Volume 9 Issue 5
Sep.  2019
Turn off MathJax
Article Contents
Article Navigation >  Journal of Environmental Engineering Technology  > 2019  >  9(5): 566-572
LI Zhilin, XIE Yufeng, CHENG Deyi, WANG Lei, SHI Jiaqi, ZHU Xin. Adsorption properties of ammonia-modified wheat straw on aquatic cadmium[J]. Journal of Environmental Engineering Technology, 2019, 9(5): 566-572. doi: 10.12153/j.issn.1674-991X.2019.04.010
Citation: LI Zhilin, XIE Yufeng, CHENG Deyi, WANG Lei, SHI Jiaqi, ZHU Xin. Adsorption properties of ammonia-modified wheat straw on aquatic cadmium[J]. Journal of Environmental Engineering Technology, 2019, 9(5): 566-572. doi: 10.12153/j.issn.1674-991X.2019.04.010
shu

Adsorption properties of ammonia-modified wheat straw on aquatic cadmium

doi: 10.12153/j.issn.1674-991X.2019.04.010
  • 1.

    Nanjing Institute of Environmental Sciences, Ministry of Ecology and Environment, Nanjing 210042, China

  • 2.

    College of Resources and Environmental Science, Nanjing Agricultural University, Nanjing 210095, China

More Information
  • Corresponding author: Yufeng XIE E-mail: pkuyufeng@163.com
  • Received Date: 2018-11-14
  • Publish Date: 2019-09-20
    Abstract
  • In order to solve the problem of chromium-contaminated wastewater, urea ammoniated modified wheat straw was prepared as a kind of Cd 2+ sorbent. The characterization before and after modification was observed by scanning electron and Fourier transform infrared spectroscopy, and the effects of different initial pH and dosage concentration on adsorption capacity of Cd 2+ by wheat straw before and after modification were studied. The adsorption kinetics and isothermal characteristics of wheat straw were fitted by kinetic and thermodynamic models. The results showed that the structure of the ammoniated wheat straw (N1) was loose, the pores were enlarged, the surface was grafted with primary amide group, and the activity of each functional group was enhanced, which was conducive to improving the adsorption capacity of Cd 2+. The optimum conditions for Cd 2+ adsorption on wheat straw after ammoniation modification were pH of 6, temperature of 25 ℃ and sorbent dosage of 1/300 g/mL. Under these conditions, the removal rate and the biggest saturated adsorption capacity were 74.32% and 11.29 mg/g, respectively. At different temperatures, the adsorption kinetics of Cd 2+ on wheat straw modified by ammonia could be described by the quasi-second order kinetic equation, which was shown as the endothermic reaction. The thermodynamic process could be described by Langmuir model, indicating that the adsorption on Cd 2+ was dominated by chemical adsorption.

     

    • FullText(HTML)
  • loading
    • References(32)
  • [1]
    PILLAI S S, DEEPA B, ABRAHAM E , et al. Biosorption of Cd(Ⅱ) from aqueous solution using xanthated nano banana cellulose:equilibrium and kinetic studies[J]. Ecotoxicology & Environmental Safety, 2013,98:352-360.
    [2]
    KIM N, PARK M, PARK D . A new efficient forest biowaste as biosorbent for removal of cationic heavy metals[J]. Bioresource Technology, 2015,175:629-632.
    [3]
    PARK D, YUN Y S, PARK J M . The past,present, and future trends of biosorption[J]. Biotechnology and Bioprocess Engineering, 2010,15:86-102.
    [4]
    丁洋, 靖德兵, 周连碧, 等 .吴亚君 . 板栗内皮对水溶液中镉的吸附研究[J]. 环境科学学报, 2011,31(9):1933-1941.

    DING Y, JING D B, ZHOU L B , et al. Study on the adsorption of aquatic cadmium(Ⅱ) by chestnut inner shell[J]. Acta Scientiae Circumstantiae, 2011,31(9):1933-1941.
    [5]
    ALQADAMI A A, NAUSHAD M, ABDALLA M A , et al. Efficient removal of toxic metal ions from wastewater using a recyclable nanocomposite:a study of adsorption parameters and interaction mechanism[J]. Journal of Cleaner Production, 2017,156:426-436.
    [6]
    SUD D, MAHAJAN G, KAUR M P . Agricultural waste material as potential adsorbent for sequestering heavy metal ions from aqueous solutions:a review[J]. Bioresource Technology, 2008,99:6017-6027.
    [7]
    DANG V, DOAN H, DANG V T , et al. Equilibrium and kinetics of biosorption of cadmium(Ⅱ) and copper(Ⅱ) ions by wheat straw[J]. Bioresource Technology, 2009,100:211-219.
    [8]
    QI J, LIANG Z, DENG X , et al. Adsorption of Cu 2+ onto chestnut(Castanea mollissima) shells:equilibrium, kinetics and process design [J]. Acta Scientiae Circumstantiae, 2009,29:2141-2147.
    [9]
    SARI A, TUZEN M . Biosorption of cadmium(Ⅱ) from aqueous solution by red algae (Ceramium virgatum):equilibrium,kinetic and thermodynamic studies[J]. Journal of Hazardous Materials, 2008,157:448-454.
    [10]
    TATY-COSTODES V C, FAUDUET H, PORTE C , et al. Removal of Cd(Ⅱ) and Pb(Ⅱ) ions,from aqueous solutions,by adsorption onto sawdust of Pinus sylvestris[J]. Journal of Hazardous Materials, 2003,105:121-142.
    [11]
    ARNOLD D R, BINELLI M, VONK J , et al. Sorption of cadmium from aqueous solution using pretreated rice husk[J]. Bioresource Technology, 2006,97:104-109.
    [12]
    KAIKAKE K, HOAKI K, SUNADA H , et al. Removal characteristics of metal ions using degreased coffee beans:adsorption equilibrium of cadmium(Ⅱ)[J]. Bioresource Technology, 2007,98:2787-2791.
    [13]
    MEHRASBI M R, FARAHMANDKIA Z, TAGHIBEIGLOO B , et al. Adsorption of lead and cadmium from aqueous solution by using almond shells[J]. Water Air & Soil Pollution, 2009,199:343-351.
    [14]
    FAROOQ U, KOZINSKI J A, KHAN M A , et al. Biosorption of heavy metal ions using wheat based biosorbents:a review of the recent literature[J]. Bioresource Technology, 2010,101:5043-5053.
    [15]
    刘澜 . 改性稻秆吸附剂表征及处理亚甲基蓝溶液的吸附性能研究[D]. 重庆:重庆大学, 2011.
    [16]
    BAE H D, MCALLISTER T A, KOKKO E G , et al. Effect of silica on the colonization of rice straw by ruminal bacteria[J]. Animal Feed Science & Technology, 1997,65:165-181.
    [17]
    张涵飞, 潘云霞 . 不同化学处理方法对水稻秸秆结构的影响[J]. 广东化工, 2018,45(18):83-84.

    ZHANG H F, PAN Y X . The Effect of different chemical methods on structure of rice straw[J]. Guangdong Chemical Industry, 2018,45(18):83-84.
    [18]
    BUTA J G, ZADRAZIL F, GALLETTI G C . FT-IR determination of lignin degradation in wheat straw by white rot fungus Stropharia rugosoannulata with different oxygen concentrations[J]. Journal of Agricultural and Food Chemistry, 1989,37(5):1382-1384.
    [19]
    田建平, 张名楠, 陈国良 , 等. 红外指纹图谱和聚类分析法在山银花(华南忍冬)产域分类鉴别中的应用[J]. 安徽农业科学, 2015,43(4):112-114.

    TIAN J P, ZHANG M N, CHEN G L , et al. The application in identification and classification in production domain of Lonicerae Flos by using FTIR fingerprint and cluster analysis[J]. Journal of Anhui Agricultural Sciences, 2015,43(4):112-114.
    [20]
    PANIAGUA S, OTERO M, COIMBRA R N , et al. Simultaneous thermogravimetric and mass spectrometric monitoring of the pyrolysis,gasification and combustion of rice straw[J]. Journal of Thermal Analysis & Calorimetry, 2015,121:603-611.
    [21]
    蓝碧健 . 秸秆氨化改性条件对农田土壤中铜离子的去除研究[J]. 广州化工, 2017,45(20):73-75.

    LAN B J . Study on Effects of ammoniation modification of straw on removal of copper ion from agricultural soil[J]. Guangzhou Chemical Industry, 2017,45(20):73-75.
    [22]
    李闻达, 周念莺, 李云 , 等. 共沉淀法制备Cr2O3绿色料[J]. 中国陶瓷, 2017,53(5):67-71.

    LI W D, ZHOU N Y, LI Y , et al. Preparation of Cr2O3 green pigments by co-precipitation method[J]. China Ceramics, 2017,53(5):67-71
    [23]
    王静, 陈光辉, 陈建 , 等. 巯基改性活性炭对水溶液中汞的吸附性能研究[J]. 环境工程学报, 2009,3(2):219-222.

    WANG J, CHEN G H, CHEN J , et al. Investigation on aqueous Hg(Ⅱ) adsorption properties by thiol-modified activated carbon[J]. Chinese Journal of Environmental Engineering, 2009,3(2):219-222.
    [24]
    刘恒博, 徐宝月, 李明明 , 等. 改性小麦秸秆对水中Cd 2+吸附的研究 [J]. 水处理技术, 2013,39(4):15-19.

    LIU H B, XU B Y, LI M M , et al. Adsorption of aquatic cadmium(Ⅱ) by modified wheat straw[J]. Technology of Water Treatment, 2013,39(4):15-19.
    [25]
    王婧瑶 . 黑曲霉-稻草秸秆复合吸附剂吸附重金属离子特征及机制研究[D]. 哈尔滨:哈尔滨工业大学, 2017.
    [26]
    刘树丽, 段正洋, 徐龙乾 , 等. 克雷伯氏菌活细胞和死细胞对水中Pb(Ⅱ)的去除性能[J]. 农业环境科学学报, 2018,37(10):2278-2288.

    LIU S L, DUAN Z Y, XU L Q , et al. Performance of live and dead cells of Klebsiella sp. in removing Pb(Ⅱ) from aqueous solution[J]. Journal of Agro-Environment Science, 2018,37(10):2278-2288.
    [27]
    吴思 . 溶液环境对金属氧化物/水界面上NOM吸附过程中疏水效应的影响研究[D]. 武汉:武汉理工大学, 2011.
    [28]
    王旭亮, 赵静红, 李宗雨 , 等. 离子效应对纳滤膜表面Zeta电位测定的影响[J]. 化学分析计量, 2018,27(3):12-15.

    WANG X L, ZHAO J H, LI Z Y , et al. Influence of ionic effect on Zeta potential measurement of nanofiltration membrane[J]. Chemical Analysis and Meterage, 2018,27(3):12-15.
    [29]
    程德义, 杜超, 黄兆琴 , 等. 巯基化稻壳炭吸附废水中Zn(Ⅱ)试验研究[J]. 环境工程技术学报, 2018,8(5):519-526.

    CHENG D Y, DU C, HUANG Z Q , et al. Adsorption of Zn(Ⅱ) from wastewater by sulfhydryl rice husk carbon[J]. Journal of Environmental Engineering Technology, 2018,8(5):519-526.
    [30]
    钱程, 桂明生, 刘兴勇 . 改性小麦秸秆的制备及其对水中亚甲基蓝的吸附性能[J]. 环境工程, 2014,32(12):42-46.

    QIAN C, GUI M S, LIU X Y . Synjournal and adsorption properties of methylene blue by modified wheat straw[J]. Environmental Engineering, 2014,32(12):42-46.
    [31]
    方彩霞, 李方方, 贾晶 , 等. 巯基改性互花米草对阳离子染料的吸附性能[J]. 环境工程技术学报, 2017,7(2):188-193.

    FANG C X, LI F F, JIA J , et al. Adsorption of cationic dye from aqueous solution by thiol-modified spartina alterniflora[J]. Journal of Environmental Engineering Technology, 2017,7(2):188-193.
    [32]
    高欢, 韦安磊, 郑晓青 , 等. 乙酰化小麦秸秆吸附水中六价铬[J]. 环境工程学报, 2016,10(9):4753-4760.

    GAO H, WEI A L, ZHENG X Q , et al. Adsorption of hexavalent chromium from aqueous solution by acetylated wheat straw[J]. Chinese Journal of Environmental Engineering, 2016,10(9):4753-4760.
    • Relative Articles
    • Supplements(0)
    • Cited By
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索
    Get Citation
    PDF
    XML

    Article Metrics

    Article Views(360) PDF Downloads(108) Cited by()
    Proportional views
    Related

    Copyright © Editorial Department of Journal of Environmental Engineering Technology

    京ICP备05031605号-2

    Supported by: Beijing Renhe Information Technology Co., Ltd.  

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return