The Hg
0, Hg
2+ and Hg
p distribution of coal-fired flue gas was investigated by the OHM and hydride generation-inductively coupled plasma atomic emission spectrometry (HG-ICP-AES) method. The impacts of chlorine and sodium content of wastewater and SO
2 and NO concentration of flue gas on Hg
0 oxidation were tested on the coal-fired test furnace in hot state. The results showed that the ferrous and chlorine content in the test coal was low and the ratio of Hg
0 to Hg
T was 68.3% and 80.6% for coal-fired flue gas 1
# and 2
# respectively, while Hg
2+ ratio was only 22.2% and 13.1% respectively. When the sodium acrylate and naphthalene sulfonate wastewater liquid to flue gas ratio was 0.028 L/m
3, the Hg
2+ ratio reached higher than 80% and 75% in coal-fired flue gas 1
# and 2
# respectively. While, there were no significance variations for Hg
p ratio in flue gas. When the wastewater liquid to flue gas ratio was 0.028 L/m
3, the SO
2 concentration decreased by 11.4%-15.7% and 12.2%-17.7% for coal-fired flue gas 1
# and 2
# respectively, which accelerated Hg
0 oxidation. There was no significant effect of NO in flue gas on Hg
0 oxidation.