Volume 7 Issue 2
Mar.  2017
Turn off MathJax
Article Contents
Article Navigation >  Journal of Environmental Engineering Technology  > 2017  >  7(2): 249-254
CAO Qing, ZHANG Yanping, TAN Yuling, LIU Yu, WANG Hongchang, WANG Xiangfeng, ZHANG Fan. Determination of fluorine and chlorine in flue gas by ion chromatography[J]. Journal of Environmental Engineering Technology, 2017, 7(2): 249-254. doi: 10.3969/j.issn.1674-991X.2017.02.036
Citation: CAO Qing, ZHANG Yanping, TAN Yuling, LIU Yu, WANG Hongchang, WANG Xiangfeng, ZHANG Fan. Determination of fluorine and chlorine in flue gas by ion chromatography[J]. Journal of Environmental Engineering Technology, 2017, 7(2): 249-254. doi: 10.3969/j.issn.1674-991X.2017.02.036
shu

Determination of fluorine and chlorine in flue gas by ion chromatography

doi: 10.3969/j.issn.1674-991X.2017.02.036
  • 1.

    State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Research Academy of Environmental Sciences, Beijing 100012, China

  • 2.

    Research Center of Air Pollution Control Technology, Chinese Research Academy of Environmental Sciences, Beijing 100012, China

More Information
  • Corresponding author: Yanping ZHANG E-mail: zypneimeng@163.com
  • Received Date: 2016-07-08
  • Publish Date: 2017-03-20
    Abstract
  • The concentrations of fluorine and chlorine in flue gas of a glass furnace in Wuhan were determined by using experimental comparative method. The result shows that the sampling error of EPA Method 26A is lower. Through one sampling it can obtain multiple parameter data such as gaseous fluorine, gaseous chlorine, hydrogen chloride, halogen, etc. with the advantages of saving time and human resources. The chromatographic conditions for analyzing flue gas absorption are optimized. The KOH concentration of EG40 eluent automatic generator is set at 30 mmol/L, with the eluent flow rate of 1.2 mL/min and the injection volume of 25 μL. The method could fully meet the testing requirements of F -, Cl - for flue gas absorbent for its high precision with the relative standard deviation RSD less than 3.0% and good accuracy with sample average recovery rate of 96.7%-104.3%.

     

    • FullText(HTML)
  • loading
    • References(15)
  • [1]
    郑宝山 . 地方性氟中毒及工业氟污染研究[M]. 北京: 中国环境科学出版社, 1992: 8-12.
    [2]
    蒋旭光, 徐旭, 严建华 , 等. 煤中氯的分布及燃烧过程中氯析出特性的试验研究[J]. 煤炭学报, 2001,26(6):667-670.

    JIANG X G, XU X, YAN J H , et al. Research of chlorine in coal and isolation characteristic of chlorine in coal combustion process[J]. Journal of China Coal Society, 2001,26(6):667-670.
    [3]
    环境影响评价工程师培训教材:火电建材[M]. 北京:国家环境保护总局环境影响评价工程师职业资格登记办公室, 2006.
    [4]
    国家环境保护总局. 大气固定污染源氟化物的测定离子选择电极法:HJ/T 67—2001[S]. 北京: 中国标准出版社, 2001.
    [5]
    环境保护部. 固定污染源废气氯气的测定碘量法(暂行):HJ 547—2009[S]. 北京: 中国标准出版社, 2009.
    [6]
    环境保护部. 固定污染源废气氯化氢的测定硝酸银容量法(暂行):HJ 548—2009[S]. 北京: 中国标准出版社, 2009.
    [7]
    国家环境保护总局. 空气和废气监测分析方法[M].4版. 北京: 中国环境科学出版社, 2003: 318-344.
    [8]
    US EPA. Determination of hydrogen halide and halogen emission from stationary sources-isokinetic method:Method 26A[S]. Washington DC:US EPA, 2001.
    [9]
    US EPA. Determination of hydrogen halide and halogen emission from stationary sources-non-isokinetic method:Method 26[S]. Washington DC:US EPA, 2001.
    [10]
    邓双, 李映日, 刘宇 , 等. 固定污染源排气中卤族污染物测定方法研究[C] //中国环境科学学会.中国环境科学学会学术年会论文集. 北京: 中国环境科学出版社, 2011: 1400-1403.
    [11]
    陶钢, 牛星梅 . 离子色谱法测定环境水样阴离子处理方法的试验[J]. 中国环境监测, 1998,14(3):30-31.

    TAO G, NIU X M . Test of sample treatment for the determination of anions in environmental water-samples with ion chromatography[J]. Environmental Monitoring in China, 1998,14(3):30-31.
    [12]
    潘丙珍, 刘青, 庞世琦 , 等. 离子色谱法测定酒中的有机酸和无机阴离子[J]. 现代食品科技, 2013,29(4):876-881.

    PAN B Z, LIU Q, PANG S Q , et al. Determination of organic acids and mineral anions in liquor by ion chromatography[J]. Modern Food Science and Technology, 2013,29(4):876-881.
    [13]
    傅生会 . 离子色谱法同时测定饮用水中的5种无机阴离子[J]. 环境科学与技术, 2013,36(6):265-267.

    FU S H . Simultaneous determination of five inorganic anions in drinking water by ion chromatography[J]. Environmental Science & Technology, 2013,36(6):265-267.
    [14]
    林华影, 林风华, 盛丽娜 , 等. 淋洗液自动发生-离子色谱法同时测定食品中的21种有机酸[J]. 化学测定方法, 2007,25(1):107-111.
    pmid: 17432587

    LIN H Y, LIN F H, SHENG L N , et al. Simultaneous determination of twenty one organic acids in food by ion chromatography with eluent autogeneration[J]. Chinese Journal of Chromatography, 2007,25(1):107-111. pmid: 17432587
    [15]
    杨蕾, 侯英, 王保兴 , 等. 梯度淋洗/离子色谱法对烟草及烟草制品中7种无机阴离子的快速测定[J]. 分析测定学报, 2010,29(2):165-170.

    YANG L, HOU Y, WANG B X , et al. Determination of seven inorganic anions in tobacco and tobacco products using gradient elution/ion chromatography[J]. Journal of Instrumental Analysis, 2010,29(2):165-170.
    • Relative Articles
    • Supplements(0)
    • Cited By
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索
    Get Citation
    PDF
    XML

    Article Metrics

    Article Views(1424) PDF Downloads(884) Cited by()
    Proportional views
    Related

    Copyright © Editorial Department of Journal of Environmental Engineering Technology

    京ICP备05031605号-2

    Supported by: Beijing Renhe Information Technology Co., Ltd.  

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return