我国铜、铅和锌冶炼过程中危险废物产生与污染特性

王菲; 张曼丽; 王雪娇; 赵彤; 杨玉飞

doi:10.12153/j.issn.1674-991X.20210080

我国铜、铅和锌冶炼过程中危险废物产生与污染特性

doi: 10.12153/j.issn.1674-991X.20210080

王菲^1,,
张曼丽²,
王雪娇¹,
赵彤¹,
杨玉飞^1,*, ,

1.
国家环境保护危险废物鉴别与风险控制重点实验室,中国环境科学研究院
2.
重庆市固体废物管理中心

详细信息

作者简介:
王菲(1991—),女,助理研究员,主要从事危险废物鉴别研究, wangfei@craes.org.cn

通讯作者:
杨玉飞 E-mail: yangyf@craes.org.cn

中图分类号: X758
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- 被引次数: 0
出版历程
- 收稿日期: 2021-03-22
- 刊出日期: 2021-09-20

Generation and pollution characteristics of hazardous wastes from smelting of copper, lead and zinc in China

1.
State Environmental Protection Key Laboratory of Hazardous Waste Identification and Risk Control, Chinese Research Academy of Environmental Sciences
2.
Chongqing Solid Waste Management Center

More Information

Corresponding author: Yufei YANG E-mail: yangyf@craes.org.cn

摘要

摘要: 我国有色金属冶炼行业工艺和反应多样,废物种类繁多,产生环节迥异,易出现此类危险废物管控过程中废物产生节点识别困难、废物指向不明确以及污染特性不清晰等问题,进而导致管理误判。通过梳理和分析《国家危险废物名录(2021年版)》规定的HW48大类中铜、铅、锌冶炼共22种废物的来源,以及铅滤饼和砷渣等重点废物的污染特性,明确废物指向,并提出完善我国有色金属冶炼危险废物管理的建议。
- 有色金属冶炼 /
- 危险废物 /
- 产生 /
- 污染特性 /
- 管理
Abstract: There are a variety of processes and reactions and numerous kinds of wastes in the non-ferrous metal smelting industry, and the links generating wastes are quite different. It is easy to cause some problems such as the difficulty in identifying waste generation nodes, unclear waste direction, unclear pollution characteristics, and so on, in the process of management and control of such hazardous wastes, thus leading to misjudgment in management. By sorting out and analyzing the sources of 22 kinds of copper, lead and zinc smelting wastes in HW48 in National Catalogue of Hazardous Wastes (NCHWs 2021) and the pollution characteristics of key wastes, such as lead skim and arsenic slag, the waste direction was identified. Finally, suggestions were put forward for improving the management of hazardous wastes from smelting of non-ferrous metals in China.
- non-ferrous metal smelting /
- hazardous waste /
- generation /
- pollution characteristics /
- management

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参考文献(27)

[1]	国家统计局. 中国统计年鉴2017[M]. 北京: 中国统计出版社, 2017.
[2]	舒波, 任军祥, 刘大方, 等. 从铜冶炼烟气制酸污泥中富集汞试验研究[J]. 湿法冶金, 2021, 40(1):57-61. SHU B, REN J X, LIU D F, et al. Enrichment of Hg in acid sludge from acid production using flue gas during copper smelting[J]. Hydrometallurgy of China, 2021, 40(1):57-61.
[3]	郭盼盼, 孔令昊, 胡星云, 等. 铜冶炼污酸废水中Cu²+和Cl^-的同步去除研究[J]. 有色金属工程, 2020, 10(10):120-126. GUO P P, KONG L H, HU X Y, et al. Study on simultaneous removal of Cu2+ and Cl- from copper smelting waste acidic water[J]. Nonferrous Metals Engineering, 2020, 10(10):120-126.
[4]	廖亚龙, 叶朝, 王祎洋, 等. 铜冶炼渣资源化利用研究进展[J]. 化工进展, 2017, 36(8):3066-3073. LIAO Y L, YE C, WANG Y Y, et al. Resource utilization of copper smelter slag:a state-of-the-arts review[J]. Chemical Industry and Engineering Progress, 2017, 36(8):3066-3073.
[5]	蒋开喜, 王海北, 王玉芳, 等. 铜冶炼过程中硫化砷渣综合利用技术[J]. 有色金属科学与工程, 2014, 5(5):13-17. JIANG K X, WANG H B, WANG Y F, et al. Comprehensive utilization technology of arsenic sulphide slag in copper smelting process[J]. Nonferrous Metals Science and Engineering, 2014, 5(5):13-17.
[6]	王鹏, 高利坤, 董方, 等. 铜冶炼渣浮选回收铜的研究现状[J]. 矿产综合利用, 2017(1):16-20. WANG P, GAO L K, DONG F, et al. Status of copper recovery from copper smelting slag by flotation[J]. Multipurpose Utilization of Mineral Resources, 2017(1):16-20.
[7]	韩明霞, 孙启宏, 乔琦, 等. 中国火法铜冶炼污染物排放情景分析[J]. 环境科学与管理, 2009, 34(12):40-44. HAN M X, SUN Q H, QIAO Q, et al. Pollutants emission scenario analysis of China’s copper smelter industry[J]. Environmental Science and Management, 2009, 34(12):40-44.
[8]	李先和, 马成骋, 马平一. 铜冶炼物料中铅、砷、汞的分布走向及回收处理技术研究[J]. 中国有色冶金, 2019, 48(4):17-20. LI X H, MA C C, MA P Y. Investigation on distribution trend and recovery technology of lead,arsenic and mercury in copper smelting materials[J]. China Nonferrous Metallurgy, 2019, 48(4):17-20.
[9]	金尚勇, 李永鹏, 陈虎. 铜冶炼危险废物环境管理问题探讨[J]. 中国资源综合利用, 2019, 37(3):142-143. JIN S Y, LI Y P, CHEN H. Discussion on environmental management of copper smelting hazardous waste[J]. China Resources Comprehensive Utilization, 2019, 37(3):142-143.
[10]	赵伟, 严文勋, 封亚辉. 精矿冶炼过程中固体废物的鉴别[J]. 冶金分析, 2016, 36(10):57-61. ZHAO W, YAN W X, FENG Y H. Identification of solid wastes in the concentrate smelting process[J]. Metallurgical Analysis, 2016, 36(10):57-61.
[11]	白猛. 铜冶炼伴生元素砷、锑、铋、铼的增值冶金新方法研究[D]. 长沙: 中南大学, 2013.
[12]	李方鸿. 硫酸废渣中有害重金属的浸出毒性研究及综合利用建议[D]. 长沙: 湖南农业大学, 2014.
[13]	吴清茹, 王书肖, 惠霂霖. 污酸处理过程的汞流向[J]. 环境工程学报, 2017, 11(9):4965-4970. WU Q R, WANG S X, HUI M L. Mercury flow during waste acid disposal processes[J]. Chinese Journal of Environmental Engineering, 2017, 11(9):4965-4970.
[14]	吴清茹, 王书肖, 王祖光, 等. 锌回转窑处理浸出渣过程汞排放特征研究[J]. 中国环境科学, 2017, 37(7):2513-2519. WU Q R, WANG S X, WANG Z G, et al. Study on mercury emission characteristics during leaching slags disposal process in the rotary kilns of Zn smelters[J]. China Environmental Science, 2017, 37(7):2513-2519.
[15]	胡生杰. 1 450 kt/a铜冶炼烟气制酸硫化工序砷处理能力分析[J]. 硫酸工业, 2019(3):6-8. HU S J. Analysis to increase arsenic treatment capacity in the sulfurization process of 1 450 kt/a copper smelting off-gas acid production system[J]. Sulphuric Acid Industry, 2019(3):6-8.
[16]	谭聪, 肖筱瑜, 孙伟, 等. 铜冶炼污泥中砷的固化/稳定化处理[J]. 矿产与地质, 2020, 34(3):579-582. TAN C, XIAO X Y, SUN W, et al. The solidificating/stabilizing treatment of arsenic element in copper smelting sludge[J]. Mineral Resources and Geology, 2020, 34(3):579-582.
[17]	高志正. 铜冶炼含砷污酸处理工艺的生产实践与改进[J]. 有色冶金节能, 2009, 25(5):53-55. GAO Z Z. Production and improvement on arsenious content acid treatment in copper smelter[J]. Energy Saving of Nonferrous Metallurgy, 2009, 25(5):53-55.
[18]	钟琴道, 乔琦, 李艳萍, 等. 粗铅冶炼过程铅元素流分析[J]. 环境科学研究, 2014, 27(12):1549-1555. ZHONG Q D, QIAO Q, LI Y P, et al. Lead flow analysis of lead bullion smelting process[J]. Research of Environmental Sciences, 2014, 27(12):1549-1555.
[19]	王兵, 孙启宏, 扈学文, 等. 铅冶炼污染防治最佳可行技术筛选研究[J]. 环境工程技术学报, 2011, 1(6):526-532. WANG B, SUN Q H, HU X W, et al. Screening of best available techniques for lead smelting pollution prevention and control[J]. Journal of Environmental Engineering Technology, 2011, 1(6):526-532.
[20]	蒋继穆. 我国铅锌冶炼现状与持续发展[J]. 中国有色金属学报, 2004, 14(增刊1):52-62. JIANG J M. Status and sustainable development of lead and zinc smelting industry in China[J]. The Chinese Journal of Nonferrous Metals, 2004, 14(Suppl 1):52-62.
[21]	牛学奎, 吴学勇, 吴文卫, 等. 典型鼓风炉铅冶炼废渣重金属浸出特性及化学形态分析[J]. 环境工程, 2019, 37(10):174-177. NIU X K, WU X Y, WU W W, et al. Analysis of leaching characteristics and chemical speciation of heavy metals in the slag of lead smelting by blast furnace[J]. Environmental Engineering, 2019, 37(10):174-177.
[22]	刘大钧, 汪家权. 铅冶炼厂无组织排放源不同颗粒物中铅含量特征[J]. 环境科学, 2016, 37(9):3315-3321. LIU D J, WANG J Q. Characterization of particle size distributions of the no-organized lead emission for a lead and zinc smelter[J]. Environmental Science, 2016, 37(9):3315-3321.
[23]	黄汝杰, 谢建宏, 刘振辉. 从锌冶炼渣中回收银的试验研究[J]. 矿冶工程, 2013, 33(2):52-55. HUANG R J, XIE J H, LIU Z H. Experiential study on silver recovery from hydrometallurgical zinc residue[J]. Mining and Metallurgical Engineering, 2013, 33(2):52-55.
[24]	高峰, 贾永忠, 孙进贺, 等. 锌冶炼废渣浸出液硫化法除砷的研究[J]. 环境工程学报, 2011, 5(4):812-814. GAO F, JIA Y Z, SUN J H, et al. Study on arsenic removal from acid-leaching solution of zinc smelter slag with sulfide precipitation process[J]. Chinese Journal of Environmental Engineering, 2011, 5(4):812-814.
[25]	李贺, 陈露露, 王海北, 等. 锌冶炼净化钴渣综合回收工艺研究[J]. 有色金属(冶炼部分), 2019(9):67-71. LI H, CHEN L L, WANG H B, et al. Study on comprehensive recovery process for purification cobalt residue from zinc hydrometallurgy[J]. Nonferrous Metals (Extractive Metallurgy), 2019(9):67-71.
[26]	李皓, 刘美林, 温建康. 广西某锌冶炼厂萃原液中铟的离心萃取研究[J]. 稀有金属, 2019, 43(4):420-427. LI H, LIU M L, WEN J K. Indium centrifugal extraction from feeding liquid[J]. Chinese Journal of Rare Metals, 2019, 43(4):420-427.
[27]	段宏志. 锌冶炼污酸处理工艺改进实践[J]. 中国有色冶金, 2017, 46(2):57-60. DUAN H Z. Practice of zinc smelting waste acid treatment process improvement[J]. China Nonferrous Metallurgy, 2017, 46(2):57-60.