chemical Science,2016,7(4):2711-2716. doi: 10.1039/C5SC04368A [40] ZHANG G P, WO R, SUN Z, et al. Effective magnetic MOFs adsorbent for the removal of bisphenol A, tetracycline, Congo red and methylene blue pollutions[J]. Nanomaterials (Basel, Switzerland),2021,11(8):1917. doi: 10.3390/nano11081917 [41] FU Q S, ZHANG L, ZHANG H F, et al. Ice- and MOF-templated porous carbonaceous monoliths for adsorptive removal of dyes in water with easy recycling[J]. Environmental Research,2020,186:109608. doi: 10.1016/j.envres.2020.109608 [42] LI J, GONG J L, ZENG G M, et al. The performance of UiO-66-NH2/graphene oxide (GO) composite membrane for removal of differently charged mixed dyes[J]. Chemosphere,2019,237:124517. doi: 10.1016/j.chemosphere.2019.124517 [43] CHEN T, JI M, WEN L L, et al. In-situ forming Sub-2 nm hydrous iron oxide particles in MOFs for deep-treatment and high anti-interference in arsenic removal[J]. Chemical Engineering Journal,2022,431:133813. doi: 10.1016/j.cej.2021.133813 [44] 邓圣, 胡宇晗, 杨昱, 等. 金属有机框架材料吸附去除水中有机砷研究进展[J]. 环境科学研究. https://doi.org/10.13198/j.issn.1001-6929.2022.07.20.DENG S, HU Y H, YANG Y, et al. Research progress in adsorption removal of organic arsenic from water by metal-organic frameworks materials[J]. Research of Environmental Sciences. https://doi.org/10.13198/j.issn.1001-6929.2022.07.20. [45] 周琪琪, 王学谦, 宁平, 等.FeCl3改性MOFs在低温下对Hg0的吸附性能[J]. 环境科学研究,2018,31(3):528-536.ZHOU Q Q, WANG X Q, NING P, et al. Adsorption performance of elemental mercury on MOFs modified with FeCl3 at low temperatures[J]. Research of Environmental Sciences,2018,31(3):528-536. [46] TAN F C, LIU M, LI K Y, et al. Facile synthesis of size-controlled MIL-100(Fe) with excellent adsorption capacity for methylene blue[J]. Chemical Engineering Journal,2015,281:360-367. doi: 10.1016/j.cej.2015.06.044 [47] CHEN Q, HE Q Q, LÜ M M, et al. Selective adsorption of cationic dyes by UiO-66-NH2[J]. Applied Surface Science,2015,327:77-85. doi: 10.1016/j.apsusc.2014.11.103 [48] BAI Z Y, LIU Q, ZHANG H S, et al. Anti-biofouling and water-stable balanced charged metal organic framework-based polyelectrolyte hydrogels for extracting uranium from seawater[J]. ACS Applied Materials & Interfaces,2020,12(15):18012-18022. [49] CEN S H, LÜ X G, JIANG Y L, et al. Synthesis and structure of iron-copper/hollow magnetic/metal-organic framework/coordination sites in a heterogeneous catalyst for a Fenton-based reaction[J]. Catalysis Science & Technology,2020,10(19):6687-6693. [50] DU A F, FU H F, WANG P, et al. Enhanced catalytic peroxymonosulfate activation for sulfonamide antibiotics degradation over the supported CoSx-CuSx derived from ZIF-L(Co) immobilized on copper foam[J]. Journal of Hazardous Materials,2022,426:128134. doi: 10.1016/j.jhazmat.2021.128134 [51] ZHAO J J, WEI H X, LIU P S, et al. Activation of peroxymonosulfate by metal-organic frameworks derived Co1+xFe2−xO4 for organic dyes degradation: a new insight into the synergy effect of Co and Fe[J]. Journal of Environmental Chemical Engineering,2021,9(4):105412. doi: 10.1016/j.jece.2021.105412 [52] FAN Y, LIU Y R, HU X, et al. Preparation of metal organic framework derived materials CoFe2O4@NC and its application for degradation of norfloxacin from aqueous solutions by activated peroxymonosulfate[J]. Chemosphere,2021,275:130059. doi: 10.1016/j.chemosphere.2021.130059 [53] 王茀学, 王崇臣.金属-有机骨架MIL-88A(Fe)及其复合物的合成与高级氧化降解水体有机污染物的研究进展[J]. 环境科学研究,2021,34(12):2924-2934.WANG F X, WANG C C. Fabrication approaches and organic pollutants degradation performances via advanced oxidation processes of MIL-88A(Fe) and its composites[J]. Research of Environmental Sciences,2021,34(12):2924-2934. [54] ZHU M P, YANG J C E, DUAN X G, et al. Interfacial CoAl2O4 from ZIF-67@γ-Al2O3 pellets toward catalytic activation of peroxymonosulfate for metronidazole removal[J]. Chemical Engineering Journal,2020,397:125339. ⊗ doi: 10.1016/j.cej.2020.125339 -
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